Power system live working is an important part of power production safety, power system staff training has always been the majority attention of power industry researchers. The 10kV distribution network with high reliability and high security of distribution live working personnel raised taller requirement. In this paper the research and development of 10kV distribution of charged live working simulation training system based on virtual reality technology, it can solve some traditional physical training restrictions, in climate, site, equipment and so on, and has been applied in a number of areas.