scholarly journals Crystal structure of bis[bis(4-azaniumylphenyl) sulfone] tetranitrate monohydrate

2017 ◽  
Vol 73 (11) ◽  
pp. 1721-1725 ◽  
Author(s):  
Amani Hind Benahsene ◽  
Lamia Bendjeddou ◽  
Hocine Merazig
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bonding ◽  
Water Molecule ◽  
Three Dimensional ◽  
Dihedral Angles ◽  
Supramolecular Network ◽  
Nitrate Salt ◽  
Hydrogen Bonding Interactions ◽  
Benzene Rings ◽  
Ring Centroid

In the title compound, the hydrated tetra(nitrate) salt of dapsone (4,4′-diaminodiphenylsulfone), 2C12H14N2O2S2+·4NO3−·H2O {alternative name: bis[bis(4,4′-diazaniumylphenyl) sulfone] tetranitrate monohydrate}, the cations are conformationally similar, with comparable dihedral angles between the two benzene rings in each of 70.03 (18) and 69.69 (19)°. In the crystal, mixed cation–anion–water molecule layers lying parallel to the (001) plane are formed through N—H...O, O—H...O and C—H...O hydrogen-bonding interactions and these layers are further extended into an overall three-dimensional supramolecular network structure. Inter-ring π–π interactions are also present [minimum ring centroid separation = 3.693 (3) Å].

scholarly journals Crystal structure of ethyl 2-phenyl-9-phenylsulfonyl-9H-carbazole-3-carboxylate

2015 ◽  
Vol 71 (10) ◽  
pp. o725-o726
Author(s):  
M. Umadevi ◽  
P. Raju ◽  
R. Yamuna ◽  
A. K. Mohanakrishnan ◽  
G. Chakkaravarthi
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bonds ◽  
Three Dimensional ◽  
Ester Group ◽  
Ring System ◽  
Side Chain ◽  
Dihedral Angles ◽  
Supramolecular Network ◽  
Compound C ◽  
Benzene Rings

In the title compound, C27H21NO4S, the dihedral angles between the carbazole ring system (r.m.s. deviation = 0.015 Å) and the sulfur-bonded and directly linked benzene rings are 79.98 (11) and 53.51 (18)°, respectively. The benzene rings subtend a dihedral angle of 48.4 (2)°. The ethyl side chain of the ester group has an extended conformation [C—O—C—C = −172.3 (3)°]. In the crystal, inversion dimers linked by pairs of weak C—H...O hydrogen bonds generateR22(22) loops. The dimers are linked by weak C—H...π and π–π [centroid-to-centroid distances ranging from 3.5042 (14) to 3.888 (2) Å] interactions, thereby forming a three-dimensional supramolecular network.

scholarly journals Crystal structure of NH4[La(SO4)2(H2O)]

2015 ◽  
Vol 71 (6) ◽  
pp. 663-666 ◽  
Author(s):  
Meriem Benslimane ◽  
Yasmine Kheira Redjel ◽  
Hocine Merazig ◽  
Jean-Claude Daran
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bonding ◽  
Water Molecule ◽  
Three Dimensional ◽  
Sulfate Anion ◽  
Hydrogen Bonding Interactions ◽  
Trigonal Prisms ◽  
Hydrogen Bonded

The principal building units in the crystal structure of ammonium aquabis(sulfato)lanthanate(III) are slightly distorted SO4tetrahedra, LaO9polyhedra in the form of distorted tricapped trigonal prisms, and NH4+ions. The La3+cation is coordinated by eight O atoms from six different sulfate tetrahedra, two of which are bidentate coordinating and four monodentate, as well as one O atom from a water molecule; each sulfate anion bridges three La3+cations. These bridging modes result in the formation of a three-dimensional anionic [La(SO4)2(H2O)]−framework that is stabilized by O—H...O hydrogen-bonding interactions. The disordered ammonium cations are situated in the cavities of this framework and are hydrogen-bonded to six surrounding O atoms.

