scholarly journals Poly[octakis(1H-imidazole-κN3)octa-μ-oxido-tetraoxidodicopper(II)tetravanadate(V)]

2012 ◽  
Vol 68 (4) ◽  
pp. m362-m363
Author(s):  
Songwuit Chanthee ◽  
Tongchai Saesong ◽  
Watcharin Saphu ◽  
Kittipong Chainok ◽  
Samroeng Krachodnok
Keyword(s):  
Hydrogen Bonds ◽  
Three Dimensional ◽  
Octahedral Geometry ◽  
Distorted Octahedral Geometry ◽  
Supramolecular Network ◽  
Two Dimensional ◽  
Hybrid Compound ◽  
Organic Hybrid ◽  
Distorted Octahedral ◽  
Imidazole Ligands

In the title inorganic–organic hybrid compound, [Cu2V4O12(C3H4N2)8]n, the VVion is tetracoordinated by four O atoms and the CuIIion is hexacoordinated by four N atoms from four imidazole ligands and two O atoms from two tetrahedral vanadate (VO4) units in a distorted octahedral geometry. The structure consists of two-dimensional sheets constructed from centrosymmetric cyclic [V4O12]4−anions covalently bound through O to [Cu(imidazole)4]2+cations. Adjacent sheets are linked by N—H...O hydrogen bonds and weak C—H...π interactions (H...centroid distances = 2.59, 2.66, 2.76, 2.91 and 2.98 Å into a three-dimensional supramolecular network.

scholarly journals Tris(ethylenediamine-κ2N,N′)cadmium hexafluoridogermanate

2012 ◽  
Vol 68 (4) ◽  
pp. m396-m397
Author(s):  
Guo-Ming Wang ◽  
Zeng-Xin Li ◽  
Pei Wang
Keyword(s):  
Hydrogen Bonds ◽  
Title Compound ◽  
Rotation Axis ◽  
Three Dimensional ◽  
Octahedral Geometry ◽  
Distorted Octahedral Geometry ◽  
Supramolecular Network ◽  
Distorted Octahedral ◽  
Axis Passing

In the title compound, [Cd(C2H8N2)3](GeF6), the CdIIatom, lying on a 32 symmetry site, is coordinated by six N atoms from three ethylenediamine (en) ligands in a distorted octahedral geometry. The Ge atom also lies on a 32 symmetry site and is coordinated by six F atoms. The en ligand has a twofold rotation axis passing through the mid-point of the C—C bond. The F atom is disordered over two sites with equal occupancy factors. In the crystal, the [Cd(en)3]2+cations and [GeF6]2−anions are connected through N—H...F hydrogen bonds, forming a three-dimensional supramolecular network.

scholarly journals 1:1 Co-crystal of 4,4′-(ethene-1,2-diyl)dipyridin-1-ium sulfate and hexaaquairon(II) sulfate monohydrate

2014 ◽  
Vol 70 (5) ◽  
pp. m169-m169
Author(s):  
Dan Yang ◽  
Fei-Lin Yang
Keyword(s):  
Hydrogen Bonds ◽  
Dihedral Angle ◽  
Three Dimensional ◽  
Octahedral Geometry ◽  
Double Salt ◽  
Distorted Octahedral Geometry ◽  
Water Molecules ◽  
Supramolecular Network ◽  
Distorted Octahedral

In the title hydrated double salt, 4,4′-(ethene-1,2-diyl)dipyridin-1-ium hexaaquairon(II) bis(sulfate) monohydrate, (C12H12N2)[Fe(H2O)6](SO4)2·H2O, the FeIIcation is coordinated by six water molecules in a slightly distorted octahedral geometry; the two pyridine rings of the 4,4′-(ethene-1,2-diyl)dipyridin-1-ium cation are twisted to each other by a dihedral angle of 11.84 (10)°. In the crystal, the cations, sulfate anions and water molecules of crystallization are linked by O—H...O, N—H...O and weak C—H...O hydrogen bonds, forming a three-dimensional supramolecular network.

scholarly journals catena-Poly[[(acetato-κ2O,O′)[2-(4-oxo-1,4-dihydroquinolin-1-yl)acetato-κO1]copper(II)]-μ-4,4′-bipyridine-κ2N:N′]

2012 ◽  
Vol 68 (8) ◽  
pp. m1132-m1132
Author(s):  
Jun Wang ◽  
Chuntao Dai ◽  
Jianhua Nie
Keyword(s):  
Hydrogen Bonds ◽  
Water Molecule ◽  
Title Compound ◽  
Octahedral Geometry ◽  
Distorted Octahedral Geometry ◽  
Supramolecular Network ◽  
Two Dimensional ◽  
Acetate Ligand ◽  
Distorted Octahedral ◽  
A Chain

