Synthesis and crystal structure of [Pd{C6H4(CH2NHCH2Ph)-2-κ2C,N}(μ-I)]2
2017 ◽
Vol 73
(11)
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pp. 1612-1615
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Type C
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The binuclear title complex, di-μ-iodido-bis({2-[(benzylamino-κN)methyl]phenyl-κC1}palladium(II)), [Pd2I2(C14H14N)2], was prepared by reaction of [Pd{C6H4(CH2NHCH2Ph)-2}(μ-OAc)]2with NaI. It crystallizes with one discrete molecule in the asymmetric unit. The molecule presents an iodide-bridged dimeric structure with acisoidarrangement with respect to theC,N-cyclopalladated ligands. Both PdIIatoms have a slightly distorted square-planar coordination environment. Weak intermolecular contacts of the type C—H...Pd seem to have a significant influence on the arrangement of the molecules along thebaxis in the crystal.
2014 ◽
Vol 70
(10)
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pp. 252-255
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2015 ◽
Vol 71
(4)
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pp. 350-353
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2014 ◽
Vol 70
(12)
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pp. m395-m396
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2014 ◽
Vol 70
(7)
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pp. 36-38
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2015 ◽
Vol 71
(11)
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pp. m207-m208
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2015 ◽
Vol 71
(12)
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pp. 1485-1487
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2016 ◽
Vol 72
(5)
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pp. 760-763
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2015 ◽
Vol 71
(6)
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pp. 706-708
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