Geochemical indicators of a biogenic component in source materials of moldavites

ABSTRACT Formation of the Central European tektites, known as moldavites, has been associated with a large meteorite impact in southern Germany 14.8 m.y. ago. The geochemical link between moldavites and their source materials, and the processes of their possible chemical differentiation still remain uncertain. Some differences in chemical composition between moldavites and sediments of corresponding age from the surroundings of the Ries crater could be explained by a hypothesis according to which biomass covering the pre-impact area contributed to the source materials. In a comparison of the geochemical compositions of a large representative set of moldavites and suitable Ries sediments, enrichment in elements K, Ca, Mg, and Mn and depletion of Na in moldavites, similar to redistribution of these elements during their transfer from soil to plants, could indicate the unconventional biogenic component in moldavite source materials. Simple mixing calculations of the most suitable Ries sediments and a model biogenic component represented by burned biomass residue are presented. The plausibility of the estimated biomass contribution considering reconstructions of the middle Miocene paleoenvironment in the pre-impact Ries area is discussed. No significant vapor fractionation is required to explain the observed variability of moldavite chemical composition.

Taxonomy of Middle Miocene foraminifera from the northern Namibian continental shelf

Middle Miocene foraminifera from the northern Namibian outer continental shelf are indicators of a period prior to the initiation of the Benguela Upwelling System (BUS). This study provides an update to the occurrence and taxonomy of Miocene foraminifera from the continental margin of Namibia. The taxonomy of 51 benthic and 12 planktic foraminiferal species from the northern Namibian shelf are discussed, their stratigraphic significance given, and their ecological preferences and regional distribution summarised within this study. The identification of extinct planktic foraminifera provided key stratigraphic control for the middle Miocene strata of this region. The taxa identified in this study provide a distinct and different assemblage to the overlying younger strata. Many of the species recorded in this study have not been identified in the region and are reported for the first time from the middle Miocene on the southwestern continental shelf of Africa, off Namibia. A total of 47 species are identified and discussed for the first time from this region. Nineteen species recorded in this study are extinct and eleven taxa reported here have previously only been reported on the genus level on the southwestern shelf of South Africa. Seven benthic species (Amphicoryna scalaris, Marginulina obesa, Glandulina laevigata, Globocassidulina subglobosa, Uvigerina peregrina, Sphaeroidina bulloides and Melonis affinis) and two planktic species (Globigerina bulloides and Orbulina universa) did not disappear from the regional stratigraphy and continued to occur in Plio-Pleistocene to Recent sediments along the southwestern continental shelf of Africa.

COPROLITES FROM CALVERT CLIFFS: MIOCENE FECAL PELLETS AND BURROWED CROCODILIAN DROPPINGS FROM THE CHESAPEAKE GROUP OF MARYLAND, U.S.A.

New finds of remarkable coprolites (fossilized feces) are here reported from the famous Miocene marine sediments of the Chesapeake Group exposed along Calvert Cliffs (Maryland, U.S.A.). Although vertebrate coprolites have been described from these deposits, here we provide the first description of tiny invertebrate fecal pellets. Thus far, these fecal pellets have only been found in the upper Miocene (Tortonian) St. Marys Formation. The micro-coprolites represent the coprulid ichnospecies Coprulus oblongus. The fecal pellets are found in small clusters or strings of dozens to masses of many hundreds. Pellets range in size from approximately 0.4 – 2.0 mm wide by 1.0 – 5.0 mm long, and range in color from gray to brownish black. Their length/diameter ratio is always very nearly 2. These coprulids have been found in a variety of Miocene fossils/concretions including a uranoscopid neurocranium, naticid gastropod, bivalve shells, barnacle tests, and in pellet-backfilled sinuous burrows through sediment. Because the fecal pellets are often found in tiny spaces or spaces thought to be inaccessible to shelled invertebrates, the coprulids are attributed to small and soft-bodied polychaetes or other annelids. Some coprolites attributed to crocodilians from the lower-middle Miocene Calvert Formation were tunneled into, presumably the result of coprophagy, by some unknown kind of organism(s). These compound trace fossils are in the form of burrows that excavate the coprolites, the sides of which are sculptured by scratch/gouge marks.

Immigration dynamics of tropical and subtropical Southeast Asian limestone karst floras

Ex situ origins and dispersal of taxa have played important roles in the assembly of island-like biodiversity hotspots. Insular limestone karsts in Southeast Asia are hotspots of biodiversity and endemism, but the immigration processes of their unique floras are still poorly known. Here, we used Gesneriaceae as a proxy to investigate the immigration dynamics of tropical and subtropical Southeast Asian karst floras. We present the most comprehensive phylogenetic analysis of the Old World gesneriads to date based on twelve loci. By estimating divergence times and reconstructing ancestral states (habitat, soil type and range), we found that immigration into subtropical Southeast Asian karst floras first occurred in the Early Miocene, with two peaks in the Early–Middle Miocene and the Pliocene–Early Pleistocene, whereas immigration into tropical Southeast Asian karsts initiated in the Late Eocene, with two peaks in the Late Oligocene and the Late Miocene. We also discover that Southeast Asian karst biodiversity comprises immigrant pre-adapted lineages and descendants from local acid soil ancestors, although niche shift from acid soil to karst in tropical Southeast Asian islands was lacking. This study advances our understanding of the historical assembly of Southeast Asian karst floras.

