scholarly journals A copper(II) zig-zag metal–organic coordination polymer: synthesis, crystal structure, topology study, hirshfeld surface analysis and survey different conditions on morphology of a novel nano structure [Cu(L)(SCN)(H2O)2]n.2H2O

2019 ◽  
Vol 50 (2) ◽  
pp. 80-93 ◽  
Author(s):  
Bagher Souri ◽  
Payam Hayati ◽  
Ali Reza Rezvani ◽  
Rafael Mendoza-Meroño ◽  
Jan Janczak
Keyword(s):  
Crystal Structure ◽  
Coordination Polymer ◽  
Surface Analysis ◽  
Polymer Synthesis ◽  
Hirshfeld Surface ◽  
Hirshfeld Surface Analysis ◽  
Nano Structure ◽  
Structure Topology ◽  
Metal Organic

A new ladder-type silver(I) coordination polymer with 4,4′-bipyridine and 4-[(4-carboxybenzyloxy)methyl]benzoate ligands: synthesis, crystal structure, fluorescence properties and Hirshfeld surface analysis

2020 ◽  
Vol 76 (10) ◽  
pp. 952-957
Author(s):  
Zhao Chen ◽  
Zilong Zhang ◽  
Chong Zhang ◽  
Yu Xiao
Keyword(s):  
Crystal Structure ◽  
Coordination Polymer ◽  
Surface Analysis ◽  
Silver Ions ◽  
Hirshfeld Surface ◽  
Hirshfeld Surface Analysis ◽  
Fluorescence Properties ◽  
X Ray Diffraction ◽  
X Ray ◽  
Hydrothermal Methods

A novel ladder-type coordination polymer (CP), poly[(μ-4,4′-bipyridine-κ2 N:N′){μ-4-[(4-carboxybenzyloxy)methyl]benzoato-κO}silver(I)](Ag—Ag), [Ag(C16H13O5)(C10H8N2)] n or [Ag(HL)(4,4′-bpy)] n {H2 L is 4,4′-[oxybis(methylene)]dibenzoic acid and 4,4′-bpy is 4,4′-bipyridine}, was synthesized using hydrothermal methods. The complex was characterized by IR spectroscopy, elemental analysis and single-crystal X-ray diffraction, and is a ladder-type CP which exhibits an obvious Ag—Ag interaction. The legs of the ladder are formed by parallel 4,4′-bipy ligands and silver ions, and the rungs are constructed by Ag—Ag interactions. A Hirshfeld surface analysis was carried out and is discussed in detail. The complex also displays favourable fluorescence properties.

scholarly journals SYNTHESIS, CRYSTAL STRUCTURE AND HIRSHFELD SURFACE ANALYSIS OF A NEW COORDINATION POLYMER: STRONTIUM BENZILATE

2021 ◽  
Vol 66 (1) ◽  
pp. 5081-5085
Author(s):  
Gerzon E. Delgado ◽  
Asiloé J. Mora ◽  
Belkis Ramírez ◽  
Graciela Díaz de Delgado ◽  
Jonathan Cisterna ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Coordination Polymer ◽  
Surface Analysis ◽  
Hirshfeld Surface ◽  
Hirshfeld Surface Analysis

scholarly journals Crystal structure and Hirshfeld surface analysis of poly[tris(μ4-benzene-1,4-dicarboxylato)tetrakis(dimethylformamide)trinickel(II)]: a two-dimensional coordination network

2019 ◽  
Vol 75 (12) ◽  
pp. 1839-1843
Author(s):  
Cesario Ajpi ◽  
Leopoldo Suescun ◽  
Naviana Leiva ◽  
Anders Lundblad ◽  
Göran Lindbergh ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Surface Analysis ◽  
Coordination Mode ◽  
Hirshfeld Surface ◽  
Hirshfeld Surface Analysis ◽  
Two Dimensional ◽  
Positional Disorder ◽  
Coordination Network ◽  
Metal Organic ◽  
Triangular Network

The crystal structure of the title compound, [Ni3(C8H4O4)3(C3H7NO)4], is a two-dimensional coordination network formed by trinuclear linear Ni3(tp)3(DMF)4 units (tp = terephthalate = benzene-1,4-dicarboxylate and DMF = dimethylformamide) displaying a characteristic coordination mode of acetate groups in polynuclear metal–organic compounds. Individual trinuclear units are connected through tp anions in a triangular network that forms layers. One of the DMF ligands points outwards and provides interactions with equivalent planes above and below, leaving the second ligand in a structural void much larger than the DMF molecule, which shows positional disorder. Parallel planes are connected mainly through weak C—H...O, H...H and H...C interactions between DMF molecules, as shown by Hirshfeld surface analysis.

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