scholarly journals Crystal structure of the lead-containing organic–inorganic hybrid: (C18H26N2)3[Pb4I14(DMSO)2]·2DMSO

2018 ◽  
Vol 74 (12) ◽  
pp. 1878-1880 ◽  
Author(s):  
Li Li ◽  
Dan Zhao ◽  
Zhi Liu ◽  
Dingchao Zhang ◽  
Zhenhao Hu ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bonding ◽  
Dimethyl Sulfoxide ◽  
Hybrid Materials ◽  
Three Dimensional ◽  
Supramolecular Network ◽  
Inorganic Hybrid ◽  
Compound C ◽  
Hydrogen Bonding Interactions ◽  
Short Contacts

The title compound, tris(1,1′-dibutyl-4,4′-bipyridine-1,1′-diium) bis(dimethyl sulfoxide)di-μ3-iodido-tetra-μ2-iodido-octaiodidotetralead(II) dimethyl sulfoxide disolvate, (C18H26N2)3[Pb4I14(C2H6OS)2]·2C2H6OS, belongs to a class of organic–inorganic hybrid materials with novel functionalities. In this compound, C—H...O and C—H...I hydrogen-bonding interactions, π–π interactions, other short contacts and Pb octahedral chains are present, extending the crystal structure into a three-dimensional supramolecular network.

N-(4-Bromobenzyl)-4-cyanopyridinium bis(2-thioxo-1,3-dithiole-4,5-dithiolato)nickelate(III) acetone solvate

2006 ◽  
Vol 62 (5) ◽  
pp. m1004-m1005 ◽  
Author(s):  
Shuang-Quan Zang ◽  
Yang Su ◽  
Ruo-Jie Tao
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bonding ◽  
Title Compound ◽  
Three Dimensional ◽  
Supramolecular Network ◽  
Ionic Complex ◽  
Compound C ◽  
Hydrogen Bonding Interactions ◽  
Square Planar

The title compound, (C13H10BrN2)[Ni(C3S5)2]·C3H6O, is a new ionic complex in which the NiIII atom exhibits a square-planar coordination involving four S atoms from two 2-thioxo-1,3-dithiole-4,5-dithiolate (dmit) ligands. In the crystal structure, weak S...S and hydrogen-bonding interactions form a three-dimensional supramolecular network.

scholarly journals Crystal structure of di-μ-iodido-bis[(dimethyl sulfoxide-κO)(triphenylphosphane-κP)copper(I)]

2014 ◽  
Vol 70 (12) ◽  
pp. 547-549
Author(s):  
Rodolphe Kinghat ◽  
Michael Knorr ◽  
Yoann Rousselin ◽  
Marek M. Kubicki
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bonding ◽  
Dimethyl Sulfoxide ◽  
Title Compound ◽  
Van Der Waals ◽  
Three Dimensional ◽  
Supramolecular Network ◽  
Hydrogen Bonding Interactions ◽  
Van Der Waals Radii

The centrosymmetric dinuclear title compound, [Cu2I2(C2H6OS)2(C18H15P)2], represents the first example of a CuI complex ligated by anO-bound dimethyl sulfoxide ligand. In the crystal, the two tetrahedrally coordinated CuIatoms are bridged by two μ2-iodido ligands in an almost symmetrical rhomboid geometry. The loose Cu...Cu contact of 2.9874 (8) Å is longer than the sum of the van der Waals radii of two Cu atoms (2.8 Å), excluding a significant cupriophilic interaction in the actual dimer. C—H...O and C—H...I hydrogen bonding interactions as well as C—H...π(aryl) interactions stabilize the three-dimensional supramolecular network.

scholarly journals Crystal structure and Hirshfeld surface analysis of 4-{[(anthracen-9-yl)methyl]amino}benzoic acid dimethylformamide monosolvate

2020 ◽  
Vol 76 (5) ◽  
pp. 728-731
Author(s):  
Adeeba Ahmed ◽  
Aiman Ahmad ◽  
Musheer Ahmad ◽  
Valentina A. Kalibabchuk
Keyword(s):  
Crystal Structure ◽  
Surface Analysis ◽  
Three Dimensional ◽  
Hirshfeld Surface ◽  
Hirshfeld Surface Analysis ◽  
Supramolecular Network ◽  
Compound C ◽  
Hydrogen Bonding Interactions ◽  
The Mean ◽  
Dimethylformamide Solution

