Electrons are known to be efficient in rotationally exciting molecular ions in low-density astrophysical plasmas. Rotational excitation of molecular ions has also been shown to affect the measured values of dissociative recombination (DR) rate coefficients. Thus, electron collisions with
are expected to play a significant role in thermalization and dissociation dynamics of this ion, both in the laboratory and in space. Using the molecular
R
-matrix method combined with the adiabatic-nuclei-rotation approximation, we have computed new rate coefficients for the rotational excitation of
by electrons at temperatures from 10 to 10 000 K. De-excitation rates are found to amount to a few 10
−7
cm
3
s
−1
below 1000 K, i.e. comparable in magnitude to that of DR. In astrophysical environments where the electron fraction exceeds 10
−4
, electron collisions are thus expected to contribute to the non-thermal rotational distribution of
. The competition between electron and neutral collisions is discussed in the context of recent observations of
towards Galactic centre sources.
Rotational excitation of molecular ions in interstellar clouds: HCO+ and HCS+
