NEW ARTHROPOD SITES IN THE MUD HILLS: MIOCENE BARSTOW FORMATION, CALIFORNIA

2017 ◽  
Author(s):  
V. Leroy Leggitt ◽  
Keyword(s):  
2020 ◽  
Author(s):  
E. Troy Rasbury ◽  
Theodore M. Present ◽  
Paul Northrup ◽  
Ryan V. Tappero ◽  
Antonio Lanzirotti ◽  
...  

Abstract. Laser ablation U-Pb analyses of carbonate (LAcarb) samples has greatly expanded the potential for U-Pb dating to a variety of carbonate producing settings. Carbonates that were previously considered impossible to date using isotope dilution methods may preserve domains that are favorably interrogated when using spatially resolved laser ablation geochronology techniques. Work is ongoing to identify reference materials and to consider best practices for LAcarb. In this study we apply standard and emerging characterization toolsets on three natural samples with the dual goal of enhancing the study of carbonates and in establishing a new set of precisely characterized natural standards for LAcarb studies. We start with the existing carbonate reference material WC-1 from the Permian Reef Complex of Texas, building on the published description to offer a deeper look at U and fluids. We consider a tufa sample from the Miocene Barstow Formation of the Mojave Block, California, as a possible secondary calcite reference material due to its well-behaved U/Pb systematics. There are currently no natural dolomite standards. We present an unusual dolomite sample with very well-behaved U-Pb systematics from the Miocene of the Turkana Basin of Kenya as a possible dolomite reference material for LAcarb dating. In addition to using XRF mapping and spectroscopy to better understand U in these natural samples, we have analyzed multiple aliquots of each of them for 87Sr/86Sr. The Sr isotope compositions are reasonably homogeneous in all three samples, so that these could be used as Sr isotope standards as well. This combination could streamline split stream analyses of 87Sr/86Sr and U/Pb geochronology.


Preservation of soft integument in calcareous nodules seems to be more widespread geographically and stratigraphically than hitherto realized. It cannot be recognized in the field, and to recover such material requires special etching techniques. Such preservation can be of exceptional quality, with fossils preserved three dimensionally either by secondary phosphatization or by silicification. Coating as well as the replacement of integument has been observed even within the same sample. Methodical search for such preservation may be based on the common denominators of depositional, geochemical, and environmental indicators in previously described occurrences. As such exceptionally preserved material may be rare within the samples, large quantities of rock have to be prepared. The examples described here are from anthraconitic limestones (Orsten) of the Upper Cambrian Alum Shale Formation in Sweden. They are now known from many localities and from different trilobite zones. In addition nodules from the Lower Cretaceous Santana Formation in Brazil, the Upper Devonian cephalopod limestone in the Carnic Alps, the Lower Triassic of Spitzbergen and the Miocene Barstow Formation in California have all yielded extremely fine material.


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