Poly[(μ-pentafluorobenzoato-κ2O:O′)(pentafluorobenzoato-κO)(μ-pyrazine-κ2N:N′)copper(II)]: a coordination polymer linked into a three-dimensional network by intermolecular C—H...F—C interactions

2014 ◽  
Vol 70 (11) ◽  
pp. 1017-1020 ◽  
Author(s):  
Li-Juan Han ◽  
Ya-Jie Kong
Keyword(s):  
Coordination Polymer ◽  
Title Compound ◽  
Three Dimensional ◽  
Coordination Geometry ◽  
Supramolecular Architecture ◽  
Two Dimensional ◽  
Asymmetric Unit ◽  
Dimensional Network

In the title compound, [Cu(C6F5COO)2(C4H4N2)]n, (I), the asymmetric unit contains one CuIIcation, two anionic pentafluorobenzoate ligands and one pyrazine ligand. Each CuIIcentre is five-coordinated by three O atoms from three independent pentafluorobenzoate anions, as well as by two N atoms from two pyrazine ligands, giving rise to an approximately square-pyramidal coordination geometry. Adjacent CuIIcations are bridged by a pyrazine ligand and two pentafluorobenzoate anions to give a two-dimensional layer. The layers are stacked to generate a three-dimensional supramolecular architectureviastrong intermolecular C—H...F—C interactions, as indicated by the F...H distance of 2.38 Å.

A two-dimensional CdII coordination polymer with 2,2′-(disulfanediyl)dibenzoate and 1,10-phenanthroline ligands

2014 ◽  
Vol 70 (5) ◽  
pp. 517-521
Author(s):  
Yu-Xiu Jin ◽  
Fang Yang ◽  
Li-Min Yuan ◽  
Chao-Guo Yan ◽  
Wen-Long Liu
Keyword(s):  
Coordination Polymer ◽  
Three Dimensional ◽  
Phen Ligand ◽  
Supramolecular Architecture ◽  
Two Dimensional ◽  
Asymmetric Unit ◽  
Π Interactions ◽  
Carboxylate Groups ◽  
Phenanthroline Ligand ◽  
Phenanthroline Ligands

In poly[[μ3-2,2′-(disulfanediyl)dibenzoato-κ5 O:O,O′:O′′,O′′′](1,10-phenanthroline-κ2 N,N′)cadmium(II)], [Cd(C14H8O4S2)(C12H8N2)] n , the asymmetric unit contains one CdII cation, one 2,2′-(disulfanediyl)dibenzoate anion (denoted dtdb2−) and one 1,10-phenanthroline ligand (denoted phen). Each CdII centre is seven-coordinated by five O atoms of bridging/chelating carboxylate groups from three dtdb2− ligands and by two N atoms from one phen ligand, forming a distorted pentagonal–bipyramidal geometry. The CdII cations are bridged by dtdb2− anions to give a two-dimensional (4,4) layer. The layers are stacked to generate a three-dimensional supramolecular architecture via a combination of aromatic C—H...π and π–π interactions. The thermogravimetric and luminescence properties of this compound were also investigated.

Poly[deca-μ2-cyanido-dicyanidobis(μ2-ethylenediamine)bis(ethylenediamine)tricadmium(II)dicobalt(III)]: a two-dimensional coordination polymer

2009 ◽  
Vol 65 (3) ◽  
pp. m118-m120
Author(s):  
Olha Sereda ◽  
Helen Stoeckli-Evans
Keyword(s):  
Coordination Polymer ◽  
Network Structure ◽  
General Position ◽  
Rotation Axis ◽  
Three Dimensional ◽  
The Other ◽  
Dimensional Structure ◽  
Two Dimensional ◽  
Asymmetric Unit ◽  
Dimensional Network

The title coordination polymer, [Cd3Co2(CN)12(C2H8N2)4]n, has an infinite two-dimensional network structure. The asymmetric unit is composed of two crystallographically independent CdIIatoms, one of which is located on a twofold rotation axis. There are two independent ethylenediamine (en) ligands, one of which bis-chelates to the Cd atom that sits in a general position, while the other bridges this Cd atom to that sitting on the twofold axis. The Cd atom located on the twofold rotation axis is linked to four equivalent CoIIIatomsviacyanide bridges, while the Cd atom that sits in a general position is connected to three equivalent CoIIIatomsviacyanide bridges. In this way, a series of trinuclear, tetranuclear and pentanuclear macrocycles are linked to form a two-dimensional network structure lying parallel to thebcplane. In the crystal structure, these two-dimensional networks are linkedviaN—H...N hydrogen bonds involving an en NH2H atom and a cyanide N atom, leading to the formation of a three-dimensional structure. This coordination polymer is only the second example involving a cyanometallate where the en ligand is present in both chelating and bridging coordination modes.

