Freeway control has been increasingly used as an innovative approach to ease traffic congestion, improve traffic safety and reduce exhaust emissions. As an important predictive model involved in freeway control, the predictive performance of METANET greatly influences the effect of freeway control. This paper focuses on modifying the METANET model by modeling the critical density. Firstly, the critical density model is deduced based on the catastrophe theory. Then, the perturbation wave and traveling wave that are obtained using the macro and micro data, respectively, have been developed to modify the above proposed critical density model. Finally, the numerical simulation is established to evaluate the effectiveness of the modified METANET model based on the field data from the realistic motorway network. The results show that overall, the predicted data from the modified METANET model are closer to the field data than those obtained from the original model.