In the title compound, [Cu(C11H8NO3)(CH3COO)(C10H8N2)]n, the CuIIion is six-coordinated by two N atoms from two 4,4′-bipyridine ligands, four O atoms from one acetate ligand, one 2-(4-oxo-1,4-dihydroquinolin-1-yl)acetate ligand and one water molecule in a distorted octahedral geometry. The 4,4′-bipyridine ligands interconnect [Cu(C11H8NO3)(CH3COO)] units, giving rise to a chain along [010]. These chains are further linked to each other by O—H...O hydrogen bonds, leading to a two-dimensional supramolecular network parallel to (100).

scholarly journals Crystal structure ofcatena-poly[[[tetraaquairon(II)]-trans-μ-1,2-bis(pyridin-4-yl)ethene-κ2N:N′] bis(p-toluenesulfonate) methanol disolvate]

2017 ◽  
Vol 73 (12) ◽  
pp. 1977-1980
Author(s):  
Volodymyr M. Hiiuk ◽  
Diana D. Barakhty ◽  
Sergiu Shova ◽  
Ruslan A. Polunin ◽  
Il'ya A. Gural'skiy
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bonds ◽  
Three Dimensional ◽  
Distorted Octahedral Geometry ◽  
Water Molecules ◽  
Supramolecular Network ◽  
Polymeric Complex ◽  
Distorted Octahedral ◽  
Polymeric Chains ◽  
Coordinated Water

In the title polymeric complex, {[Fe(C12H10N2)2(H2O)4](CH3C6H4SO3)2·2CH3OH}n, the FeIIcation, located on an inversion centre, is coordinated by four water molecules in the equatorial positions and two 1,2-bis(pyridin-4-yl)ethene molecules in the axial positions. This results in a distorted octahedral geometry for the [N2O4] coordination polyhedron. The 1,2-bis(pyridin-4-yl)ethene molecules bridge the FeIIcations, forming polymeric chains running along thea-axis direction. Stabilization of the crystal structure is provided by O—H...O hydrogen bonds; these are formed by coordinated water molecules as donors towards the O atoms of the methanol molecules and tosylate anions as acceptors of protons, leading to the formation of a three-dimensional supramolecular network. Weak C—H...O hydrogen bonds are also observed in the crystal.

scholarly journals Bis(2,2′,2′′-nitrilotriacetamide-κ3O,N,O′)nickel(II) dinitrate tetrahydrate

2013 ◽  
Vol 69 (2) ◽  
pp. m89-m89 ◽  
Author(s):  
Xiao-Hui Deng ◽  
Qi-Jun Nie ◽  
Feng-Juan Zhu
Keyword(s):  
Hydrogen Bonds ◽  
Title Compound ◽  
Three Dimensional ◽  
Octahedral Geometry ◽  
Distorted Octahedral Geometry ◽  
Water Molecules ◽  
Inversion Center ◽  
Lattice Water ◽  
Distorted Octahedral ◽  
Nitrate Anions

In the title compound, [Ni(C6H12N4O3)2](NO3)2·4H2O, the NiIIcation is located on an inversion center and isN,O,O′-chelated by two nitrilotris(acetamide) molecules in a distorted octahedral geometry. The complex cations, nitrate anions and lattice water molecules are connected by O—H...O and N—H...O hydrogen bonds, forming a three-dimensional supramolecular structure.

scholarly journals cis-Tetraaquabis{5-[4-(1H-imidazol-1-yl-κN3)phenyl]tetrazolido}manganese(II) dihydrate

2012 ◽  
Vol 68 (4) ◽  
pp. m413-m414 ◽  
Author(s):  
Xin Wang ◽  
Shi-Wei Yan ◽  
Suo-Cheng Chang ◽  
Yan-Chen Liang ◽  
Fu-Tian Zhang
Keyword(s):  
Hydrogen Bonds ◽  
Rotation Axis ◽  
Three Dimensional ◽  
Imidazole Ring ◽  
Octahedral Geometry ◽  
Dimensional Structure ◽  
Distorted Octahedral Geometry ◽  
Water Molecules ◽  
Solvent Water ◽  
Distorted Octahedral

In the title compound, [Mn(C10H7N6)2(H2O)4]·2H2O, the complex unit comprises an Mn2+ion, coordinated by two imidazole N atoms fromcis-related monodentate 5-[4-(imidazol-1-yl)phenyl]tetrazolide ligands and four water molecules, together with two water molecules of solvation. The Mn2+ion lies on a twofold rotation axis and has a slightly distorted octahedral geometry. The molecules are connected by O—H...N and O—H...O hydrogen bonds involving both coordinated and solvent water molecules, generating a three-dimensional structure. Two C atoms of the imidazole ring of the ligand are each disordered over two sites with occupancy factors of 0.75 and 0.25.

scholarly journals (2,2′-Bipyridine-6,6′-dicarboxylato-κ3N,N′,O6)(6′-carboxy-2,2′-bipyridine-6-carboxylato-κ3N,N′,O6)cobalt(III)

