Integration of Catalytic Combustion and Heat Recovery With Meso-Scale Solid Oxide Fuel Cell System

To facilitate high-power density operation of a meso-scale solid oxide fuel cell (SOFC) system, fuel processing and anode exhaust catalytic combustor with waste heat recovery are critical components. An integrated modeling study of a catalytic combustor with a solid oxide fuel cell and a catalytic partial oxidation (CPOx) reactor indicates critical aspects of the butane-fueled system design in order to ensure stable operation of the SOFC as well as the combustor and CPOx reactor. The modeled system consists of: 1) a Rh-coated ceramic foam catalytic partial oxidation reactor, 2) a SOFC with a Ni/YSZ structural anode, a dense YSZ electrolyte, and a LSM/YSZ cathode layer, and 3) a Pt-coated anode exhaust combustor with waste heat recovery. Model results for a system designed to produce < 30 W electric power from n-butane show how the design of the inlet-air cooled catalytic combustor can maximize combustion efficiency of the anode exhaust and heat recovery to the system inlet air flow. The model also shows the need to minimize heat loss in the air flow passages in order to maintain stable SOFC operation at 700 °C or higher. There is a strong sensitivity of the system operation to the SOFC operating voltage as well as the overall air to fuel ratio, and these sensitivities place important bounds on the range of operating conditions.