Bis(cyanido-κC)bis(1,10-phenanthroline-κ2
N,N′)chromium(III) bis(azido-κN)[N,N′-(o-phenylene)bis(pyridine-2-carboxamide)-κ4
N]chromate(III) monohydrate
2007 ◽
Vol 63
(11)
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pp. m2750-m2750
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Keyword(s):
The title compound, [Cr(CN)2(C12H8N2)2][Cr(N3)2(C18H12N4O2)]·H2O, contains [CrIII(CN)2(phen)2]+ cations (phen is 1,10-phenanthroline) and [CrIII(N3)2(bpb)]− anions [bpb is 1,2-bis(pyridine-2-carboxamido)benzene or N,N′-(o-phenylene)bis(pyridine-2-carboxamide)]. In the cations, the CrIII atom is coordinated by two phen ligands and two cyanide ligands in a distorted octahedral geometry. In the anions, the CrIII atom is coordinated by the tetradentate bpb ligand and two azide ions, forming a distorted octahedral geometry. There is one solvent water molecule per cation–anion pair, which forms hydrogen bonds to one carbonyl group of the bpb ligand and to the terminal N atom of one cyanide ligand.
2012 ◽
Vol 68
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pp. m1088-m1088
2014 ◽
Vol 70
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pp. m324-m325
2012 ◽
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pp. m422-m423
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2012 ◽
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pp. m1132-m1132
2012 ◽
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pp. m829-m829
2012 ◽
Vol 68
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pp. m396-m397
2013 ◽
Vol 69
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pp. m89-m89
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2014 ◽
Vol 70
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pp. m170-m171
2012 ◽
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pp. m1058-m1059
2012 ◽
Vol 68
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pp. m413-m414
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