Bis[2-(2,4-dioxopentan-3-ylidene-κO)-1-(4-methoxyphenyl)hydrazinato-κN 1]copper(II)

2007 ◽  
Vol 63 (3) ◽  
pp. m670-m672 ◽  
Author(s):  
Desmond A. Mac-Leod-Carey ◽  
Carlos Bustos ◽  
Eduardo Schott ◽  
Luis Alvarez-Thon ◽  
Mauricio Fuentealba
Keyword(s):  
Title Compound ◽  
Three Dimensional ◽  
Coordination Geometry ◽  
Formula Unit ◽  
Asymmetric Unit ◽  
Dimensional Network ◽  
Distorted Octahedral

Molecules in the title compound, [Cu(C12H13N2O3)2], are linked via weak C—H...O and C—H...π(arene) interactions into a three-dimensional network. The Cu atom lies on an inversion centre, and therefore the asymmetric unit contains half a formula unit. The coordination geometry about the Cu atom can be described as tetragonally distorted octahedral.

A novel two-dimensional cadmium(II) complex: poly[diaquatris(μ4-cyclohexane-1,4-dicarboxylato)bis[2-(pyridin-4-yl)-1H-benzimidazole]tricadmium(II)

2015 ◽  
Vol 71 (5) ◽  
pp. 369-373 ◽  
Author(s):  
Xiu-Hong Yang ◽  
Ming-Xing Yang ◽  
Li-Juan Chen ◽  
Jing Guo ◽  
Shen Lin
Keyword(s):  
Water Molecule ◽  
Title Compound ◽  
Aqua Ligand ◽  
Coordination Geometry ◽  
Two Dimensional ◽  
Asymmetric Unit ◽  
One Dimensional ◽  
Dimensional Network ◽  
Rotationally Symmetric ◽  
Coordinated Water

The title compound, [Cd3(C8H10O4)3(C12H9N3)2(H2O)2]nor [Cd3(chdc)3(4-PyBIm)2(H2O)2]n, was synthesized hydrothermally from the reaction of Cd(CH3COO)2·2H2O with 2-(pyridin-4-yl)-1H-benzimidazole (4-PyBIm) and cyclohexane-1,4-dicarboxylic acid (1,4-chdcH2). The asymmetric unit consists of one and a half CdIIcations, one 4-PyBIm ligand, one and a half 1,4-chdc2−ligands and one coordinated water molecule. The central CdIIcation, located on an inversion centre, is coordinated by six carboxylate O atoms from six 1,4-chdc2−ligands to complete an elongated octahedral coordination geometry. The two terminal rotationally symmetric CdIIcations each exhibits a distorted pentagonal–bipyramidal geometry, coordinated by one N atom from 4-PyBIm, five O atoms from three 1,4-chdc2−ligands and one O atom from an aqua ligand. The 1,4-chdc2−ligands possess two conformations,i.e.e,e-trans-chdc2−ande,a-cis-chdc2−. Thecis-1,4-chdc2−ligands bridge the CdIIcations to form a trinuclear {Cd3}-based chain along thebaxis, while thetrans-1,4-chdc2−ligands further link adjacent one-dimensional chains to construct an interesting two-dimensional network.

scholarly journals Crystal structure of catena-poly[[[bis(3-oxo-1,3-diphenylprop-1-enolato-κ2 O,O′)zinc(II)]-μ2-tris[4-(pyridin-3-yl)phenyl]amine-κ2 N:N′] tetrahydrofuran monosolvate]

2019 ◽  
Vol 75 (10) ◽  
pp. 1432-1435
Author(s):  
Yukiyasu Kashiwagi ◽  
Koji Kubono ◽  
Toshiyuki Tamai
Keyword(s):  
Coordination Polymer ◽  
Crystal Packing ◽  
Three Dimensional ◽  
Polymer Chains ◽  
Coordination Geometry ◽  
Asymmetric Unit ◽  
One Dimensional ◽  
Π Interactions ◽  
Dimensional Network ◽  
Sheet Structure