The title compound, C22H17NO2·C3H7NO, was synthesized by condensation of an aromatic aldehyde with a secondary amine and subsequent reduction. It was crystallized from a dimethylformamide solution as a monosolvate, C22H17NO2·C3H7NO. The aromatic molecule is non-planar with a dihedral angle between the mean planes of the aniline moiety and the methyl anthracene moiety of 81.36 (8)°. The torsion angle of the Caryl—CH2—NH—Caryl backbone is 175.9 (2)°. The crystal structure exhibits a three-dimensional supramolecular network, resulting from hydrogen-bonding interactions between the carboxylic OH group and the solvent O atom as well as between the amine functionality and the O atom of the carboxylic group and additional C—H...π interactions. Hirshfeld surface analysis was performed to quantify the intermolecular interactions.

scholarly journals (Z)-2-(5-Chloro-2-oxoindolin-3-ylidene)-N-methylhydrazinecarbothioamide

2012 ◽  
Vol 68 (4) ◽  
pp. o964-o965 ◽  
Author(s):  
Amna Qasem Ali ◽  
Naser Eltaher Eltayeb ◽  
Siang Guan Teoh ◽  
Abdussalam Salhin ◽  
Hoong-Kun Fun
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bonding ◽  
Three Dimensional ◽  
Hydrogen Bonding Interaction ◽  
Compound C ◽  
Hydrogen Bonding Interactions ◽  
Dimensional Network ◽  
Bonding Interaction ◽  
A Chain ◽  
Graph Sets

In the title compound, C10H9ClN4OS, an intramolecular N—H...O hydrogen-bonding interaction and an N—H...N interaction generate ring motifs [graph setsS(6) andS(5), respectively]. In the crystal, molecules form a chain through N—H...O hydrogen bonds, and these are extended by N—H...S hydrogen-bonding interactions into an infinite three-dimensional network. The crystal structure also exhibits weak C—H...π interactions.

scholarly journals Crystal structure of bis[bis(4-azaniumylphenyl) sulfone] tetranitrate monohydrate

2017 ◽  
Vol 73 (11) ◽  
pp. 1721-1725 ◽  
Author(s):  
Amani Hind Benahsene ◽  
Lamia Bendjeddou ◽  
Hocine Merazig
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bonding ◽  
Water Molecule ◽  
Three Dimensional ◽  
Dihedral Angles ◽  
Supramolecular Network ◽  
Nitrate Salt ◽  
Hydrogen Bonding Interactions ◽  
Benzene Rings ◽  
Ring Centroid

In the title compound, the hydrated tetra(nitrate) salt of dapsone (4,4′-diaminodiphenylsulfone), 2C12H14N2O2S2+·4NO3−·H2O {alternative name: bis[bis(4,4′-diazaniumylphenyl) sulfone] tetranitrate monohydrate}, the cations are conformationally similar, with comparable dihedral angles between the two benzene rings in each of 70.03 (18) and 69.69 (19)°. In the crystal, mixed cation–anion–water molecule layers lying parallel to the (001) plane are formed through N—H...O, O—H...O and C—H...O hydrogen-bonding interactions and these layers are further extended into an overall three-dimensional supramolecular network structure. Inter-ring π–π interactions are also present [minimum ring centroid separation = 3.693 (3) Å].

scholarly journals Crystal structure of (4-chlorophenyl)[2-(10-hydroxyphenanthren-9-yl)phenanthro[9,10-b]furan-3-yl]methanone

2014 ◽  
Vol 70 (11) ◽  
pp. 355-358
Author(s):  
L. U. Sajitha ◽  
M. Sithambaresan ◽  
Jomon P. Jacob ◽  
M. R. Prathapachandra Kurup
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bonding ◽  
Dihedral Angle ◽  
Three Dimensional ◽  
Dihedral Angles ◽  
Supramolecular Architecture ◽  
Intermolecular Hydrogen Bonding ◽  
Compound C ◽  
Hydrogen Bonding Interactions ◽  
Donor Acceptor

In the title compound, C37H21ClO3, the dihedral angle between the two phenanthrene moieties is 57.79 (5)°. The furan and one of the phenanthrene groups are fused in an almost coplanar arrangement [dihedral angle = 5.14 (8)°] and the furan unit makes dihedral angles of 70.27 (11) and 57.58 (8)° with the planes of the phenyl and the second phenanthrene group, respectively. In the crystal, neighbouring molecules are connectedviatwo intermolecular hydrogen-bonding interactions (O—H...O and C—H...O) towards the carbonyl O atom with donor–acceptor distances of 2.824 (2) and 3.277 (3) Å, creating an inversion dimer. A non-classical C—H...Cl interaction [3.564 (2) Å] and three C—H...π interactions, with C...π distances of 3.709 (3), 3.745 (2) and 3.628 (3) Å, connect the molecules, forming a three-dimensional supramolecular architecture in the solid state.

scholarly journals Crystal structure of di-μ-isobutyrato-κ4O:O′-bis[cis-dichlorido(dimethyl sulfoxide-κS)rhenium(III)]

