Poly[deca-μ2-cyanido-dicyanidobis(μ2-ethylenediamine)bis(ethylenediamine)tricadmium(II)dicobalt(III)]: a two-dimensional coordination polymer

2009 ◽  
Vol 65 (3) ◽  
pp. m118-m120
Author(s):  
Olha Sereda ◽  
Helen Stoeckli-Evans
Keyword(s):  
Coordination Polymer ◽  
Network Structure ◽  
General Position ◽  
Rotation Axis ◽  
Three Dimensional ◽  
The Other ◽  
Dimensional Structure ◽  
Two Dimensional ◽  
Asymmetric Unit ◽  
Dimensional Network

The title coordination polymer, [Cd3Co2(CN)12(C2H8N2)4]n, has an infinite two-dimensional network structure. The asymmetric unit is composed of two crystallographically independent CdIIatoms, one of which is located on a twofold rotation axis. There are two independent ethylenediamine (en) ligands, one of which bis-chelates to the Cd atom that sits in a general position, while the other bridges this Cd atom to that sitting on the twofold axis. The Cd atom located on the twofold rotation axis is linked to four equivalent CoIIIatomsviacyanide bridges, while the Cd atom that sits in a general position is connected to three equivalent CoIIIatomsviacyanide bridges. In this way, a series of trinuclear, tetranuclear and pentanuclear macrocycles are linked to form a two-dimensional network structure lying parallel to thebcplane. In the crystal structure, these two-dimensional networks are linkedviaN—H...N hydrogen bonds involving an en NH2H atom and a cyanide N atom, leading to the formation of a three-dimensional structure. This coordination polymer is only the second example involving a cyanometallate where the en ligand is present in both chelating and bridging coordination modes.

scholarly journals Tris(1,10-phenanthroline-κ2 N,N′)cobalt(II) bis(2,4,5-tricarboxybenzoate) monohydrate

IUCrData ◽  
2019 ◽  
Vol 4 (1) ◽  
Author(s):  
Kai-Long Zhong ◽  
Guo-Qing Cao ◽  
Wei Song ◽  
Chao Ni
Keyword(s):  
Hydrogen Bonds ◽  
Network Structure ◽  
Rotation Axis ◽  
Complex Cation ◽  
Three Dimensional ◽  
Two Dimensional ◽  
Dimensional Network ◽  
Distorted Octahedral

In the complex cation of the title salt, [Co(C12H8N2)3](C10H5O8)2·H2O, the CoII cation is situated on a twofold rotation axis and is coordinated in a distorted octahedral manner by six N atoms from three chelating 1,10-phenanthroline (phen) ligands. In the crystal, the non-coordinating 2,4,5-tricarboxybenzoate anions interact with each other via O—H...O hydrogen bonds, generating a two-dimensional network parallel to (100). Adjacent sheets are connected by waterO—H...Ocarboxylate hydrogen bonds, resulting in a three-dimensional network structure that surrounds the complex cations.

scholarly journals Crystal structure of 1,4-bis(3-ammoniopropyl)piperazine-1,4-diium bis[dichromate(VI)]

2016 ◽  
Vol 72 (5) ◽  
pp. 616-619
Author(s):  
S. Vetrivel ◽  
E. Vinoth ◽  
R. U. Mullai ◽  
R. Aruljothi ◽  
M. NizamMohideen
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bonds ◽  
Network Structure ◽  
Three Dimensional ◽  
Chair Conformation ◽  
The Other ◽  
Inversion Symmetry ◽  
Asymmetric Unit ◽  
Piperazine Ring ◽  
Dimensional Network

The asymmetric unit of the organic–inorganic title salt, (C10H28N4)[Cr2O7]2, comprises one half of an 1,4-bis(3-ammoniopropyl)piperazinediium cation (the other half being generated by the application of inversion symmetry) and a dichromate anion. The piperazine ring of the cation adopts a chair conformation, and the two CrO4tetrahedra of the anion are in an almost eclipsed conformation. In the crystal, the cations and anions form a layered arrangement parallel to (001). N—H...O hydrogen bonds between the cations and anions and additional C—H...O interactions lead to the formation of a three-dimensional network structure.

Poly[(μ-pentafluorobenzoato-κ2O:O′)(pentafluorobenzoato-κO)(μ-pyrazine-κ2N:N′)copper(II)]: a coordination polymer linked into a three-dimensional network by intermolecular C—H...F—C interactions

2014 ◽  
Vol 70 (11) ◽  
pp. 1017-1020 ◽  
Author(s):  
Li-Juan Han ◽  
Ya-Jie Kong
Keyword(s):  
Coordination Polymer ◽  
Title Compound ◽  
Three Dimensional ◽  
Coordination Geometry ◽  
Supramolecular Architecture ◽  
Two Dimensional ◽  
Asymmetric Unit ◽  
Dimensional Network

In the title compound, [Cu(C6F5COO)2(C4H4N2)]n, (I), the asymmetric unit contains one CuIIcation, two anionic pentafluorobenzoate ligands and one pyrazine ligand. Each CuIIcentre is five-coordinated by three O atoms from three independent pentafluorobenzoate anions, as well as by two N atoms from two pyrazine ligands, giving rise to an approximately square-pyramidal coordination geometry. Adjacent CuIIcations are bridged by a pyrazine ligand and two pentafluorobenzoate anions to give a two-dimensional layer. The layers are stacked to generate a three-dimensional supramolecular architectureviastrong intermolecular C—H...F—C interactions, as indicated by the F...H distance of 2.38 Å.