The reaction of bis(3-oxo-1,3-diphenylprop-1-enolato-κ2 O,O′)zinc(II), [Zn(dbm)2], with tris[4-(pyridin-3-yl)phenyl]amine (T3PyA) in tetrahydrofuran (THF) afforded the title crystalline coordination polymer, {[Zn(C15H11O2)2(C33H24N4)]·C4H8O} n . The asymmetric unit contains two independent halves of Zn(dbm)2, one T3PyA and one THF. Each ZnII atom is located on an inversion centre and adopts an elongated octahedral coordination geometry, ligated by four O atoms of two dbm ligands in equatorial positions and by two N atoms of pyridine moieties from two different bridging T3PyA ligands in axial positions. The crystal packing shows a one-dimensional polymer chain in which the two pyridyl groups of the T3PyA ligand bridge two independent Zn atoms of Zn(dbm)2. In the crystal, the coordination polymer chains are linked via C—H...π interactions into a sheet structure parallel to (010). The sheets are cross-linked via further C—H...π interactions into a three-dimensional network. The solvate THF molecule shows disorder over two sets of atomic sites having occupancies of 0.631 (7) and 0.369 (7).

Poly[(μ5-3-carboxybenzene-1,2-dicarboxylato)lead(II)]: a helical lead(II) coordination polymer

2014 ◽  
Vol 70 (7) ◽  
pp. 693-696
Author(s):  
Shao-Min Cheng ◽  
Xian-Fei Wang ◽  
Fang Yang ◽  
Hang Chen ◽  
Wen-Long Liu
Keyword(s):  
Optical Properties ◽  
Coordination Polymer ◽  
Three Dimensional ◽  
Pentagonal Bipyramid ◽  
Supramolecular Architecture ◽  
Two Dimensional ◽  
Asymmetric Unit ◽  
Carboxylate Groups

In the title polymer, [Pb(C9H4O6)]n, the asymmetric unit contains a monomer of a PbIIcation with a doubly deprotonated 3-carboxybenzene-1,2-dicarboxylate dianion (1,2,3-Hbtc2−). Each PbIIcentre is seven-coordinated by seven O atoms of bridging carboxy/carboxylate groups from five 1,2,3-Hbtc2−ligands, forming a distorted pentagonal bipyramid. The PbIIcations are bridged by 1,2,3-Hbtc2−anions, yielding two-dimensional chiral layers. The layers are stacked above each other to generate a three-dimensional supramolecular architectureviaa combination of C—H...O interactions. The thermogravimetric and optical properties are also reported.

A new two-dimensional ZnIIcoordination polymer constructed by a multidentate N-heterocyclic ligand and 5-carboxybenzene-1,3-dicarboxylate

2015 ◽  
Vol 71 (8) ◽  
pp. 701-705 ◽  
Author(s):  
Qiu-Ying Huang ◽  
Yi Yang ◽  
Xiang-Ru Meng
Keyword(s):  
Solid State ◽  
Coordination Polymer ◽  
Hydrogen Bonds ◽  
Three Dimensional ◽  
Supramolecular Architecture ◽  
Two Dimensional ◽  
Tetrahedral Geometry ◽  
Heterocyclic Ligand ◽  
Distorted Tetrahedral Geometry ◽  
Dimensional Network

In the coordination polymer, poly[[{μ-1-[(1H-benzimidazol-2-yl)methyl]-1H-imidazole-κ2N:N′}(μ-5-carboxybenzene-1,3-dicarboxylato-κ2O1:O3)zinc(II)] dimethylformamide monosolvate pentahydrate], {[Zn(C9H4O6)(C11H10N4)]·C3H7NO·5H2O}n, the ZnIIion is coordinated by two N atoms from two symmetry-related 1-[(1H-benzimidazol-2-yl)methyl]-1H-imidazole (bmi) ligands and two O atoms from two symmetry-related 5-carboxybenzene-1,3-dicarboxylate (Hbtc2−) ligands in a slightly distorted tetrahedral geometry. The ZnIIions are bridged by Hbtc2−and bmi ligands, leading to a 4-connected two-dimensional network with the topological notation (44.62). Adjacent layers are further connected by 12 kinds of hydrogen bonds and also by π–π interactions, resulting in a three-dimensional supramolecular architecture in the solid state.