2015 ◽  
Vol 71 (10) ◽  
pp. 1219-1221 ◽  
Author(s):  
Alexander A. Golichenko ◽  
Alexander V. Shtemenko
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bonding ◽  
Dimethyl Sulfoxide ◽  
Title Compound ◽  
Binuclear Complex ◽  
Three Dimensional ◽  
Chloride Ions ◽  
Complex Molecules ◽  
Hydrogen Bonding Interactions

The title compound, [Re2(C3H7COO)2Cl4{(CH3)2SO}2], comprises binuclear complex molecules [Re—Re = 2.24502 (13) Å] involvingcis-oriented double carboxylate bridges, four equatorial chloride ions and two weakly bonded O atoms from dimethyl sulfoxide ligands in the axial positions at the ReIIIatoms. In the crystal, molecules are linked into corrugated layers parallel to (101) by very weak C—H...Cl and C—H...O hydrogen-bonding interactions. C—H...Cl hydrogen bonding provides the links between layers to consolidate a three-dimensional framework.

[(1H-Benzimidazol-2-ylmethyl)iminodimethylene]diphosphonic acid dihydrate

2006 ◽  
Vol 62 (7) ◽  
pp. o2694-o2696
Author(s):  
Jian-Wei Tong ◽  
Li-Fang Ma ◽  
Deng-Ke Cao ◽  
Yi-Zhi Li ◽  
Li-Min Zheng
Keyword(s):  
Hydrogen Bonding ◽  
Phosphonic Acid ◽  
Three Dimensional ◽  
Supramolecular Network ◽  
Stacking Interactions ◽  
Diphosphonic Acid ◽  
Compound C ◽  
Hydrogen Bonding Interactions ◽  
Phosphonic Acid Groups ◽  
Benzimidazole Group

The title compound, C9H15O6N3P2·2H2O, contains two phosphonic acid groups and one benzimidazole group connected by an N(CH2–)3 group. One of the benzimidazole N atoms and two phosphonic acid O atoms of each PO3 group are protonated. Extensive hydrogen-bonding interactions, as well as π–π stacking interactions, are found between the molecules, leading to a three-dimensional supramolecular network structure.

Metal complexes with chloride and triazole-based ligands: investigation of a well-resolved up–up–down–down (uudd) cyclic water tetramer andX—H...Cl (X= O and C) hydrogen-bonding interactions

2012 ◽  
Vol 68 (12) ◽  
pp. m344-m346 ◽  
Author(s):  
Jian-Hua Guo
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bonding ◽  
Hydrogen Bonds ◽  
Equatorial Plane ◽  
Three Dimensional ◽  
Title Complex ◽  
Supramolecular Network ◽  
Inversion Symmetry ◽  
Hydrogen Bonding Interactions ◽  
Cobalt Compounds

The crystal structure of the title complex,trans-dichloridotetrakis[1-phenyl-3-(1H-1,2,4-triazol-1-yl-κN4)propan-1-one]copper(II) hexahydrate, [CuCl2(C11H11N3O)4]·6H2O, is isomorphous with that of the corresponding nickel and cobalt compounds. The complex has crystallographic inversion symmetry with the CuIIatom on an inversion centre. Each CuIIatom is six-coordinated by one N atom from each of the four 1-phenyl-3-(1H-1,2,4-triazol-1-yl)propan-1-one ligands in the equatorial plane and by two chloride ligands in axial positions. The structure includes a centrosymmetric irregular up–up–down–down (uudd) water tetramer cluster and O—H...Cl hydrogen bonds. Intermolecular C—H...Cl hydrogen bonds exist between adjacent molecules, resulting in a three-dimensional supramolecular network.

Hexaaquamagnesium(II) 2-methyl-5-nitrobenzenesulfonate dihydrate

2007 ◽  
Vol 63 (3) ◽  
pp. m812-m814 ◽  
Author(s):  
Yong-Rong Xie ◽  
Gen-Wu Ge ◽  
Xiao-Yong Yuan ◽  
Dong-Bei Wan ◽  
Rui-Qing Yang
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bonding ◽  
Three Dimensional ◽  
Title Complex ◽  
Complex Pattern ◽  
Water Molecules ◽  
Supramolecular Network ◽  
Inversion Center ◽  
Hydrogen Bonding Interactions

In the title complex, [Mg(H2O)6](C7H6NO5)2·2H2O, the MgII cation lies on an inversion center and is octahedrally coordinated by six water molecules. The 2-methyl-5-nitrobenzenesulfonate anions do not coordinate to the magnesium, but act as counter-anions. The crystal structure is composed of alternating layers of [Mg(H2O)6]2+ cations and anions. The [Mg(H2O)6]2+ cations, water molecules and anions are connected through a complex pattern of hydrogen-bonding interactions, resulting in a three-dimensional supramolecular network.

Sign in / Sign up

Export Citation Format

Share Document