This paper studies the cluster synchronization of a kind of complex networks by means of impulsive pinning control scheme. These networks are subject to stochastic noise perturbations and Markovian switching, as well as internal and outer time-varying delays. Using the Lyapunov-Krasovskii functional, Itö’s formula, and some linear matrix inequalities (LMI), several novel sufficient conditions are obtained to guarantee the desired cluster synchronization. At the end of this writing, a numerical simulation is given to demonstrate the effectiveness of those theoretical results.