scholarly journals Tris(3-chloropentane-2,4-dionato-κ2 O,O′)iron(III)

2012 ◽  
Vol 68 (6) ◽  
pp. m807-m807
Author(s):  
Franc Perdih
Keyword(s):  
Title Compound ◽  
Rotation Axis ◽  
Distorted Octahedral Environment ◽  
Bond Lengths ◽  
Octahedral Environment ◽  
Distorted Octahedral

In the title compound, [Fe(C5H6ClO2)3], the FeIII cation is situated on a twofold rotation axis and is coordinated by six O atoms from three 3-chloropentane-2,4-dionate ligands in a slightly distorted octahedral environment. Fe—O bond lengths are in the range 1.9818 (18)–1.9957 (18) Å. The trans O—Fe—O angles are 169.06 (13) and 171.54 (8)°, whereas the corresponding cis angles are in the range 84.81 (10)–100.68 (12)°. In the crystal, molecules are linked via C—H...Cl interactions.

scholarly journals Tris(2-acetylcyclopentan-1-onato-κ2 O,O′)aluminium

2012 ◽  
Vol 68 (6) ◽  
pp. m781-m781
Author(s):  
Franc Perdih
Keyword(s):  
Title Compound ◽  
Thermal Motion ◽  
The Other ◽  
Distorted Octahedral Environment ◽  
Bond Lengths ◽  
Octahedral Environment ◽  
Distorted Octahedral

In the title compound, [Al(C7H9O2)3], the AlIII cation is coordinated by six O atoms from three 2-acetylcyclopentanonate ligands in a slightly distorted octahedral environment, with Al—O bond lengths in the range 1.882 (2)–1.896 (2) Å. In the crystal, molecules are linked together via C—H...O interactions. One of the C atoms in one ring has a large thermal motion compared to the other atoms, indicating some possible disorder. However, the treatment of this C atom as disordered over two positions did not give a significant improvement.

scholarly journals A neutral cubane with a ZnII4O4core: tetrabenzoatotetrakis(μ3-hydroxydi-2-pyridylmethanolato)tetrazinc(II)–acetone–methanol (1/2/1)

2009 ◽  
Vol 65 (6) ◽  
pp. m658-m659 ◽  
Author(s):  
Dong Hoon Shin ◽  
Sim-Hee Han ◽  
Pan-Gi Kim ◽  
Cheal Kim ◽  
Youngmee Kim
Keyword(s):  
Hydrogen Bonds ◽  
Title Compound ◽  
Rotation Axis ◽  
Solvent Molecule ◽  
Asymmetric Unit ◽  
Distorted Octahedral Environment ◽  
Octahedral Environment ◽  
Distorted Octahedral ◽  
Type Bond

In the title compound, [Zn4(C11H9N2O2)4(C7H5O2)4]·2(CH3)2CO·CH3OH, the tetranuclear molecule lies on a fourfold inversion axis. ZnIIions and μ3-O atoms in the cubane core occupy alternating vertices, forming two interpenetrating tetrahedra. Each ZnIIion is further coordinated by two N atoms from two different (py)2C(OH)O ligands (py is pyridyl) and one O atom from a monodentate benzoate ligand, forming a distorted octahedral environment. The (py)2C(OH)O ligand acts in an η1:η3:η1:μ3manner, forming two five-membered ZnNCCO chelating rings with two different ZnIIatoms sharing a common C—O bond, and an alkoxide-type bond to a third ZnIIion. There are four symmetry-related intramolecular O—H...O hydrogen bonds between the two types of ligands. In the asymmetric unit, there is a half-occupancy acetone solvent molecule and a half-occupancy methanol solvent molecule that lies on a twofold rotation axis.

Tris[2-(1,3-thiazol-2-yl-κN)-1H-benzimidazole-κN3]zinc(II) dinitrate ethanol hemisolvate monohydrate at 100 K

2013 ◽  
Vol 69 (2) ◽  
pp. 119-122
Author(s):  
F. L. Oliveira ◽  
P. C. Huber ◽  
W. P. Almeida ◽  
J. R. Sabino ◽  
R. Aparicio
Keyword(s):  
Hydrogen Bonds ◽  
Title Compound ◽  
Solvent Molecule ◽  
Water Molecules ◽  
Inversion Center ◽  
Distorted Octahedral Environment ◽  
Bond Lengths ◽  
Octahedral Environment ◽  
Distorted Octahedral ◽  
Benzene Rings