Nanoscale Permanent Rings in Two- or Three-Dimensional Structure Constructed by the Self-Assembly of Copper(II)-Macrocyclic Complexes and Tetracyanonickelate(II)

2013 ◽  
Vol 699 ◽  
pp. 40-45
Author(s):  
Chee Hun Kwak ◽  
Mee Chang ◽  
Min Chul Chung
Keyword(s):  
Hydrogen Bonding ◽  
Network Structure ◽  
Self Assembly ◽  
Three Dimensional ◽  
Ring Structure ◽  
Dimensional Structure ◽  
Crystalline Solid ◽  
Two Dimensional ◽  
One Dimensional ◽  
Dimensional Network

Self-assembly of polyazamacricyclic complexes of copper(II), [Cu(H2L1]4+, where L1 = 1,8-bis(2-aminoethyl)-1,3,6,8,13-hexaazacyclotetradecane, and [Cu(H2L2)]2+, where L2 = 1,8-bis(4-butylic acid)-1,3,6,8,13-hexaazacyclotetradecane, [Ni(CN)4]2- produces two-dimensional permanent ring structure (1) and three-dimensional network structure (2), respectively, in crystalline solid. The geometry around copper(II) ion is an z-elongated octahedron (1) and square pyramid (2). Inter molecular hydrogen bonding of 1 produces one-dimensional ring chain and 2 produces one-dimensional zig-zag shape coordination polymer. Hydrogen bonding of neighboring chains of 1 produces two-dimensional permanent ring structure with a nanoscale area and that of 2 produces three-dimensional network structure having one-dimensional channels with nanoscale cross-section in crystalline solid.

scholarly journals 9-Amino-5,7-dibromo-1,2,3,4-tetrahydroacridine hemihydrate

IUCrData ◽  
2017 ◽  
Vol 2 (7) ◽  
Author(s):  
Ísmail Çelik ◽  
Mehmet Akkurt ◽  
Makbule Ekiz ◽  
Salih Ökten ◽  
Ahmet Tutar ◽  
...  
Keyword(s):  
Hydrogen Bonds ◽  
Water Molecule ◽  
Three Dimensional ◽  
Dimensional Structure ◽  
Stacking Interactions ◽  
Two Dimensional ◽  
Asymmetric Unit ◽  
Compound C ◽  
Dimensional Network ◽  
Centroid Distance

The asymmetric unit of the title compound, C13H12Br2N2·0.5H2O, includes two molecules of 5,7-dibromo-1,2,3,4-tetrahydroacridin-9-amine and one water molecule. In the crystal, C—H...O, N—H...N, N—H...O and O—H...N hydrogen bonds connect the molecules, forming a two-dimensional network parallel to (010). The two-dimensional sheets are further assembled into a three-dimensional structure through C—H...π and π–π stacking interactions [centroid–centroid distance = 3.719 (2) Å].

A two-dimensional CdII coordination polymer with 2,2′-(disulfanediyl)dibenzoate and 1,10-phenanthroline ligands

2014 ◽  
Vol 70 (5) ◽  
pp. 517-521
Author(s):  
Yu-Xiu Jin ◽  
Fang Yang ◽  
Li-Min Yuan ◽  
Chao-Guo Yan ◽  
Wen-Long Liu
Keyword(s):  
Coordination Polymer ◽  
Three Dimensional ◽  
Phen Ligand ◽  
Supramolecular Architecture ◽  
Two Dimensional ◽  
Asymmetric Unit ◽  
Π Interactions ◽  
Carboxylate Groups ◽  
Phenanthroline Ligand ◽  
Phenanthroline Ligands

In poly[[μ3-2,2′-(disulfanediyl)dibenzoato-κ5 O:O,O′:O′′,O′′′](1,10-phenanthroline-κ2 N,N′)cadmium(II)], [Cd(C14H8O4S2)(C12H8N2)] n , the asymmetric unit contains one CdII cation, one 2,2′-(disulfanediyl)dibenzoate anion (denoted dtdb2−) and one 1,10-phenanthroline ligand (denoted phen). Each CdII centre is seven-coordinated by five O atoms of bridging/chelating carboxylate groups from three dtdb2− ligands and by two N atoms from one phen ligand, forming a distorted pentagonal–bipyramidal geometry. The CdII cations are bridged by dtdb2− anions to give a two-dimensional (4,4) layer. The layers are stacked to generate a three-dimensional supramolecular architecture via a combination of aromatic C—H...π and π–π interactions. The thermogravimetric and luminescence properties of this compound were also investigated.

