Consumer rejection threshold of ethyl phenylacetate and phenylacetic acid, compounds responsible for the sweet-like off odour in wines made from sour rotten grapes

2012 ◽  
Vol 18 (3) ◽  
pp. 280-286 ◽  
Author(s):  
E. CAMPO ◽  
M.P. SAENZ-NAVAJAS ◽  
J. CACHO ◽  
V. FERREIRA
1933 ◽  
Vol 8 (5) ◽  
pp. 447-449 ◽  
Author(s):  
Steward Basterfield ◽  
James W. Tomecko

The ionization constants of p-nitrophenylacetic and phenylmalonic acids have been determined from conductivity data. The value of K for p-nitrophenylacetic acid at 25 °C. is 1.04 × 10−4, about twice that of phenylacetic acid. The nitro group in the nucleus has not as powerful an effect on the ionization when the COOH group is in the side chain as it has when both nitro group and COOH are in the nucleus. K for p-nitrobenzoic acid is six times as great as K for benzoic acid. K for phenylmalonic acid is 2. 77 × 10−3 as compared with 1.6 × 10−3 for malonic acid.


1991 ◽  
Vol 46 (6) ◽  
pp. 783-788 ◽  
Author(s):  
Christian Egger ◽  
Ulrich Schubert

A heterogenized rhodium complex, prepared by sol-gel processing of Rh(CO)Cl[PPh2CH2CH2Si(OEt)3]2 and Si(OEt)4, is shown to catalyze the conversion of the silanes H4-nSiPh„ (n = 1 - 3) or (HMe2Si)2O to (poly)siloxanes by air or water. Using THF as a solvent, the silanoles Ph3SiOH or Ph2Si(OH)2 are obtained instead. The reaction of phenylacetic acid or acetic acid with HSiPh3 to give silyl esters is catalyzed by the same compound.


1996 ◽  
Vol 73 (4) ◽  
pp. 465-469 ◽  
Author(s):  
Kazuaki Ishii ◽  
Fujio Mizukami ◽  
Shu-ichi Niwa ◽  
Makoto Toba ◽  
Hirobumi Ushijima ◽  
...  

1986 ◽  
Vol 28 (2) ◽  
pp. 145-148 ◽  
Author(s):  
Rumjana Nikolova ◽  
L. Chovjka ◽  
Věra Hadačová ◽  
Věra Schejblová

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