scholarly journals Di-μ-aqua-bis[aqua(2,2′-bipyridine)(4-nitrobenzoato)cobalt(II)] bis(4-nitrobenzoate)

IUCrData ◽  
2020 ◽  
Vol 5 (6) ◽  
Author(s):  
Bikshandarkoil R. Srinivasan ◽  
Sarvesh S. Harmalkar ◽  
Luann R. D'Souza ◽  
Sunder N. Dhuri
Keyword(s):  
Hydrogen Bonds ◽  
Title Compound ◽  
Octahedral Coordination ◽  
Bimetallic Complex ◽  
Coordination Environment

The title compound, [Co2(C7H4NO4)2(C10H8N2)2(H2O)4](C7H4NO4)2, consists of a centrosymmetric bimetallic complex charge-balanced by free 4-nitrobenzoate anions. The CoII ion exhibits a distorted cis-CoN2O4 octahedral coordination environment and the Co...Co separation is 3.326 (2) Å. In the crystal, the dications and anions are linked by O—H...O and C—H...O hydrogen bonds.

scholarly journals Bis[tris(propane-1,3-diamine-κ2N,N′)nickel(II)] diaquabis(propane-1,3-diamine-κ2N,N′)nickel(II) hexabromide dihydrate

2014 ◽  
Vol 70 (6) ◽  
pp. m227-m228 ◽  
Author(s):  
Aymen Yangui ◽  
Walid Rekik ◽  
Slim Elleuch ◽  
Younes Abid
Keyword(s):  
Hydrogen Bonds ◽  
Title Compound ◽  
General Position ◽  
Three Dimensional ◽  
The Other ◽  
Octahedral Coordination ◽  
Water Molecules ◽  
Coordination Environment ◽  
Lattice Water ◽  
Dimensional Network

In the title compound, [Ni(C3H10N2)3]2[Ni(C3H10N2)2(H2O)2]Br6·2H2O, one Ni2+cation, located on an inversion centre, is coordinated by four N atoms from two ligands and by two water O atoms. The other Ni2+cation, located in a general position, is coordinated by six N atoms from three ligands. In both cases, the Ni2+cation has an octahedral coordination environment. The overall structural cohesion is ensured by three types of hydrogen bonds, N—H...Br, O—H...Br and O—H...O, which connect the two types of complex cations, the bromide counter-anions and the lattice water molecules into a three-dimensional network.

scholarly journals cis-Bromidobis(ethylene-1,2-diamine)(2-methylpropan-1-amine)cobalt(III) dibromide

IUCrData ◽  
2018 ◽  
Vol 3 (9) ◽  
Author(s):  
M. Manjunathan ◽  
K. Anbalagan ◽  
K. Sambathkumar ◽  
E. Govindan
Keyword(s):  
Hydrogen Bonds ◽  
Equatorial Plane ◽  
Title Compound ◽  
Complex Cation ◽  
Octahedral Coordination ◽  
Supramolecular Framework ◽  
Coordination Environment ◽  
Distorted Octahedral Coordination ◽  
Distorted Octahedral ◽  
Distorted Octahedral Coordination Environment

In the title compound, [CoBr(C2H8N2)2(C4H11N)]Br2, the cobalt(III) ion has a distorted octahedral coordination environment and is ligated by three N atoms and a bromine ion in the equatorial plane, and by two N atoms occupying the axial positions. In the crystal, the complex cation and the two Br− counter-anions are linked by N—H...Br hydrogen bonds, forming a supramolecular framework.

scholarly journals Crystal structure ofcatena-poly[[bis(acetato-κO)copper(II)]-bis[μ-4-(1H-imidazol-1-yl)phenol]-κ2N3:O;κ2O:N3]

2017 ◽  
Vol 73 (2) ◽  
pp. 209-212
Author(s):  
Mehmet Poyraz ◽  
Musa Sarı
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bonds ◽  
Title Compound ◽  
Octahedral Coordination ◽  
Stacking Interactions ◽  
Coordination Environment ◽  
Heterocyclic Ligand ◽  
Distorted Octahedral Coordination ◽  
Distorted Octahedral ◽  
Distorted Octahedral Coordination Environment