The ZnIIcenter in the dicationic complex of the title compound, [Zn(C10H7N3S)3](NO3)2·0.5C2H5OH·H2O, is in a distorted octahedral environment with imperfect noncrystallographicC3symmetry. Each 2-(1,3-thiazol-2-yl)-1H-benzimidazole ligand coordinates in a bidentate manner, with the Zn—N(imidazole) bond lengths approximately 0.14 Å shorter than the Zn—N(thiazole) bond lengths. Charge-assisted hydrogen bonds connect cations, anions and water molecules. A lattice void is occupied by an ethanol solvent molecule disordered about a crystallographic inversion center and π-stacking is observed between one type of symmetry-related benzene rings.

scholarly journals Poly[bis(μ-4-aminobenzenesulfonato-κ2 N:O)diaquacobalt(II)]

IUCrData ◽  
2018 ◽  
Vol 3 (8) ◽  
Author(s):  
Antoine Blaise Kama ◽  
Mamadou Sidibe ◽  
Cheikh Abdoul Khadre Diop ◽  
Florent Blanchard
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bonding ◽  
Title Compound ◽  
Three Dimensional ◽  
Water Molecules ◽  
Supramolecular Framework ◽  
Distorted Octahedral Environment ◽  
Octahedral Environment ◽  
Distorted Octahedral

The title compound, [Co(C6H6NO3S)2(H2O)2] n , was obtained from a mixture of Co(NO3)2·6H2O and a previously synthesized salt, namely CyNH3·NH2PhSO3, in a 1:1 ratio (Cy = cyclohexyl; Ph = phenyl). The crystal structure consists of a three-dimensional supramolecular framework, in which polymeric layers are interconnected via N—H...O and O—H...O hydrogen bonding. The polymeric layers are formed by an interconnection of neighbouring cobalt(II) cations via NH2PhSO3 − bridges. Each cobalt(II) cation is surrounded by four NH2PhSO3 − moieties and two water molecules, leading to a distorted octahedral environment.

scholarly journals Tris[2,4-dichloro-6-(ethyliminomethyl)phenolato-κ2N,O]cobalt(III)

2012 ◽  
Vol 68 (8) ◽  
pp. m1047-m1047 ◽  
Author(s):  
Qiu Ping Huang ◽  
Jing Jing Guo ◽  
Yi Dong Zhang ◽  
Shu Hua Zhang
Keyword(s):  
Hydrogen Bond ◽  
Title Compound ◽  
Asymmetric Unit ◽  
Distorted Octahedral Environment ◽  
Octahedral Environment ◽  
Distorted Octahedral ◽  
Phenolate Ligands ◽  
Independent Molecules

The asymmetric unit of the title compound, [Co(C9H8Cl2NO)3], contains three independent molecules. In each molecule, the CoIIIion is coordinated by an O atom and an N atom from three bidentate 2,4-dichloro-6-(ethyliminomethyl)phenolate ligands in a slightly distorted octahedral environment. In the crystal, a weak C—H...Cl hydrogen bond is observed.

(2,9-Dimethyl-1,10-phenanthroline-κ2 N,N′)bis(3-hydroxybenzoato-κ2 O,O′)manganese(II) 2,9-dimethyl-1,10-phenanthroline dihydrate

2007 ◽  
Vol 63 (11) ◽  
pp. m2813-m2814 ◽  
Author(s):  
Xiao-peng Xuan ◽  
Pei-zheng Zhao ◽  
Shu-xia Zhang
Keyword(s):  
Hydrogen Bonds ◽  
Title Compound ◽  
Three Dimensional ◽  
Water Molecules ◽  
Distorted Octahedral Environment ◽  
Octahedral Environment ◽  
Dimensional Network ◽  
Distorted Octahedral

In the title compound, [Mn(C7H5O3)2(C14H12N2)]·C14H12N2·2H2O, the MnII ion is coordinated by a bidentate 2,9-dimethyl-1,10-phenanthroline (dmphen) ligand and two bidentate 3-hydroxybenzoate anions in a distorted octahedral environment. The structure is stabilized by O—H...O and O—H...N hydrogen bonds involving water molecules, the 3-hydroxybenzoate ligands and the uncoordinated dmphen molecules to form a three-dimensional network.

catena-Poly[[bis(1,3-propylenediamine)zinc(II)]-μ-naphthalene-2,6-dicarboxylato-κ2 O 2:O 6]

2006 ◽  
Vol 62 (4) ◽  
pp. m736-m737
Author(s):  
Rong Yu ◽  
Ya-Qi Jiang ◽  
Zhao-Xiong Xie
Keyword(s):  
Dicarboxylic Acid ◽  
Title Compound ◽  
Chain Structure ◽  
Dimensional Chain ◽  
Distorted Octahedral Environment ◽  
One Dimensional ◽  
Octahedral Environment ◽  
Distorted Octahedral