scholarly journals Crystal structure of (4-chlorophenyl)[2-(10-hydroxyphenanthren-9-yl)phenanthro[9,10-b]furan-3-yl]methanone

2014 ◽  
Vol 70 (11) ◽  
pp. 355-358
Author(s):  
L. U. Sajitha ◽  
M. Sithambaresan ◽  
Jomon P. Jacob ◽  
M. R. Prathapachandra Kurup
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bonding ◽  
Dihedral Angle ◽  
Three Dimensional ◽  
Dihedral Angles ◽  
Supramolecular Architecture ◽  
Intermolecular Hydrogen Bonding ◽  
Compound C ◽  
Hydrogen Bonding Interactions ◽  
Donor Acceptor

In the title compound, C37H21ClO3, the dihedral angle between the two phenanthrene moieties is 57.79 (5)°. The furan and one of the phenanthrene groups are fused in an almost coplanar arrangement [dihedral angle = 5.14 (8)°] and the furan unit makes dihedral angles of 70.27 (11) and 57.58 (8)° with the planes of the phenyl and the second phenanthrene group, respectively. In the crystal, neighbouring molecules are connectedviatwo intermolecular hydrogen-bonding interactions (O—H...O and C—H...O) towards the carbonyl O atom with donor–acceptor distances of 2.824 (2) and 3.277 (3) Å, creating an inversion dimer. A non-classical C—H...Cl interaction [3.564 (2) Å] and three C—H...π interactions, with C...π distances of 3.709 (3), 3.745 (2) and 3.628 (3) Å, connect the molecules, forming a three-dimensional supramolecular architecture in the solid state.

scholarly journals Crystal structure of the lead-containing organic–inorganic hybrid: (C18H26N2)3[Pb4I14(DMSO)2]·2DMSO

2018 ◽  
Vol 74 (12) ◽  
pp. 1878-1880 ◽  
Author(s):  
Li Li ◽  
Dan Zhao ◽  
Zhi Liu ◽  
Dingchao Zhang ◽  
Zhenhao Hu ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bonding ◽  
Dimethyl Sulfoxide ◽  
Hybrid Materials ◽  
Three Dimensional ◽  
Supramolecular Network ◽  
Inorganic Hybrid ◽  
Compound C ◽  
Hydrogen Bonding Interactions ◽  
Short Contacts

The title compound, tris(1,1′-dibutyl-4,4′-bipyridine-1,1′-diium) bis(dimethyl sulfoxide)di-μ3-iodido-tetra-μ2-iodido-octaiodidotetralead(II) dimethyl sulfoxide disolvate, (C18H26N2)3[Pb4I14(C2H6OS)2]·2C2H6OS, belongs to a class of organic–inorganic hybrid materials with novel functionalities. In this compound, C—H...O and C—H...I hydrogen-bonding interactions, π–π interactions, other short contacts and Pb octahedral chains are present, extending the crystal structure into a three-dimensional supramolecular network.

scholarly journals Crystal structure of 1,4,8,11-tetraazoniacyclotetradecane bis(dichromate) monohydrate from synchrotron data

2017 ◽  
Vol 73 (5) ◽  
pp. 755-758
Author(s):  
Dohyun Moon ◽  
Jong-Ha Choi
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bonding ◽  
Water Molecule ◽  
Three Dimensional ◽  
Inversion Symmetry ◽  
Asymmetric Unit ◽  
Intermolecular Hydrogen Bonds ◽  
Hydrogen Bonding Interactions ◽  
Dimensional Network ◽  
Dichromate Anions

The asymmetric unit of the hydrated title salt, (C10H28N4)[Cr2O7]2·H2O [C10H28N4= H4(cyclam) = 1,4,8,11-tetraazoniacyclotetradecane], contains two half-cations (both completed by crystallographic inversion symmetry), two dichromate anions and one water molecule. The two [CrO7]2−anions exhibit a nearly staggered conformation, with bridging angles of 133.37 (11) and 136.28 (12)°. The distortions of the dichromate anions are due to their participation in hydrogen-bonding interactions with the water molecule and the cations. Intermolecular hydrogen bonds involving the cyclam N—H groups and water O—H groups as donor groups, and the O atoms of the dichromate anions as acceptor groups give rise to a three-dimensional network.

