Crystal structure of di-μ-iodido-bis[(dimethyl sulfoxide-κO)(triphenylphosphane-κP)copper(I)]
2014 ◽
Vol 70
(12)
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pp. 547-549
Keyword(s):
The centrosymmetric dinuclear title compound, [Cu2I2(C2H6OS)2(C18H15P)2], represents the first example of a CuI complex ligated by anO-bound dimethyl sulfoxide ligand. In the crystal, the two tetrahedrally coordinated CuIatoms are bridged by two μ2-iodido ligands in an almost symmetrical rhomboid geometry. The loose Cu...Cu contact of 2.9874 (8) Å is longer than the sum of the van der Waals radii of two Cu atoms (2.8 Å), excluding a significant cupriophilic interaction in the actual dimer. C—H...O and C—H...I hydrogen bonding interactions as well as C—H...π(aryl) interactions stabilize the three-dimensional supramolecular network.
2015 ◽
Vol 71
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pp. 1219-1221
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2018 ◽
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pp. 1878-1880
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2006 ◽
Vol 62
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pp. m1004-m1005
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2006 ◽
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pp. m796-m798
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2007 ◽
Vol 63
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pp. m761-m763
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2017 ◽
Vol 73
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pp. 1279-1281
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2017 ◽
Vol 73
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pp. 1712-1715
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2015 ◽
Vol 71
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pp. 136-139
2017 ◽
Vol 73
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pp. 1721-1725
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2015 ◽
Vol 71
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pp. 1493-1496
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