DIGITAL SIMULATION OF THE DIFFUSION CURRENT FOR A PARTIALLY BLOCKED ROTATING DISK ELECTRODE

1983 ◽  
Vol 404 (1 Fourth Intern) ◽  
pp. 477-479 ◽  
Author(s):  
Eugéne Levart
1992 ◽  
Vol 46 ◽  
pp. 949-955 ◽  
Author(s):  
Henrik Balslev ◽  
Dieter Britz ◽  
Géza Stájer ◽  
Samuel Frimpong-Manso ◽  
Johan Springborg ◽  
...  

Author(s):  
Milivoj Lovrić

Cyclic staircase voltammograms of a simple, reversible oxidation on the rotating disk electrode is analysed by the digital simulation. It is demonstrated that the peak currents and potentials depend on the single dimensionless variable that considers nonlinear relationship between peak currents and the potential increment. The reverse, cathodic branch of voltammograms depends on this variable differently than the anodic one.


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