Kerim A Kuliyev Kerim A Kuliyev
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Nailya A Verdizadeh Nailya A Verdizadeh
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Geysar S Suleymanova and Naiba N Efendiyeva Geysar S Suleymanova and Naiba N Efendiyeva
Mixed-ligand complexes of Cobalt(II) with dithiolphenol (DP) {2, 6-dithiolphenol (DTP) and its derivatives (2, 6-dithiol-4-methylphenol (DTMP), 2, 6-dithiol-4-propylphenol (DTPP), 2, 6-dithiol-4-tert-buthylphenol (DTBP)} in the presence of aminophenols (AP) have been studied by spectrophotometry. Extraction of mixed ligand complexes is maximal at pH 4.1-6.5. The optimal conditions for the formation and extraction of mixed-ligand compounds have been found and the ratios of components I the complexes have been determined. The Beer’s law was applicable in the range of 0.2-20 μg/ml. The effect of foreign ions and reagents on the extraction was studied. The method is free from common interferences. A procedure has been developed for extraction – spectroand#172;photometric determination cobalt in different objects (in steel, sewage water, bottom sediments, food and soil samples).
Separation and Estimation of Lanthanides as Mixed-Ligand Complexes with Hexafluoroacetylacetone and Tri-n-octylphosphine Oxide Using Solvent Extraction and Gas Chromatography