scholarly journals 2-Amino-3-carboxypyridinium perchlorate

2012 ◽  
Vol 68 (6) ◽  
pp. o1601-o1602 ◽  
Author(s):  
Fadila Berrah ◽  
Sofiane Bouacida ◽  
Hayet Anana ◽  
Thierry Roisnel
Keyword(s):  
Hydrogen Bonds ◽  
Three Dimensional ◽  
Two Dimensional ◽  
Asymmetric Unit ◽  
Dimensional Network

The asymmetric unit includes two crystallographically independent equivalents of the title salt, C6H7N2O2 +·ClO4 −. The cations and anions form separate layers alternating along the c axis, which are linked by N—H...O, O—H...O and C—H...O hydrogen bonds into a two-dimensional network parallel to (100). Further C—H...O contacts connect these layers, forming a three-dimensional network, in which R 4 4(20) rings and C 2 2(11) infinite chains can be identified.

scholarly journals Crystal structure of trihydrogen bis{[1,1,1-tris(2-oxidoethylaminomethyl)ethane]cobalt(III)} trinitrate

2015 ◽  
Vol 71 (12) ◽  
pp. m275-m276 ◽  
Author(s):  
Waqas Sethi ◽  
Heini V. Johannesen ◽  
Thorbjørn J. Morsing ◽  
Stergios Piligkos ◽  
Høgni Weihe
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bonding ◽  
Network Structure ◽  
Title Compound ◽  
Rotation Axis ◽  
Three Dimensional ◽  
Rotation Axes ◽  
Dimensional Network ◽  
Nitrate Anions

The title compound, [Co2(L)2]3+·3NO3−[whereL= CH3C(CH2NHCH2CH2OH1/2)3], has been synthesized from the ligand 1,1,1-tris(2-hydroxyethylaminomethyl)ethane. The cobalt(III) dimer has an interesting and uncommon O—H...O hydrogen-bonding motif with the three bridging hydroxy H atoms each being equally disordered over two positions. In the dimeric trication, the octahedrally coordinated CoIIIatoms and the capping C atoms lie on a threefold rotation axis. The N atoms of two crystallographically independent nitrate anions also lie on threefold rotation axes. N—H...O hydrogen bonding between the complex cations and nitrate anions leads to the formation of a three-dimensional network structure. The compound is a racemic conglomerate of crystals containing either D or L molecules. The crystal used for this study is a D crystal.

scholarly journals Bis(μ2-4-nitrophenolato)bis(4-nitrophenolato)di-μ3-oxido-octaphenyltetratin chloroform sesquisolvate [+ solvate]: a tetranuclear stannoxane

IUCrData ◽  
2019 ◽  
Vol 4 (8) ◽  
Author(s):  
Patrick Butler
Keyword(s):  
Hydrogen Bonds ◽  
Electron Density ◽  
Three Dimensional ◽  
The Other ◽  
Dimensional Structure ◽  
Coordination Geometry ◽  
Asymmetric Unit ◽  
Acta Cryst ◽  
Complex Molecules ◽  
Three Dimensional Structure

The title tetranuclear stannoxane, [Sn4(C6H5)8(C6H4NO3)4O2]·1.5CHCl3·solvent, crystallized with two independent complex molecules, A and B, in the asymmetric unit together with 1.5 molecules of chloroform. There is also a region of disordered electron density, which was corrected for using the SQUEEZE routine [Spek (2015). Acta Cryst. C71, 9–18]. The oxo-tin core of each complex is in a planar `ladder' arrangement and each Sn atom is fivefold SnO3C2 coordinated, with one tin centre having an almost perfect square-pyramidal coordination geometry, while the other three Sn centres have distorted shapes. In the crystal, the complex molecules are arranged in layers, composed of A or B complexes, lying parallel to the bc plane. The complex molecules are linked by a number of C—H...O hydrogen bonds within the layers and between the layers, forming a supramolecular three-dimensional structure.

scholarly journals Bis[tris(propane-1,3-diamine-κ2N,N′)nickel(II)] diaquabis(propane-1,3-diamine-κ2N,N′)nickel(II) hexabromide dihydrate

2014 ◽  
Vol 70 (6) ◽  
pp. m227-m228 ◽  
Author(s):  
Aymen Yangui ◽  
Walid Rekik ◽  
Slim Elleuch ◽  
Younes Abid
Keyword(s):  
Hydrogen Bonds ◽  
Title Compound ◽  
General Position ◽  
Three Dimensional ◽  
The Other ◽  
Octahedral Coordination ◽  
Water Molecules ◽  
Coordination Environment ◽  
Lattice Water ◽  
Dimensional Network

In the title compound, [Ni(C3H10N2)3]2[Ni(C3H10N2)2(H2O)2]Br6·2H2O, one Ni2+cation, located on an inversion centre, is coordinated by four N atoms from two ligands and by two water O atoms. The other Ni2+cation, located in a general position, is coordinated by six N atoms from three ligands. In both cases, the Ni2+cation has an octahedral coordination environment. The overall structural cohesion is ensured by three types of hydrogen bonds, N—H...Br, O—H...Br and O—H...O, which connect the two types of complex cations, the bromide counter-anions and the lattice water molecules into a three-dimensional network.

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