Multi-proxy evidence of Caribbean-sourced marine incursions in the Neogene of Western Amazonia, Brazil

The timing of continental-scale marine flooding events in Western Amazonia during the Neogene is still an unsolved question. Despite broad proxy-based evidence of such events, the pathways and duration of late Miocene marine incursions remain controversial. We provide coupled calcareous and organic microfossil and geochemical data from six onshore cores from Neogene sequences of the Solimões Basin, Brazil. Our records support minor marine influence in the early Miocene (23.0, 21.1, 18.6, and 16.3 Ma), middle Miocene (14.9, 13.7, and 12.9 Ma) and early Pliocene (4.7, 4.2–4.1, and 3.8 Ma), and conspicuous marine incursions in the late Miocene (11.1–8.8 Ma) suggested by the consistent presence of salinity-indicative microfossils and geochemical data. Our findings challenge the view of major marine incursions in the early and middle Miocene in the studied area. We propose for the first time a new late Miocene incursion (LMI) event as the main marine flooding event in Western Amazonia during the Neogene. These onshore records are compared with three offshore cores from the Atlantic and Pacific Oceans. The similarity between microfossil assemblages of the Solimões Basin and the Caribbean Sea, and evidence of increased runoff from the Orinoco river drainage system, strongly suggest the Caribbean Sea as the primary source area of the marine incursions, supporting a Venezuelan seaway. We further show for the first time the potential linkage between Neogene marine incursions (mainly the LMI) into the Solimões Basin and major disturbances in the global carbon cycle.

Palaeoecologic and Palaeoclimatic Inferences from Calcareous Nannofossils in Western Lobe Offshore, Niger Delta

In support of the ongoing temporal palaeoenvironment and palaeoclimatic reconstructions of the Neogene sediments, this study attempts to detail the paleo-proxies recovered from DEL-1 Well, western offshore Niger Delta. The standard smear slide method enabled the recovery of well-preserved calcareous nannofossils that depict early to mid–Miocene (NN4–NN5) sediments. The up-hole relationships between the nannofossil accumulation rate (NAR), the relative abundance of Discoaster and coccolith size of Reticulofenestra show step by step collapse of sea surface stability from early to middle Miocene. The lower horizons (8000–9460 ft) exhibit a low NAR, relatively high Discoaster abundance and relatively large Reticulofenestra size to suggest a deep thermocline and nutricline that characterise oligotrophic conditions in less warm-water induced climate. Conversely, upper horizons (5225–6550 ft) exhibit a high NAR, relatively low Discoaster abundance and relatively small Reticulofenestra size to suggest a shallow thermocline and nutricline that characterise eutrophic conditions in warm-water induced climate. The relative abundance of Helicosphaera carteri within the mid-NN5 suggests mesotrophic conditions within a stressed environment, with the possible occurrence of carbonate crash events. The combined parameters indicate gradual eutrophication and collapse of sea surface stability favouring nutrients and influx of terrestrial sediments in the ocean water as it progressed from early to middle Miocene. The abundance of the palaeo-proxies assemblages suggests hyposaline waters in a neritic environment that prevailed during the warm climatic condition.

Manufacture of Portland Cement from Claystone of Nfayil Formation Middle Miocene, in Southern Desert of Iraq

The research aims to assess the claystone exposed in the Nfayil Formation (Middle Miocene) for Portland cement (P.C.) manufacturing based on mineralogy and geochemistry. The importance of the study is to avoid the miming of the agricultural soils that are mining now for the cement industry. Claystones of Nfayil Formation and the limestone of the Euphrates Formation were used to design the raw mixture as clay to limestone (1:3). The chemical composition (%) of the designed mixture was calculated using the Alligation Alternative Method (A.A.M.) as CaO (65.52), MgO (1.05), SiO2 (21.65), Al2O3 (7.43), Fe2O3 (2.62), Na2O3+K2O (1.52) and SO3 (0.26), which are suitable for P.C. The lime saturation factor (LSF = 92.8), silica saturation factor (SSF = 0.87), alumina ratio (AR = 2.8), silica ratio (SR = 2.16), and calcium to silica (CS = 3.04) of the planned mixture are all within the permissible range. A clinker was successfully manufactured as composed mainly of belite, alite, aluminate, and ferrite.