Steady shear rheology of entangled polymer liquids: Implications of interfacial slip

2002 ◽  
Vol 46 (5) ◽  
pp. 1239-1262 ◽  
Author(s):  
Javier Sanchez-Reyes ◽  
Lynden A. Archer
2003 ◽  
Vol 47 (2) ◽  
pp. 469-482 ◽  
Author(s):  
Javier Sanchez-Reyes ◽  
Lynden A. Archer

Author(s):  
Rodrigo E. Teixeira ◽  
Richard S. Graham

The visco-elastic properties of entangled polymer liquids arise from molecular-scale topological interactions and stochastic fluctuations under flow. Here, the evolutions of individual entangled polymers were observed in rheologically relevant shear flow histories. We uncover a high degree of molecular individualism and broad conformational distributions resulting from incessant stretch-collapse cycles. The data and insights of the present study may lead to improved molecular-level models and constitutive equations. These tools, in turn, may enable the rational design of novel materials with properties tailored to accomplish specific tasks such as high-pressure vessels and piping with greater safety margins and cost-effectiveness.


1999 ◽  
Vol 38 (4) ◽  
pp. 257-267 ◽  
Author(s):  
Rudy Folkersma ◽  
Alois J. G. van Diemen ◽  
Jozua Laven ◽  
Hans N. Stein

2018 ◽  
Vol 57 (4) ◽  
pp. 293-306 ◽  
Author(s):  
Francesco Del Giudice ◽  
Benjamin V. Cunning ◽  
Rodney S. Ruoff ◽  
Amy Q. Shen

2005 ◽  
Vol 43 (8) ◽  
pp. 917-933 ◽  
Author(s):  
Sathish K. Sukumaran ◽  
Gary S. Grest ◽  
Kurt Kremer ◽  
Ralf Everaers

2002 ◽  
Vol 35 (13) ◽  
pp. 5194-5202 ◽  
Author(s):  
Javier Sanchez-Reyes ◽  
Lynden A. Archer

Langmuir ◽  
2018 ◽  
Vol 34 (37) ◽  
pp. 10993-11002 ◽  
Author(s):  
Valeriy V. Ginzburg ◽  
Tirtha Chatterjee ◽  
Alan I. Nakatani ◽  
Antony K. Van Dyk

2018 ◽  
Vol 121 (16) ◽  
Author(s):  
Aditya Raghunandan ◽  
Amir H. Hirsa ◽  
Patrick T. Underhill ◽  
Juan M. Lopez

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