In the title compound, [Cu(CH3COO)2(C9H8N2O)2]n, the CuIIion resides on a centre of inversion, displaying a tetragonally distorted octahedral coordination environment defined by two pairs of N and O atoms of symmetry-related 4-(1H-imidazol-1-yl)phenol ligands and the O atoms of two symmetry-related acetate ligands. The bridging mode of the 4-(1H-imidazol-1-yl)phenol ligands is associated with a very long Cu...O interactions involving the phenol O atom of the heterocyclic ligand, which creates chains extending parallel to [100]. In the crystal, the chains are arranged in a distorted hexagonal rod packing and are linkedviaC—H...O hydrogen bonds and by π–π stacking interactions involving centrosymmetrically related pairs of imidazole and phenol rings.

scholarly journals cis-Bromidobis(ethylene-1,2-diamine)(methylamine)cobalt(III) dibromide

IUCrData ◽  
2018 ◽  
Vol 3 (6) ◽  
Author(s):  
S. Manimaran ◽  
E. Govindan ◽  
M. Manjunathan ◽  
K. Sambathkumar ◽  
K. Anbalagan
Keyword(s):  
Hydrogen Bonds ◽  
Equatorial Plane ◽  
Title Compound ◽  
Complex Cation ◽  
Octahedral Coordination ◽  
Supramolecular Framework ◽  
Coordination Environment ◽  
Distorted Octahedral Coordination ◽  
Distorted Octahedral ◽  
Distorted Octahedral Coordination Environment

In the title compound, [CoBr(CH5N)(C2H8N2)2]Br2, the cobalt(III) ion has a distorted octahedral coordination environment and is ligated by four N atoms in the equatorial plane, with an additional N atom and a Br− ion occupying the axial positions. In the crystal, the complex cation and the two counter-anions are linked via N—H...Br and C—H...Br hydrogen bonds, forming a supramolecular framework.

scholarly journals Bis(ethanol-κO)bis(1-ferrocenyl-4,4,4-trifluorobutane-1,3-dionato-κ2 O,O′)nickel(II)

IUCrData ◽  
2021 ◽  
Vol 6 (7) ◽  
Author(s):  
Wenqing Su ◽  
Tianyue Fu ◽  
Zhongwei Xu
Keyword(s):  
Hydrogen Bonds ◽  
Title Compound ◽  
Octahedral Coordination ◽  
Intermolecular Hydrogen Bonds ◽  
Coordination Environment

In the title compound, [NiFe2(C5H5)(C9H5F3O2)2(C2H6O)2], the central NiII ion is observed in an octahedral coordination environment. The chelating β-diketonate ligands are substituted by ferrocene, a lipophilic organometallic moiety. The ferrocene groups have the normal geometry, with eclipsed cyclopentadiene rings. Coordinated ethanol molecules are engaged in intermolecular hydrogen bonds, and the crystal is further stabilized by weak C—H...F and C—H...π contacts.

scholarly journals Bis{N-[2-hydroxy-1,1-bis(hydroxymethyl)ethyl]glycinato-κ3O,N,O′}iron(II)

2014 ◽  
Vol 70 (7) ◽  
pp. m274-m274
Author(s):  
Ning Jiang ◽  
Juan-Juan Hou
Keyword(s):  
Hydrogen Bonds ◽  
Title Compound ◽  
Three Dimensional ◽  
Octahedral Coordination ◽  
Inversion Center ◽  
Coordination Environment ◽  
Distorted Octahedral Coordination ◽  
Dimensional Network ◽  
Distorted Octahedral ◽  
Distorted Octahedral Coordination Environment

In the title compound, [Fe(C6H12NO5)2], the FeIIion lies on an inversion center and is coordinated by two N atoms and four O atoms from two tridentateN-[2-hydroxy-1,1-bis(hydroxymethyl)ethyl]glycine ligands, forming a slightly distorted octahedral coordination environment. In the crystal, O—H...O, O—H...N and weak C—H...O hydrogen bonds link molecules, forming a three-dimensional network.

scholarly journals (Methanol-κO)bis(thiocyanato-κN)[2,4,6-tris(pyridin-2-yl)-1,3,5-triazine-κ3N2,N1,N6]nickel(II) methanol monosolvate

IUCrData ◽  
2019 ◽  
Vol 4 (2) ◽  
Author(s):  
Kwang Ha
Keyword(s):  
Hydrogen Bonds ◽  
Title Compound ◽  
Octahedral Coordination ◽  
Intermolecular Hydrogen Bonds ◽  
Complex Molecules ◽  
Coordination Environment ◽  
Solvent Molecules

