Chlorido(dimethyl 2,2′-bipyridine-4,4′-dicarboxylate-κ2N,N′)(η5-pentamethylcyclopentadienyl)rhodium(III) chloride 1-hydroxypyrrolidine-2,5-dione disolvate

2013 ◽  
Vol 69 (6) ◽  
pp. 584-587
Author(s):  
Dharmalingam Sivanesan ◽  
Hyung Min Kim ◽  
Yoon Sungho
Keyword(s):  
Hydrogen Bonding ◽  
Hydrogen Bonds ◽  
Substitution Reaction ◽  
Three Dimensional ◽  
Title Complex ◽  
Rhodium Complex ◽  
Synthetic Route ◽  
Dimensional Network ◽  
Weak Hydrogen Bonds ◽  
Solvent Molecules

The title complex, [Rh(C10H15)Cl(C14H12N2O4)]Cl·2C4H5NO3, has been synthesized by a substitution reaction of the precursor [bis(2,5-dioxopyrrolidin-1-yl) 2,2′-bipyridine-4,4′-dicarboxylate]chlorido(pentamethylcyclopentadienyl)rhodium(III) chloride with NaOCH3. The RhIIIcation is located in an RhC5N2Cl eight-coordinated environment. In the crystal, 1-hydroxypyrrolidine-2,5-dione (NHS) solvent molecules form strong hydrogen bonds with the Cl−counter-anions in the lattice and weak hydrogen bonds with the pentamethylcyclopentadienyl (Cp*) ligands. Hydrogen bonding between the Cp* ligands, the NHS solvent molecules and the Cl−counter-anions form links in a V-shaped chain of RhIIIcomplex cations along thecaxis. Weak hydrogen bonds between the dimethyl 2,2′-bipyridine-4,4′-dicarboxylate ligands and the Cl−counter-anions connect the components into a supramolecular three-dimensional network. The synthetic route to the dimethyl 2,2′-bipyridine-4,4′-dicarboxylate-containing rhodium complex from the [bis(2,5-dioxopyrrolidin-1-yl) 2,2′-bipyridine-4,4′-dicarboxylate]rhodium(III) precursor may be applied to link Rh catalysts to the surface of electrodes.

scholarly journals Di-μ-tricyanido-tetracyanidobis[hydrotris(pyrazoylborato)]tetramethanoldiiron(III)iron(II) dimethanol disolvate

2014 ◽  
Vol 70 (2) ◽  
pp. m56-m56
Author(s):  
Kuirun Zhang ◽  
Osamu Sato
Keyword(s):  
Hydrogen Bonds ◽  
Three Dimensional ◽  
Title Complex ◽  
Dimensional Network ◽  
Solvent Molecules

In the title complex, [FeIIFeIII2(C9H10BN6)2(CN)6(CH3OH)4]·2CH3OH, two [FeIII(Tp)(CN)3]−anions [Tp is hydrotris(pyrazoylborate)] are bridged by an [FeII(MeOH)4]2+cation, forming a centrosymmetric trinuclear unit. These units are connectedviaO—H...O and O—H...N hydrogen bonds involving the uncoordinated methanol solvent molecules, forming a three-dimensional network.

scholarly journals Bis(2,2′-bipyridine)[1,9-bis(diphenylphosphanyl)-1,2,3,4,6,7,8,9-octahydropyrimido[1,2-a]pyrimidin-5-ium]ruthenium(II) hexafluoridophosphate dibromide dichloromethane disolvate monohydrate

2013 ◽  
Vol 69 (12) ◽  
pp. m640-m641 ◽  
Author(s):  
Congcong Shang ◽  
Laure Vendier ◽  
Pierre Sutra ◽  
Alain Igau
Keyword(s):  
Hydrogen Bonds ◽  
Three Dimensional ◽  
Octahedral Geometry ◽  
Title Complex ◽  
Distorted Octahedral Geometry ◽  
Water Molecules ◽  
Dimensional Network ◽  
Distorted Octahedral ◽  
Solvent Molecules ◽  
Cl Atom

In the cation of the title complex, [Ru(C31H32N3P2)(C10H8N2)2](PF6)(Br)2·2CH2Cl2·H2O, the ruthenium ion is coordinated in a distorted octahedral geometry by two 2,2′-bipyridine (bpy) ligands and a chelating cationicN-diphenylphosphino-1,3,4,6,7,8-hexahydro-2-pyrimido[1,2-a]pyrimidine [(PPh2)2-hpp] ligand. The tricationic charge of the complex is balanced by two bromide and one hexafluoridophosphate counter-anions. The compound crystallized with two molecules of dichloromethane (one of which is equally disordered about a Cl atom) and a water molecule. In the crystal, one of the Br anions bridges two water moleculesviaO—H...Br hydrogen bonds, forming a centrosymmetric diamond-shapedR42(8) motif. The cation and anions and the solvent molecules are linkedviaC—H...F, C—H...Br, C—H...Cl and C—H...O hydrogen bonds, forming a three-dimensional network.