scholarly journals Acetonyltriphenylphosphonium 2,3,5-triphenyltetrazolium tetrachloridocuprate(II)

2018 ◽  
Vol 74 (1) ◽  
pp. 69-71 ◽  
Author(s):  
Mouhamadou Birame Diop ◽  
Libasse Diop ◽  
Allen G. Oliver
Keyword(s):  
Hydrogen Bonding ◽  
Title Compound ◽  
Three Dimensional ◽  
Dihedral Angles ◽  
Triphenyltetrazolium Chloride ◽  
Tetrahedral Geometry ◽  
Distorted Tetrahedral Geometry ◽  
Compound C ◽  
Hydrogen Bonding Interactions ◽  
Benzene Rings

The title compound, (C21H20OP)(C19H15N4)[CuCl4], was obtained by reacting CuCl2·2H2O with a mixture of one equivalent of acetonyltriphenylphosphonium chloride and one equivalent of 2,3,5-triphenyltetrazolium chloride in acetonitrile. In the structure, the Cu centre in the dianion is bonded to four chloride ligands and adopts a distorted tetrahedral geometry. The phosphonium cation likewise adopts the expected tetrahedral geometry. The tetrazolium ring forms dihedral angles of 77.68 (10), 26.85 (11) and 66.48 (10)° with the planes of the benzene rings of the substituent groups. In the crystal, weak C—H...Cl hydrogen-bonding interactions involving both cations and the anion give rise to a three-dimensional supramolecular structure.

scholarly journals Crystal structures and hydrogen bonding in the proton-transfer salts of nicotine with 3,5-dinitrosalicylic acid and 5-sulfosalicylic acid

2014 ◽  
Vol 70 (11) ◽  
pp. 430-434 ◽  
Author(s):  
Graham Smith ◽  
Urs D. Wermuth
Keyword(s):  
Hydrogen Bonding ◽  
Hydrogen Bonds ◽  
Three Dimensional ◽  
Ring System ◽  
Dimensional Structure ◽  
Sulfosalicylic Acid ◽  
Three Dimensional Structure ◽  
Hydrogen Bonding Interactions ◽  
Benzene Rings ◽  
Ring Centroid

The structures of the 1:1 anhydrous salts of nicotine (NIC) with 3,5-dinitrosalicylic acid (DNSA) and 5-sulfosalicylic acid (5-SSA), namely (1R,2S)-1-methyl-2-(pyridin-3-yl)-1H-pyrrolidin-1-ium 2-carboxy-4,6-dinitrophenolate, C10H15N2+·C7H3N2O7−, (I), and (1R,2S)-1-methyl-2-(pyridin-3-yl)-1H-pyrrolidin-1-ium 3-carboxy-4-hydroxybenzenesulfonate, C10H15N2+·C7H5O6S−, (II), are reported. The asymmetric units of both (I) and (II) comprise two independent nicotinium cations (CandD) and either two DNSA or two 5-SSA anions (AandB), respectively. One of the DNSA anions shows a 25% rotational disorder in the benzene ring system. In the crystal of (I), inter-unit pyrrolidinium N—H...Npyridinehydrogen bonds generate zigzag NIC cation chains which extend alonga, while the DNSA anions are not involved in any formal inter-species hydrogen bonding but instead form π–π-associated stacks which are parallel to the NIC cation chains alonga[ring-centroid separation = 3.857 (2) Å]. Weak C—H...O interactions between chain substructures give an overall three-dimensional structure. In the crystal of (II),AandBanions form independent zigzag chains withCandDcations, respectively, through carboxylic acid O—H...Npyridinehydrogen bonds. These chains, which extend alongb, are pseudocentrosymmetrically related and give π–π interactions between the benzene rings of anionsAandBand the pyridine rings of the NIC cationsCandD, respectively [ring centroid separations = 3.6422 (19) and 3.7117 (19) Å]. Also present are weak C—H...O hydrogen-bonding interactions between the chains, giving an overall three-dimensional structure.