In the structure of the title compound, [Ni(NCS)2(C18H12N6)(CH3OH)]·CH3OH, the NiIIion is six-coordinated in an octahedral coordination environment defined by three N atoms from a 2,4,6-tris(pyridin-2-yl)-1,3,5-triazine ligand, two N atoms from two mutuallycis-positioned SCN−anions and one O atom from a methanol ligand. The complex and methanol solvent molecules are linked by intermolecular hydrogen bonds. In the crystal, the complex molecules are stacked in columns parallel to thebaxis.

scholarly journals Crystal structure of bis(azido-κN)bis[2,5-bis(pyridin-2-yl)-1,3,4-thiadiazole-κ2N2,N3]cobalt(II)

2015 ◽  
Vol 71 (5) ◽  
pp. 452-454 ◽  
Author(s):  
Abdelhakim Laachir ◽  
Fouad Bentiss ◽  
Salaheddine Guesmi ◽  
Mohamed Saadi ◽  
Lahcen El Ammari
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bonds ◽  
Title Compound ◽  
Title Complex ◽  
Octahedral Coordination ◽  
Maximum Deviation ◽  
Coordination Geometry ◽  
Acta Cryst ◽  
Π Interactions ◽  
The Mean

In the mononuclear title complex, [Co(N3)2(C12H8N4S)2], the cobalt(II) atom is located on an inversion centre and displays an axially weakly compressed octahedral coordination geometry. The equatorial positions are occupied by the N atoms of two 2,5-bis(pyridin-2-yl)-1,3,4-thiadiazole ligands, whereas the axial positions are occupied by N atoms of the azide anions. The thiadiazole and pyridine rings linked to the metal are almost coplanar, with a maximum deviation from the mean plane of 0.0273 (16) Å. The cohesion of the crystal is ensured by weak C—H...N hydrogen bonds and by π–π interactions between pyridine rings [intercentroid distance = 3.6356 (11) Å], forming a layered arrangement parallel to (001). The structure of the title compound is isotypic with that of the analogous nickel(II) complex [Laachiret al.(2013).Acta Cryst.E69, m351–m352].

scholarly journals trans-Dichloridobis(4-methoxyaniline-κN)palladium(II)

2009 ◽  
Vol 65 (6) ◽  
pp. m673-m673 ◽  
Author(s):  
Volodimir Bon ◽  
Svitlana Orysyk ◽  
Vasyl Pekhnyo
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bonds ◽  
Title Compound ◽  
Planar Geometry ◽  
Coordination Environment ◽  
Square Planar ◽  
A Chain

In the title compound, [PdCl2(C7H9NO)2], the Pd atom is situated on a crystallographic centre of inversion. The coordination environment of the Pd atom shows a slightly distorted square-planar geometry. The crystal structure exhibits weak intermolecular Pd...Cl interactions, with Pd...Cl distances of 3.6912 (6) Å. A chain-like arrangement of molecules realized by intermolecular N—H...Cl hydrogen bonds is observed along [010].

scholarly journals Bis(1-dodecyl-4-aza-1-azoniabicyclo[2.2.2]octane)tetraisothiocyanatocobalt(II)

IUCrData ◽  
2020 ◽  
Vol 5 (1) ◽  
Author(s):  
Niels Ole Giltzau ◽  
Martin Köckerling
Keyword(s):  
Hydrogen Bonding ◽  
Equatorial Plane ◽  
Title Compound ◽  
Unit Cell ◽  
Octahedral Coordination ◽  
Coordination Environment ◽  
Distorted Octahedral Coordination ◽  
Distorted Octahedral ◽  
Triclinic Unit Cell ◽  
Distorted Octahedral Coordination Environment

The title compound, [Co(C18H37N2)2(NCS)4], consists of a cobalt(II) ion positioned on the origin of the triclinic unit cell. It is coordinated by the N atoms of two trans-oriented 1-dodecyl-4-aza-1-azoniabicyclo[2.2.2]octane (DABCO+) cations, which carry n-dodecyl chains at the non-coordinating N atoms. The distorted octahedral coordination environment of the CoII ion is completed through four N atoms of isothiocyanate ions, which are arranged within the equatorial plane. Non-classical hydrogen bonding of the types C—H...N and C—H...S between the filamentous molecules lead to the formation of layers parallel to (001).

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