scholarly journals Crystal structure of tetrakis(isonicotinamide-κN)bis(thiocyanato-κN)cobalt(II)–isonicotinamide–ethanol (1/2/1)

2016 ◽  
Vol 72 (8) ◽  
pp. 1077-1080 ◽  
Author(s):  
Tristan Neumann ◽  
Inke Jess ◽  
Christian Näther
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bonding ◽  
Hydrogen Bonds ◽  
Title Compound ◽  
Solvent Molecule ◽  
Three Dimensional ◽  
Asymmetric Unit ◽  
Hydrogen Bonding Interactions ◽  
Dimensional Network ◽  
Solvent Molecules

The asymmetric unit of the title compound, [Co(NCS)2(C6H6N2O)4]·2C6H6N2O·C2H5OH, comprises one CoIIcation, two thiocyanate anions, four coordinating and two solvent isonicotinamide molecules and one ethanol solvent molecule. The CoIIcations are octahedrally coordinated by four N-coordinating isonicotinamide ligands and two terminally N-bonded thiocyanate anions. These discrete complexes are linked by intermolecular N—H...O and N—H...S hydrogen-bonding interactions into a three-dimensional network. The two isonicotinamide and the ethanol solvent molecules are embedded in channels of this network and are linked through further N—H...O and N—H...N hydrogen bonds to the network. The ethanol solvent molecule is disordered over two sets of sites (occupancy ratio 0.6:0.4).

scholarly journals Crystal structure and hydrogen bonding in the water-stabilized proton-transfer salt brucinium 4-aminophenylarsonate tetrahydrate

2016 ◽  
Vol 72 (5) ◽  
pp. 751-755 ◽  
Author(s):  
Graham Smith ◽  
Urs D. Wermuth
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bond ◽  
Hydrogen Bonding ◽  
Hydrogen Bonds ◽  
Proton Transfer ◽  
Network Structure ◽  
Three Dimensional ◽  
Water Molecules ◽  
Arsanilic Acid ◽  
Dimensional Network

In the structure of the brucinium salt of 4-aminophenylarsonic acid (p-arsanilic acid), systematically 2,3-dimethoxy-10-oxostrychnidinium 4-aminophenylarsonate tetrahydrate, (C23H27N2O4)[As(C6H7N)O2(OH)]·4H2O, the brucinium cations form the characteristic undulating and overlapping head-to-tail layered brucine substructures packed along [010]. The arsanilate anions and the water molecules of solvation are accommodated between the layers and are linked to them through a primary cation N—H...O(anion) hydrogen bond, as well as through water O—H...O hydrogen bonds to brucinium and arsanilate ions as well as bridging water O-atom acceptors, giving an overall three-dimensional network structure.

scholarly journals (3aR*,8bR*)-3a,8b-Dihydroxy-1-(4-methylphenyl)-2-methylsulfanyl-3-nitro-1,8b-dihydroindeno[1,2-b]pyrrol-4(3aH)-one

2014 ◽  
Vol 70 (3) ◽  
pp. o279-o280
Author(s):  
R. A. Nagalakshmi ◽  
J. Suresh ◽  
R. Ranjith Kumar ◽  
V. Jeyachandran ◽  
P. L. Nilantha Lakshman
Keyword(s):  
Hydrogen Bonding ◽  
Hydrogen Bonds ◽  
Title Compound ◽  
Three Dimensional ◽  
Dihedral Angles ◽  
Asymmetric Unit ◽  
Compound C ◽  
Dimensional Network ◽  
Independent Molecules ◽  
Hydroxy Groups

The asymmetric unit of the title compound, C19H16N2O5S, contains four independent molecules (A,B,CandD), with two molecules (BandD) displaying disorder in their methylsulfanyl groups [occupancy ratios of 0.797 (11):0.203 (11) and 0.85 (2):0.15 (2)]. The nitro groups are twisted slightly out of the planes of the 2-pyrroline rings to which they are bonded with dihedral angles of 10.17 (1), 8.01 (1), 9.44 (1) and 8.87 (1)° in moleculesA,B,CandD, respectively. The 2-pyrroline rings are almost orthogonal to the attached tolyl rings, forming dihedral angles of 73.44 (1), 81.21 (1), 88.18 (8) and 73.94 (1)° for moleculesA,B,CandD, respectively. A weak intramolecular O—H...O interaction is observed in moleculesBandC. The two hydroxy groups in each molecule are involved in intermolecular O—H...O hydrogen bonding. In the crystal, molecules are connectedviaO—H...O and C—H...O hydrogen bonds, forming a complex three-dimensional network.

trans-Tetraaquabis(pyridine-3-carboxylate-κN)nickel(II)

2000 ◽  
Vol 57 (1) ◽  
pp. m9-m11 ◽  
Author(s):  
Stuart R. Batten ◽  
Alexander R. Harris
Keyword(s):  
Hydrogen Bonding ◽  
Three Dimensional ◽  
Title Complex ◽  
Mirror Plane ◽  
Carboxylate Groups ◽  
Dimensional Network ◽  
A Site ◽  
Water Ligands

