CdII and CoII coordination polymers constructed from benzene-1,4-dicarboxylic acid and 2-(pyridin-3-yl)-1H-benzimidazole ligands

2014 ◽  
Vol 70 (5) ◽  
pp. 488-492
Author(s):  
Xiao-Hua Chen ◽  
Hua Huang ◽  
Ming-Xing Yang ◽  
Li-Juan Chen ◽  
Shen Lin
Keyword(s):  
Hydrogen Bonding ◽  
Layer Structure ◽  
Three Dimensional ◽  
Water Molecules ◽  
Dimensional Chain ◽  
One Dimensional ◽  
Hydrogen Bonding Interactions ◽  
Dimensional Network ◽  
Complex Forms ◽  
Coordinated Water

In poly[aqua(μ3-benzene-1,4-dicarboxylato-κ5 O 1,O 1′:O 1:O 4,O 4′)[2-(pyridin-3-yl-κN)-1H-benzimidazole]cadmium(II)], [Cd(C8H4O4)(C12H9N3)(H2O)] n , (I), each CdII ion is seven-coordinated by the pyridine N atom from a 2-(pyridin-3-yl)benzimidazole (3-PyBIm) ligand, five O atoms from three benzene-1,4-dicarboxylate (1,4-bdc) ligands and one O atom from a coordinated water molecule. The complex forms an extended two-dimensional carboxylate layer structure, which is further extended into a three-dimensional network by hydrogen-bonding interactions. In catena-poly[[diaquabis[2-(pyridin-3-yl-κN)-1H-benzimidazole]cobalt(II)]-μ2-benzene-1,4-dicarboxylato-κ2 O 1:O 4], [Co(C8H4O4)(C12H9N3)2(H2O)2] n , (II), each CoII ion is six-coordinated by two pyridine N atoms from two 3-PyBIm ligands, two O atoms from two 1,4-bdc ligands and two O atoms from two coordinated water molecules. The complex forms a one-dimensional chain-like coordination polymer and is further assembled by hydrogen-bonding interactions to form a three-dimensional network.

scholarly journals Diaquabis{4-[(pyridin-2-yl)methylideneamino]benzenesulfonato-κ2 N,N′}nickel(II) tetrahydrate

2012 ◽  
Vol 68 (6) ◽  
pp. m809-m810 ◽  
Author(s):  
Chao-Zhu Li ◽  
Xue-Ren Huang
Keyword(s):  
Hydrogen Bonding ◽  
Three Dimensional ◽  
Title Complex ◽  
Water Molecules ◽  
Framework Structure ◽  
Distorted Octahedral Environment ◽  
Hydrogen Bonding Interactions ◽  
Octahedral Environment ◽  
Distorted Octahedral ◽  
Coordinated Water

In the title complex, [Ni(C12H9N2O3S)2(H2O)2]·4H2O, the NiII ion is coordinated by four N atoms from two bidentate chelating 4-[(pyridin-2-yl)methylideneamino]benzenesulfonate ligands and two O atoms from cis-related water molecules in a slightly distorted octahedral environment [Ni—N = 2.071 (3)–2.121 (3) Å and Ni—O = 2.071 (2) and 2.073 (3) Å]. In the crystal, the coordinated water molecules and the four water molecules of solvation are involved in intermolecular O—H...O hydrogen-bonding interactions with water and sulfonate O-atom acceptors, giving a three-dimensional framework structure.

Redetermination of trans-diaquabis(picolinato-κ2 N,O)cobalt(II) dihydrate

2006 ◽  
Vol 62 (4) ◽  
pp. m796-m798 ◽  
Author(s):  
Zerrin Heren ◽  
Cem Cüneyt Ersanlı ◽  
Cem Keser ◽  
Nazan Ocak Ískeleli
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bonding ◽  
Title Compound ◽  
Three Dimensional ◽  
Water Molecules ◽  
Inversion Center ◽  
Hydrogen Bonding Interactions ◽  
Dimensional Network ◽  
Distorted Octahedral

The crystal structure of the title compound, [Co(C6H4NO2)2(H2O)2]·2H2O, has been reinvestigated with improved precision [previous reports: Chang et al. (1972). J. Coord. Chem. 2, 31–34; Lumme et al. (1969). Suom. Kemistil. B, 42, 270]. In the title compound, the Co atom is located on an inversion center and its coordination can be described as slightly distorted octahedral, equatorially trans-coordinated by two N and O atoms of two picolinate ligands and axially coordinated by two O atoms of the water molecules. Intermolecular O—H...O and C—H...O hydrogen-bonding interactions result in the formation of an intricate three-dimensional network.