The title compound, [Zn(C12H6O4)(C3H10N2)2] n , has been prepared from zinc(II), naphthalene-2,6-dicarboxylic acid (H2napdc) and 1,3-propylenediamine (pren). The Zn atom lies on a crystallographic centre of symmetry and is coordinated by two monodentate naphthalene-2,6-dicarboxylate ligands and two chelating 1,3-propylenediamine ligands in a distorted octahedral environment. The naphthalene-2,6-dicarboxylate ligands link the Zn atoms, forming a one-dimensional chain structure.

scholarly journals Crystal structure of bis(2,2′-bipyridine-κ2N,N′)bis(thiocyanato-κN)manganese(II) 2,2′-bipyridine monosolvate

2015 ◽  
Vol 71 (1) ◽  
pp. m3-m4
Author(s):  
Stefan Suckert ◽  
Inke Jess ◽  
Christian Näther
Keyword(s):  
Crystal Structure ◽  
Intermolecular Interactions ◽  
Title Compound ◽  
Van Der Waals ◽  
Van Der Waals Forces ◽  
Asymmetric Unit ◽  
Complex Molecules ◽  
Distorted Octahedral Environment ◽  
Octahedral Environment ◽  
Distorted Octahedral

In the crystal structure of the mononuclear title compound, [Mn(NCS)2(C10H8N2)2]·C10H8N2, the MnIIcation is coordinated in an all-cisconfiguration by two N-bound thiocyanate anions and two 2,2′-bipyridine ligands within a slightly distorted octahedral environment. The asymmetric unit consists of one MnIIcation, two thiocyanate anions and two 2,2′-bipyridine ligands, as well as two non-coordinating 2,2′-bipyridine ligands that are each located on centres of inversion. In the crystal structure, the discrete [Mn(NCS)2(C10H8N2)2] complex molecules are arranged in such a way that cavities are formed, in which the solvent 2,2′-bipyridine molecules are located. Apart from van der Waals forces, there are no remarkable intermolecular interactions present in the crystal structure.

scholarly journals cis-Aquabis[bis(diphenylphosphino)ethane-κ2 P,P′]chlororuthenium(II) hexafluorophosphate dichloromethane sesquisolvate hemihydrate

2006 ◽  
Vol 62 (4) ◽  
pp. m699-m701 ◽  
Author(s):  
Luca Russo ◽  
João Figueira ◽  
João Rodrigues ◽  
Kari Rissanen
Keyword(s):  
Water Molecule ◽  
Title Compound ◽  
Chloride Anion ◽  
Distorted Octahedral Environment ◽  
Octahedral Environment ◽  
Distorted Octahedral

In the title compound, [RuCl(C26H24P)2(H2O)]PF6·1.5CH2Cl2·0.5H2O, the complex RuII cation is in a slightly distorted octahedral environment, chelated by two bis(diphenylphosphino)ethane ligands, with a water molecule and a chloride anion in a mutually cis geometry completing the coordination.

scholarly journals Tris(pyrrolidin-1-yl)carbenium tri-μ-iodido-bis[triiodidobismuthate(III)]

IUCrData ◽  
2016 ◽  
Vol 1 (3) ◽  
Author(s):  
Ioannis Tiritiris ◽  
Georg Knobloch ◽  
Stefan Saur ◽  
Willi Kantlehner
Keyword(s):  
Double Bond ◽  
Title Compound ◽  
Rotation Axis ◽  
Asymmetric Unit ◽  
Charge Delocalization ◽  
Iodide Ions ◽  
Bond Lengths ◽  
Distorted Octahedral ◽  
Methylene Groups ◽  
Bond Character

The asymmetric unit of the title compound, 3(C13H24N3)+[Bi2I9]3−, comprises two cations and one half of a [Bi2I9]3−ion. The C—N bond lengths of the CN3units in both cations range from 1.336 (3) to 1.364 (5) Å, indicating partial double-bond character pointing towards charge delocalization within the NCN planes. All five-membered rings adopt an envelope conformation with the C atoms as the flap. One of the pyrrolidine rings (cation I) is disordered over two alternative envelope conformations. Two sets of positions were found for two of the methylene groups with an occupancy ratio of 0.757 (10):0.243 (10). The second disordered pyrrolidine moiety (cation II) is disordered around a twofold rotation axis and exhibits two half-occupied symmetry equivalent counterparts. The two BiIIIions are coordinated by six iodide ions in a distorted octahedral manner, with the Bi–I bond lengths ranging from 2.9544 (2) to 3.2414 (2) Å. Two [BiI6]3−octahedra are fused together through face-sharing, forming a dinuclear [Bi2I9]3−unit. The bond lengths of bismuth to the terminal iodides [2.9544 (2)–2.9889 (2) Å] are shorter than the bridging ones [3.1450 (2)–3.2414 (2) Å].

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