Crystal structure of (2E)-N-methyl-2-(2-oxo-1,2-dihydroacenaphthylen-1-ylidene)hydrazinecarbothioamide
2014 ◽
Vol 70
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pp. 415-417
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Keyword(s):
In the title compound, C14H11N3OS, the acenaphthylene ring system and hydrazinecarbothioamide unit (=N—NH—C=S—NH–) are essentially coplanar [with maximum deviations from their mean planes of −0.009 (2) and 0.033 (2) Å, respectively], and make a dihedral angle of 1.59 (9)°. The molecular conformation is stabilized by two weak intramolecular hydrogen bonds (N—H...O and N—H...N), which generateS(6) andS(5) ring motifs. In the crystal, molecules are linked by N—H...S hydrogen bonds, forming chains along [010]. The chains are linkedviapairs of C—H...O hydrogen bonds, enclosingR22(10) ring motifs, and C—H...π interactions, forming a three-dimensional framework. The absolute structure of the title compound was determined by resonant scattering.
2014 ◽
Vol 70
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pp. o1096-o1097
2014 ◽
Vol 70
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pp. o1029-o1030
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2015 ◽
Vol 71
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pp. o492-o493
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2015 ◽
Vol 71
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pp. o807-o808
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2014 ◽
Vol 70
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pp. o1168-o1168
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2018 ◽
Vol 74
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pp. 555-558
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2014 ◽
Vol 70
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pp. o1013-o1014
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2015 ◽
Vol 71
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pp. 107-109
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2015 ◽
Vol 71
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pp. 58-61
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