Triaqua[2-(6-oxido-4-oxo-3,4-dihydropyimidin-2-ylsulfanyl)acetato]nickel(II) 2.5-hydrate

2007 ◽  
Vol 63 (3) ◽  
pp. m761-m763 ◽  
Author(s):  
Yan Jiao ◽  
Zhao-Rui Pan ◽  
Zhi-Jie Fang ◽  
Yi-Zhi Li ◽  
He-Gen Zheng
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bonding ◽  
Network Structure ◽  
Title Compound ◽  
Three Dimensional ◽  
Organic Ligand ◽  
Water Molecules ◽  
Hydrogen Bonding Interactions ◽  
Acetate Ligand ◽  
Dimensional Network

In the crystal structure of the title compound, [Ni(C6H4N2O4S)(H2O)3]·2.5H2O, the NiII atom is six-coordinated by one 2-(6-oxido-4-oxo-3,4-dihydropyimidin-2-ylsulfanyl)acetate ligand and three water molecules. Hydrogen-bonding interactions between the coordinated and uncoordinated water molecules and between the water molecules and the organic ligand result in a three-dimensional network structure.

scholarly journals catena-Poly[[[triaquacobalt(II)]-μ-10-methylphenothiazine-3,7-dicarboxylato] monohydrate]

2012 ◽  
Vol 68 (4) ◽  
pp. m402-m403
Author(s):  
Yun-Xia Hu ◽  
Yan Zhou ◽  
Fang-Ming Wang ◽  
Wen-Wei Zhang
Keyword(s):  
Hydrogen Bonding ◽  
Three Dimensional ◽  
Water Molecules ◽  
Hydrogen Bonding Interactions ◽  
Octahedral Environment ◽  
Carboxylate Groups ◽  
Dimensional Network ◽  
Distorted Octahedral ◽  
Benzene Rings ◽  
Interchain Interactions

The polymeric title compound, {[Co(C15H9NO4S)(H2O)3]·H2O}n, consists of chains along [001] made up from Co2+ions bridged by 10-methylphenothiazine-3,7-dicarboxylate anions. The Co2+ion, coordinated by three O atoms from two different carboxylate groups and three water molecules, displays a distorted octahedral environment. In the crystal, π–π interchain interactions, with centroid–centroid distances of 3.656 (2) and 3.669 (2) Å between the benzene rings of the ligands, assemble the chains into sheets parallel to (100). O—H...O hydrogen-bonding interactions between the coordinating water molecules and carboxylate O atoms link the sheets into a three-dimensional network.

scholarly journals catena-Poly[[diaqua(1H-imidazo[4,5-f][1,10]phenanthroline)cobalt(II)]-μ-sulfato]

2009 ◽  
Vol 65 (6) ◽  
pp. m618-m618 ◽  
Author(s):  
Jian Yu
Keyword(s):  
Three Dimensional ◽  
Title Complex ◽  
Water Molecules ◽  
Coordination Environment ◽  
One Dimensional ◽  
Distorted Octahedral Coordination ◽  
Dimensional Network ◽  
Distorted Octahedral ◽  
Coordinated Water ◽  
Distorted Octahedral Coordination Environment

The CoIIion in the title complex, [Co(SO4)(C13H8N4)(H2O)2]n, has a slightly distorted octahedral coordination environment formed by two O atoms from two symmetry-related bridging sulfate ligands, two N atoms from a bis-chelating 1H-imidazo[4,5-f][1,10]phenanthroline (IPL) ligand and two O atoms from coordinated water molecules. The bridging sulfate ligands connect CoIIions to form a one-dimensional chain along theb-axis direction. In the crystal structure, intermolecular O—H...O, O—H...N and N—H...O hydrogen bonds link the chains into a three-dimensional network.