The title complex, [Ni(C6H4NO2)2(H2O)4], consists of an Ni atom coordinated to twotranspyridinecarboxylate ligands, coordinated through the N atoms, and four water ligands. The Ni atom lies on a site of 2/msymmetry, and the pyridinecarboxylate ligand lies on a mirror plane. Extensive inter-complex hydrogen bonding occurs between the water ligands and the carboxylate groups, resulting in a three-dimensional network.

trans-Tetraaquabis(pyridine-4-carboxylate-κN)nickel(II)

2000 ◽  
Vol 57 (1) ◽  
pp. m7-m8 ◽  
Author(s):  
Stuart R. Batten ◽  
Alexander R. Harris
Keyword(s):  
Hydrogen Bonding ◽  
Three Dimensional ◽  
Title Complex ◽  
Carboxylate Groups ◽  
Dimensional Network ◽  
Water Ligands

The title complex, [Ni(C6H4NO2)2(H2O)4], consists of Ni atoms coordinated to twotranspyridylcarboxylate ligands, coordinated through the N atoms, and four water ligands. The Ni atom lies on a centre of symmetry. Extensive inter-complex hydrogen bonding occurs between the water ligands and the carboxylate groups, resulting in a three-dimensional network.

scholarly journals 4,4′-{[1,2-Phenylenebis(methylene)]bis(oxy)}dibenzoic acid dimethylformamide disolvate

2014 ◽  
Vol 70 (5) ◽  
pp. o534-o535
Author(s):  
Zhen-Zhe Qiu ◽  
Bi Jing ◽  
Qiu-Xia Li ◽  
Ai-Xin Zhu
Keyword(s):  
Hydrogen Bonds ◽  
Dicarboxylic Acid ◽  
Benzene Ring ◽  
Dihedral Angle ◽  
Solvent Molecule ◽  
Three Dimensional ◽  
Acid Molecule ◽  
Dimensional Network ◽  
Benzene Rings ◽  
Solvent Molecules

In the title solvate, C22H18O6·2C3H7NO, the complete dicarboxylic acid molecule is generated by a crystallographic twofold axis, which bisects the central benzene ring and oneN,N-dimethylformamide solvent molecule. The dihedral angle between the central and pendant benzene rings is 54.53 (5)° while that between the pendant rings is 45.44 (5)°. In the crystal, the acid molecules are linked to the solvent moleculesviaO—H...O and weak C—H...O hydrogen bonds. Further weak C—H...O interactions link adjacent acid molecules into a three-dimensional network.

Diaquabis(dicyanamido)bis[4-(2-pyridyl)-4H-1,2,4-triazole-κN 1]cobalt(II)

2006 ◽  
Vol 62 (7) ◽  
pp. m1479-m1481 ◽  
Author(s):  
Yu-Hong Ma ◽  
Pi-Zhuang Ma ◽  
Huan-Qin Zhu ◽  
Chang-Cheng Liu
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bonds ◽  
Three Dimensional ◽  
Title Complex ◽  
Water Molecules ◽  
Two Dimensional ◽  
Complex Molecules ◽  
Dimensional Network

The title complex, [Co(C2N3)2(C7H6N4)2(H2O)2] or [Co(dca)2(pytrz)2(H2O)2], where pytrz is 4-(2-pyridyl)-4H-1,2,4-triazole and dca is the dicyanamide monoanion, was prepared using pytrz, Na(dca) and CoCl2·6H2O. The CoII atom lies on a center of inversion and is coordinated in a slightly distorted octahderal geometry by two pytrz ligands, two dca ligands and two trans-oriented water molecules. In the crystal structure, complex molecules are linked by O—H...N hydrogen bonds into a two-dimensional network and further into a three-dimensional network via weak C—H...N hydrogen bonds.

scholarly journals Ethylammonium hydrogen oxalate–oxalic acid (2/1)

IUCrData ◽  
2019 ◽  
Vol 4 (5) ◽  
Author(s):  
Assane Toure ◽  
Cheikh Abdoul Khadir Diop ◽  
Libasse Diop ◽  
Laurent Plasseraud ◽  
Hélène Cattey
Keyword(s):  
Hydrogen Bonding ◽  
Hydrogen Bonds ◽  
Oxalic Acid ◽  
Three Dimensional ◽  
Molar Ratio ◽  
Axis Direction ◽  
Dimensional Network

The reaction between ethylamine and oxalic acid in water in a 1:1 molar ratio afforded the title salt, C2H8N+·C2HO4 −·0.5C2H2O4. The hydrogen oxalate anions interact through hydrogen bonding and are organized into a chains propagating along the c-axis direction. The chains are connected to the neighbouring cations and oxalic acid molecules by N—H...O and O—H...O hydrogen bonds and N...O dipole–dipole contacts, leading to a supramolecular three-dimensional network.

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