A three-dimensional ZnIIcoordination framework: poly[[μ2-(E)-1,2-bis(pyridin-4-yl)ethene][μ4-(E)-2,2′-(diazene-1,2-diyl)dibenzoato][μ2-(E)-2,2′-(diazene-1,2-diyl)dibenzoato]dizinc(II)]

2014 ◽  
Vol 70 (3) ◽  
pp. 277-280 ◽  
Author(s):  
Cai-Xia Yu ◽  
Feng Zhao ◽  
Min Zhou ◽  
Dan-Feng Zhi ◽  
Lei-Lei Liu
Keyword(s):  
Solid State ◽  
Coordination Polymer ◽  
Three Dimensional ◽  
Coordination Geometry ◽  
Two Dimensional ◽  
Tetrahedral Coordination ◽  
Asymmetric Unit ◽  
X Ray Diffraction ◽  
X Ray ◽  
Carboxylate Groups

In the title coordination polymer, [Zn2(C14H8N2O4)2(C12H10N2)]n, the asymmetric unit contains one ZnIIcation, two halves of 2,2′-(diazene-1,2-diyl)dibenzoate anions (denotedL2−) and half of a 1,2-bis(pyridin-4-yl)ethene ligand (denoted bpe). The three ligands lie across crystallographic inversion centres. Each ZnIIcentre is four-coordinated by three O atoms of bridging carboxylate groups from threeL2−ligands and by one N atom from a bpe ligand, forming a tetrahedral coordination geometry. Two ZnIIatoms are bridged by two carboxylate groups ofL2−ligands, generating a [Zn2(CO2)2] ring. Each loop serves as a fourfold node, which links its four equivalent nodesviathe sharing of fourL2−ligands to form a two-dimensional [Zn2L4]nnet. These nets are separated by bpe ligands acting as spacers, producing a three-dimensional framework with a 4664topology. Powder X-ray diffraction and solid-state photoluminescence were also measured.

scholarly journals Crystal structure of a two-dimensional grid-type iron(II) coordination polymer: poly[[diaquatetra-μ-cyanido-diargentate(I)iron(II)]trans-1,2-bis(pyridin-2-yl)ethylene disolvate]

2014 ◽  
Vol 70 (8) ◽  
pp. 107-110 ◽  
Author(s):  
Jintana Othong ◽  
Nanthawat Wannarit ◽  
Chaveng Pakawatchai ◽  
Sujittra Youngme
Keyword(s):  
Crystal Structure ◽  
Title Compound ◽  
Three Dimensional ◽  
Octahedral Geometry ◽  
Water Molecules ◽  
Supramolecular Architecture ◽  
Two Dimensional ◽  
Asymmetric Unit ◽  
Guest Molecules ◽  
Related Compounds

In the title compound, {[Ag2Fe(CN)4(H2O)2]·2C12H10N2}n, the asymmetric unit contains one FeIIcation, two water molecules, two dicyanidoargentate(I) anions and two uncoordinating 1,2-bis(pyridin-2-yl)ethylene (2,2′-bpe) molecules. Each FeIIatom is six-coordinated in a nearly regular octahedral geometry by four N atoms from dicyanidoargentate(I) bridges and two coordinating water molecules. The FeIIatoms are bridged by dicyanidoargentate(I) units to give a two-dimensional layer with square-grid spaces. The intergrid spaces with interlayer distance of 6.550 (2) Å are occupied by 2,2′-bpe guest molecules which form O—H...N hydrogen bonds to the host layers. This leads to an extended three-dimensional supramolecular architecture. The structure of the title compound is compared with some related compounds containing dicyanidoargentate(I) ligands and N-donor organic co-ligands.

scholarly journals 4-Bromo-N-(4-bromophenyl)benzenesulfonamide

IUCrData ◽  
2016 ◽  
Vol 1 (4) ◽  
Author(s):  
Vinola Z. Rodrigues ◽  
S. Naveen ◽  
N. K. Lokanath ◽  
P. A. Suchetan
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bonds ◽  
Torsion Angle ◽  
Title Compound ◽  
Three Dimensional ◽  
Supramolecular Architecture ◽  
Two Dimensional ◽  
Compound C ◽  
Dimensional Network ◽  
Benzene Rings

The molecule of the title compound, C12H9Br2NO2S, is U shaped with the central C—S—N—C segment having a torsion angle of 63.2 (4)°. Further, the dihedral angle between the benzene rings is 38.5 (2)°. The crystal structure features strong N—H...O hydrogen bonds that form infinite [100]C(4) chains. Molecules in adjacent chains are interlinkedviaC—H...O interactions which run along thebaxis, formingC(7) chains. This results in a two-dimensional network in theabplane; adjacent networks are connected by short Br...Br contacts [3.5092 (8) Å] propagating along the diagonal of theacplane, so that a three-dimensional supramolecular architecture ensues.

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