The three-dimensional hydrogen-bonded structures in the ammonium and sodium salt hydrates of 4-aminophenylarsonic acid

2014 ◽  
Vol 70 (8) ◽  
pp. 738-741 ◽  
Author(s):  
Graham Smith ◽  
Urs D. Wermuth
Keyword(s):  
Hydrogen Bonding ◽  
Sodium Salt ◽  
Three Dimensional ◽  
Three Dimensions ◽  
Dimensional Structure ◽  
Water Molecules ◽  
One Dimensional ◽  
Arsanilic Acid ◽  
Hydrogen Bonding Interactions ◽  
The One

The structures of two hydrated salts of 4-aminophenylarsonic acid (p-arsanilic acid), namely ammonium 4-aminophenylarsonate monohydrate, NH4+·C6H7AsNO3−·H2O, (I), and the one-dimensional coordination polymercatena-poly[[(4-aminophenylarsonato-κO)diaquasodium]-μ-aqua], [Na(C6H7AsNO3)(H2O)3]n, (II), have been determined. In the structure of the ammonium salt, (I), the ammonium cations, arsonate anions and water molecules interact through inter-species N—H...O and arsonate and water O—H...O hydrogen bonds, giving the common two-dimensional layers lying parallel to (010). These layers are extended into three dimensions through bridging hydrogen-bonding interactions involving thepara-amine group acting both as a donor and an acceptor. In the structure of the sodium salt, (II), the Na+cation is coordinated by five O-atom donors, one from a single monodentate arsonate ligand, two from monodentate water molecules and two from bridging water molecules, giving a very distorted square-pyramidal coordination environment. The water bridges generate one-dimensional chains extending alongcand extensive interchain O—H...O and N—H...O hydrogen-bonding interactions link these chains, giving an overall three-dimensional structure. The two structures reported here are the first reported examples of salts ofp-arsanilic acid.

A two-dimensional cadmium(II) coordination polymer based on 5-(pyridin-4-yl)isophthalic acid: poly[[tetraaquabis[μ3-5-(pyridin-4-yl)isophthalato]dicadmium(II)] pentahydrate]

2015 ◽  
Vol 71 (9) ◽  
pp. 834-838 ◽  
Author(s):  
Fang Liu ◽  
Jing-Jing Zhang ◽  
Ming-Yuan Lei ◽  
Qing-Fu Zhang
Keyword(s):  
Hydrothermal Reaction ◽  
Layer Structure ◽  
Three Dimensional ◽  
Isophthalic Acid ◽  
Water Molecules ◽  
Coordination Geometry ◽  
Two Dimensional ◽  
Hydrogen Bonding Interactions ◽  
Carboxylate Groups ◽  
Coordinated Water

The title CdIIcompound, {[Cd2(C13H7NO4)2(H2O)4]·5H2O}n, was synthesized by the hydrothermal reaction of Cd(NO3)2·4H2O and 5-(pyridin-4-yl)isophthalic acid (H2L). The asymmetric unit contains two crystallographically independent CdIIcations, two deprotonatedL2−ligands, four coordinated water molecules and five isolated water molecules. One of the CdIIcations adopts a six-coordinate octahedral coordination geometry involving three O atoms from one bidentate chelating and one monodentate carboxylate group of two differentL2−ligands, one N atom of anotherL2−ligand and two coordinated water molecules. The second CdIIcation adopts a seven-coordinate pentagonal–bipyramidal coordination geometry involving four O atoms from two bidentate chelating carboxylate groups of two differentL2−ligands, one N atom of anotherL2−ligand and two coordinated water molecules. EachL2−ligand bridges three CdIIcations and, likewise, each CdIIcation connects to threeL2−ligands, giving rise to a two-dimensional graphite-like 63layer structure. These two-dimensional layers are further linked by O—H...O hydrogen-bonding interactions to form a three-dimensional supramolecular architecture. The photoluminescence properties of the title compound were also investigated.

A coordination polymer consisting of two different one-dimensional copper(II) chains

2014 ◽  
Vol 70 (3) ◽  
pp. 285-288
Author(s):  
Yang Wu ◽  
Wen-Zhen Wang ◽  
Rayyat Huseyn Ismayilov ◽  
Gene-Hsiang Lee ◽  
Shie-Ming Peng
Keyword(s):  
Hydrogen Bonding ◽  
Coordination Polymer ◽  
Title Compound ◽  
Three Dimensional ◽  
Water Molecules ◽  
Dimensional Chain ◽  
Straight Chain ◽  
Chain Polymer ◽  
Pyrazine Ring ◽  
One Dimensional

