Bis{μ-N-[(E)-4-benzyloxy-2-oxidobenzylidene]-4-nitrobenzenecarbohydrazidato}bis[diaquanickel(II)] dimethylformamide tetrasolvate
2014 ◽
Vol 70
(6)
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pp. m211-m212
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Keyword(s):
The molecule of the title complex, [Ni2(C21H15N3O5)2(H2O)4]·4C3H7NO, is located on an inversion centre. This results in a dimeric NiIIcomplex, with the two NiIIatoms bridged by phenolate O atoms. The tridentate ligand is chelated to each NiIIatomviaone N and two O atoms of the iminolate form of the hydrazide moiety, which has the same conformation as the free ligand. The coordination geometry around each NiIIion is slightly distorted octahedral. A supramolecular three-dimensional architecture is created by dominant intermolecular O—H...N, O—H...O and C—H...O hydrogen-bonding interactions. These are augmented by two C—H...π interactions and a π–π interaction with a centroid–centroid distance of 3.681 (2) Å.
2012 ◽
Vol 68
(6)
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pp. m809-m810
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2016 ◽
Vol 72
(4)
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pp. 486-488
2007 ◽
Vol 63
(3)
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pp. m772-m773
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2007 ◽
Vol 63
(3)
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pp. m774-m775
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2012 ◽
Vol 68
(4)
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pp. m427-m427
2007 ◽
Vol 63
(11)
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pp. m2694-m2694
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2019 ◽
Vol 75
(3)
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pp. 348-353
2008 ◽
Vol 63
(12)
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pp. 1357-1360
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2006 ◽
Vol 62
(4)
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pp. m796-m798
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2015 ◽
Vol 71
(10)
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pp. 1165-1168