Synthesis, structures and anticancer studies of symmetrically and non-symmetrically aliphatic nitrile functionalized silver(I)-N-heterocyclic carbene and palladium(II)-N-heterocyclic carbene complexes

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A new class of luminescent cyclometalated Ir(iii) complexes with readily tunable mechanochromic properties derived from the mechanically induced trans-to-cis isomerization have been developed.


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Iogann Tolbatov ◽  
Dianna Truong ◽  
Davide Mercadante ◽  
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2021 ◽  
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The ruthenium carbene pincer complex 2 was synthesized treating the benzo annulated cycloheptatriene bisphosphine 1 with RuCl3. Addition of three equivalents of hydrogen to the carbocyclic carbene complex 2 was...


Metallomics ◽  
2013 ◽  
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