The title compound,catena-poly[[[diaqua(methanol-κO)copper(II)]-μ-N-(4-methylpyrimidin-2-yl-κN1)pyrazin-2-amine-κ2N1:N4] [[aqua(aqua/methanol-κO)(perchlorato-κO)copper(II)]-μ-N-(4-methylpyrimidin-2-yl-κN1)pyrazin-2-amine-κ2N1:N4] tris(perchlorate) methanol monosolvate 1.419-hydrate], {[Cu(C9H9N5)(CH3OH)(H2O)2][Cu(C9H9N5)(ClO4)(CH3OH)0.581(H2O)1.419](ClO4)3·CH3OH·1.419H2O}n, is a one-dimensional straight-chain polymer ofN-(4-methylpyrimidin-2-yl)pyrazin-2-amine (L) with Cu(ClO4)2. The complex consists of two crystallographically independent one-dimensional chains in which the CuIIatoms exhibit two different octahedral coordination geometries. TheLligand coordinates to two CuIIcentres in a tridentate manner, with the pyrazine ring acting as a bridge linking the CuIIcoordination units and building an infinite one-dimensional chain. Extensive hydrogen bonding among perchlorate anions, water molecules andLligands results in three-dimensional networks.

Bridging behaviour of the 2-thiobarbiturate anion in its complexes with LiIand NaI

2013 ◽  
Vol 69 (7) ◽  
pp. 704-708 ◽  
Author(s):  
Nikolay Golovnev ◽  
Maxim Molokeev
Keyword(s):  
Hydrogen Bonding ◽  
Three Dimensional ◽  
Thiobarbituric Acid ◽  
Two Dimensional ◽  
Hydrogen Bonding Interactions ◽  
Dimensional Network ◽  
Coordinated Water ◽  
Water Ligands

The structures of the LiIand NaIsalts of 2-thiobarbituric acid (2-sulfanylidene-1-3-diazinane-4,6-dione, H2TBA) have been studied. μ-Aqua-octaaquabis(μ-2-thiobarbiturato-κ2O:O′)bis(2-thiobarbiturato-κO)tetralithium(I) dihydrate, [Li4(C4H3N2O2S)4(H2O)9]·2H2O, (I), crystallizes with four symmetry-independent four-coordinated LiIcations and four independent HTBA−anions. The structure contains two structurally non-equivalent LiIcations and two non-equivalent HTBA−anions (bridging and terminal). Eight of the coordinated water ligands are terminal and the ninth acts as a bridge between LiIcations. Discrete [Li4(HTBA)4(H2O)9]·2H2O complexes form two-dimensional layers. Neighbouring layers are connectedviahydrogen-bonding interactions, resulting in a three-dimensional network. Poly[μ2-aqua-tetraaqua(μ4-2-thiobarbiturato-κ4O:O:S:S)(μ2-thiobarbiturato-κ2O:S)disodium(I)], [Na2(C4H3N2O2S)2(H2O)5]n, (II), crystallizes with six-coordinated NaIcations. The octahedra are pairwise connected through edge-sharing by a water O atom and an O atom from the μ4-HTBA−ligand, and these pairs are further top-shared by the S atoms to form continuous chains along theadirection. Two independent HTBA−ligands integrate the chains to give a three-dimensional network.

A novel cadmium(II) coordination polymer containing two kinds of independent one-dimensional chain

2013 ◽  
Vol 69 (8) ◽  
pp. 829-832 ◽  
Author(s):  
Wei-Qiang Liao ◽  
Yi Zhang
Keyword(s):  
Three Dimensional ◽  
Water Molecules ◽  
Dimensional Chain ◽  
Two Dimensional ◽  
One Dimensional ◽  
Solvent Water ◽  
Carboxylate Groups ◽  
Chloride Ligand ◽  
Chloride Ligands ◽  
Coordinated Water

The structure of the title compound,catena-poly[[cadmium(II)-di-μ-chlorido-μ-(1,4-diazoniabicyclo[2.2.2]octane-1-carboxylato)] [[aquachloridocadmium(II)]-di-μ-chlorido] dihydrate], {[Cd(C8H15N2O2)Cl2][CdCl3(H2O)]·2H2O}n, contains two kinds of independent one-dimensional chain,viz.{[Cd(C8H15N2O2)Cl2]+}nand {[CdCl3(H2O)]−}n, and uncoordinated water molecules. Each CdIIcation in the {[Cd(C8H15N2O2)Cl2]+}nchain is octahedrally coordinated by two pairs of bridging chloride ligands and two O atoms from different bridging carboxylate groups. CdIIcations in the {[CdCl3(H2O)]−}nchain are also octahedrally surrounded by four bridging chloride ligands, one terminal chloride ligand and one coordinated water molecule. Hydrogen bonds between solvent water molecules and these two independent chains generate a three-dimensional framework containing two-dimensional zigzag layers.<!?tpb=18pt>

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