2012 ◽  
Vol 68 (4) ◽  
pp. m411-m412
Author(s):  
Huimin Wang ◽  
Xiaojun Gu ◽  
Bingbing Zhang ◽  
Haiquan Su
Keyword(s):  
Hydrogen Bonds ◽  
Title Compound ◽  
Octahedral Geometry ◽  
Distorted Octahedral Geometry ◽  
Stacking Interactions ◽  
Two Dimensional ◽  
Carboxylate Ligands ◽  
Face To Face ◽  
Centroid Distance ◽  
Distorted Octahedral

The CoIIIatom in the title compound, [Co(C12H6N2O4)(C12H7N2O4)], is six-coordinated in a distorted octahedral geometry by four N atoms and two O atoms of the chelating 2,2′-bipyridine-6,6′-dicarboxylate and 6′-carboxy-2,2′-bipyridine-6-carboxylate ligands. Intermolecular O—H...O hydrogen bonds and face-to-face π-stacking interactions [centroid–centroid distance = 3.6352 (16) Å] between inversion-related pyridine rings link adjacent mononuclear units into a two-dimensional supramolecular structure, and several intermolecular C—H...O interactions are also observed.

scholarly journals Bis(n-dodecylammonium) bis(chloranilato)diethanolcuprate(II)

2014 ◽  
Vol 70 (2) ◽  
pp. m63-m64 ◽  
Author(s):  
Akiko Himegi ◽  
Satoshi Kawata
Keyword(s):  
Hydrogen Bonds ◽  
Title Compound ◽  
Octahedral Geometry ◽  
Distorted Octahedral Geometry ◽  
Two Dimensional ◽  
Inversion Center ◽  
Axis Direction ◽  
Compound C ◽  
Dimensional Network ◽  
Distorted Octahedral

In the title compound, (C12H25NH3)2[Cu(C6Cl2O4)2(C2H5OH)2], the CuIIatom lies on a crystallographic inversion center and is coordinated in a distorted octahedral geometry by four O atoms of two chloranilate ligands and two O atoms of two ethanol molecules which aretransto each other in the axial positions. In the crystal, the CuIImononuclear dianions are linked by O—H...O hydrogen bonds into a tape along thea-axis direction. The tapes are linked through N—H...O hydrogen bonds between the dianion and then-dodecylammonium cation, forming a two-dimensional network parallel to theabplane.

scholarly journals Aquabis(4-nitrobenzoato)-κ2O,O′;κO-(piperidinium-4-carboxylato-κ2O,O′)cadmium(II)

2009 ◽  
Vol 65 (6) ◽  
pp. m664-m665 ◽  
Author(s):  
Run-Wen Zhang ◽  
Li-Li Wang ◽  
Xiao-Jun Zhao
Keyword(s):  
Water Molecule ◽  
Three Dimensional ◽  
Chair Conformation ◽  
Octahedral Geometry ◽  
Mixed Ligand ◽  
Distorted Octahedral Geometry ◽  
Supramolecular Network ◽  
Distorted Octahedral ◽  
Coordinated Water ◽  
Mononuclear Structure

In the mixed ligand title compound, [Cd(C6H11NO2)(C7H4NO4)2(H2O)], which exhibits a discrete mononuclear structure, the CdIIatom is in a distorted octahedral geometry, surrounded by five carboxylate O atoms and one coordinated water molecule. The piperdinium ring adopts a chair conformation and the two 4-nitrobenzoate rings are oriented at a dihedral angle of 75.8 (1)°. Intermolecular O—H...O and N—H...O hydrogen bonds link the mononuclear entities into a three-dimensional supramolecular network.

Diaquabis(5-carboxy-2-methyl-1H-imidazole-4-carboxylato-κ2 N 3,O 4)cadmium(II)

2007 ◽  
Vol 63 (3) ◽  
pp. m753-m755 ◽  
Author(s):  
Xu-Liang Nie ◽  
Hui-Liang Wen ◽  
Zi-Sheng Wu ◽  
Da-Bo Liu ◽  
Chong-Bo Liu
Keyword(s):  
Hydrogen Bonds ◽  
Equatorial Plane ◽  
Three Dimensional ◽  
Octahedral Geometry ◽  
Distorted Octahedral Geometry ◽  
Water Molecules ◽  
Supramolecular Framework ◽  
Inversion Center ◽  
Distorted Octahedral ◽  
Coordinated Water

In the title compound, [Cd(C6H7N2O5)2], the Cd atom lies on an inversion center and has a slightly distorted octahedral geometry. The equatorial plane contains two bidentate 5-carboxy-2-methyl-1H-imidazole-4-carboxylate monoanionic ligands. Two coordinated water molecules occupy the axial sites. Intermolecular N—H...O hydrogen bonds link the molecules into chains, which are further connected by intermolecular O—H...O hydrogen bonds, resulting in a three-dimensional supramolecular framework.

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