N-(4-Bromobenzyl)-4-cyanopyridinium bis(2-thioxo-1,3-dithiole-4,5-dithiolato)nickelate(III) acetone solvate

2006 ◽  
Vol 62 (5) ◽  
pp. m1004-m1005 ◽  
Author(s):  
Shuang-Quan Zang ◽  
Yang Su ◽  
Ruo-Jie Tao
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bonding ◽  
Title Compound ◽  
Three Dimensional ◽  
Supramolecular Network ◽  
Ionic Complex ◽  
Compound C ◽  
Hydrogen Bonding Interactions ◽  
Square Planar

The title compound, (C13H10BrN2)[Ni(C3S5)2]·C3H6O, is a new ionic complex in which the NiIII atom exhibits a square-planar coordination involving four S atoms from two 2-thioxo-1,3-dithiole-4,5-dithiolate (dmit) ligands. In the crystal structure, weak S...S and hydrogen-bonding interactions form a three-dimensional supramolecular network.

Metal complexes with chloride and triazole-based ligands: investigation of a well-resolved up–up–down–down (uudd) cyclic water tetramer andX—H...Cl (X= O and C) hydrogen-bonding interactions

2012 ◽  
Vol 68 (12) ◽  
pp. m344-m346 ◽  
Author(s):  
Jian-Hua Guo
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bonding ◽  
Hydrogen Bonds ◽  
Equatorial Plane ◽  
Three Dimensional ◽  
Title Complex ◽  
Supramolecular Network ◽  
Inversion Symmetry ◽  
Hydrogen Bonding Interactions ◽  
Cobalt Compounds

The crystal structure of the title complex,trans-dichloridotetrakis[1-phenyl-3-(1H-1,2,4-triazol-1-yl-κN4)propan-1-one]copper(II) hexahydrate, [CuCl2(C11H11N3O)4]·6H2O, is isomorphous with that of the corresponding nickel and cobalt compounds. The complex has crystallographic inversion symmetry with the CuIIatom on an inversion centre. Each CuIIatom is six-coordinated by one N atom from each of the four 1-phenyl-3-(1H-1,2,4-triazol-1-yl)propan-1-one ligands in the equatorial plane and by two chloride ligands in axial positions. The structure includes a centrosymmetric irregular up–up–down–down (uudd) water tetramer cluster and O—H...Cl hydrogen bonds. Intermolecular C—H...Cl hydrogen bonds exist between adjacent molecules, resulting in a three-dimensional supramolecular network.

scholarly journals Crystal structure of di-μ-iodido-bis[(dimethyl sulfoxide-κO)(triphenylphosphane-κP)copper(I)]

2014 ◽  
Vol 70 (12) ◽  
pp. 547-549
Author(s):  
Rodolphe Kinghat ◽  
Michael Knorr ◽  
Yoann Rousselin ◽  
Marek M. Kubicki
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bonding ◽  
Dimethyl Sulfoxide ◽  
Title Compound ◽  
Van Der Waals ◽  
Three Dimensional ◽  
Supramolecular Network ◽  
Hydrogen Bonding Interactions ◽  
Van Der Waals Radii

The centrosymmetric dinuclear title compound, [Cu2I2(C2H6OS)2(C18H15P)2], represents the first example of a CuI complex ligated by anO-bound dimethyl sulfoxide ligand. In the crystal, the two tetrahedrally coordinated CuIatoms are bridged by two μ2-iodido ligands in an almost symmetrical rhomboid geometry. The loose Cu...Cu contact of 2.9874 (8) Å is longer than the sum of the van der Waals radii of two Cu atoms (2.8 Å), excluding a significant cupriophilic interaction in the actual dimer. C—H...O and C—H...I hydrogen bonding interactions as well as C—H...π(aryl) interactions stabilize the three-dimensional supramolecular network.

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