Peritectic Reaction of Olivine in the Olivine–Jadeite–Diopside–Garnet–(C–O–H) System at 6 GPa as the Key Mechanism of the Magmatic Evolution in the Upper Mantle

2021 ◽  
Vol 59 (9) ◽  
pp. 813-839
Author(s):  
Yu. A. Litvin ◽  
A. V. Kuzyura
2019 ◽  
Vol 64 (10) ◽  
pp. 1026-1046
Author(s):  
Yu. A. Litvin ◽  
A. V. Kuzyura ◽  
E. B. Limanov

Peritectic mechanisms, controlling fractional ultrabasic-basic evolution of the upper mantle magmatism and genesis of the peridotitepyroxeniteeclogite rock series, are substantiated in theory and experiment. Melting phase relations of a differentiated mantle material are studied with polythhermal section method in the multicomponent olivineclinopyroxene/omphacitecorundumcoesite system with boundary compositions duplicated these of peridotitic and eclogitic minerals. The peritectic reaction of orthopyroxene and melt with formation of clinopyroxene (the opthopyroxene clinopyroxenization reaction) has been determined at a liquidus surface of the ultrabasic olivineorthopyroxeneclinopyroxenegarnet system. As a result of the reaction the temperature-regressive univariant curve olivine + clinopyroxene + garnet + melt is formed. A further evolution of magmatism has experimentally studied at 6 GPa in the ultrabasic-basic olivinediopsidejadeitegarnet system with changeable compositions of the diopsidejadeite solid solutions (controlling the clinopyroxene omphacite mineralogy). Peritectic reaction of olivine and melt with formation of garnet was established on the liquidus surface of the ternary olivinediopsidejadeite system as the mechanism of olivine garnetization and going to the univariant curve omphacitegarnetmelt with formation of bimineral eclogites. Structure of the liquidus surface for the olivinediopsidejadeitegarnet system is inferred, and its role as a physic-chemical bridge between ultrabasic olivinebearing peridotitepyroxenitic and basic silica-saturated eclogitic compositions of the garnetperidotite facies matter. The new experimental physic-chemical results reveal the genetic links between ultrabasic and basic rocks as well as mechanisms of the uninterrupted fractional magmatic evolution and petrogenesis from the olivinebearing peridotitepyroxenitic to silica-saturated eclogite-grospyditicrocks. This provides an explanation for the uninterrupted composition trends for rock-forming components in clinopyroxenes and garnets of the differentiated rocks of the garnetperidotite facieis.


2020 ◽  
Author(s):  
Nore Stolte ◽  
Junting Yu ◽  
Zixin Chen ◽  
Dimitri A. Sverjensky ◽  
Ding Pan

The water-gas shift reaction is a key reaction in Fischer-Tropsch-type synthesis, which is widely believed to generate hydrocarbons in the deep carbon cycle, but is little known at extreme pressure-temperature conditions found in Earth’s upper mantle. Here, we performed extensive ab initio molecular dynamics simulations and free energy calculations to study the water-gas shift reaction. We found the direct formation of formic acid out of CO and supercritical water at 10∼13 GPa and 1400 K without any catalyst. Contrary to the common assumption that formic acid or formate is an intermediate product, we found that HCOOH is thermodynamically more stable than the products of the water-gas shift reaction above 3 GPa and at 1000∼1400 K. Our study suggests that the water-gas shift reaction may not happen in Earth’s upper mantle, and formic acid or formate may be an important carbon carrier, participating in many geochemical processes in deep Earth.<br>


2017 ◽  
Vol 34 (1) ◽  
pp. 45 ◽  
Author(s):  
Elizard González-Becuar ◽  
Efrén Pérez-Segura ◽  
Ricardo Vega-Granillo ◽  
Luigi Solari ◽  
Carlos Manuel González-León ◽  
...  

Plutonic rocks of the Puerta del Sol area, in central Sonora, represent the extension to the south of the El Jaralito batholith, and are part of the footwall of the Sierra Mazatán metamorphic core complex, whose low-angle detachment fault bounds the outcrops of plutonic rocks to the west. Plutons in the area record the magmatic evolution of the Laramide arc and the Oligo-Miocene syn-extensional plutonism in Sonora. The basement of the area is composed by the ca. 1.68 Ga El Palofierral orthogneiss that is part of the Caborca block. The Laramide plutons include the El Gato diorite (71.29 ± 0.45 Ma, U-Pb), the El Pajarito granite (67.9 ± 0.43 Ma, U-Pb), and the Puerta del Sol granodiorite (49.1 ± 0.46 Ma, U-Pb). The younger El Oquimonis granite (41.78 ± 0.32 Ma, U-Pb) is considered part of the scarce magmatism that in Sonora records a transition to the Sierra Madre Occidental magmatic event. The syn-extensional plutons are the El Garambullo gabbro (19.83 ± 0.18 Ma, U-Pb) and the Las Mayitas granodiorite (19.2 ± 1.2 Ma, K-Ar). A migmatitic event that affected the El Palofierral orthogneiss, El Gato diorite, and El Pajarito granite between ca. 68 and 59 Ma might be related to the emplacement of the El Pajarito granite. The plutons are metaluminous to slightly peraluminous, with the exception of El Oquimonis granite, which is a peraluminous two-mica, garnet-bearing granite. They are mostly high-K calc-alkaline with nearly uniform chondrite-normalized REE and primitive-mantle normalized multielemental patterns that are characteristic of continental margin arcs and resemble patterns reported for other Laramide granites of Sonora. The Laramide and syn-extensional plutons also have Sr, Nd and Pb isotopic ratios that plot within the fields reported for Laramide granites emplaced in the Caborca terrane in northwestern and central Sonora. Nevertheless, and despite their geochemical affinity to continental magmatic arcs, the El Garambullo gabbro and Las Mayitas granodiorite are syn-extensional plutons that were emplaced at ca. 20 Ma during development of the Sierra Mazatán metamorphic core complex. The 40Ar/39Ar and K-Ar ages obtained for the El Palofierral orthogneiss, the Puerta del Sol granodiorite, the El Oquimonis granite, and the El Garambullo gabbro range from 26.3 ± 0.6 to 17.4 ± 1.0 Ma and are considered cooling ages associated with the exhumation of the metamorphic core complex.


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