Synthesis, characterization and computational studies of zinc(II)-halide complexes with a bidentate schiff base ligand (2,5-MeO-ba)2En: The crystal structure of (2,5-MeO-ba)2En

2013 ◽  
Vol 54 (4) ◽  
pp. 766-773 ◽  
Author(s):  
A. D. Khalaji ◽  
H. Mighani ◽  
M. Gholinejad ◽  
G. Grivani ◽  
S. Jalali Akerdi ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Schiff Base ◽  
Schiff Base Ligand ◽  
Computational Studies ◽  
Bidentate Schiff Base Ligand ◽  
Halide Complexes

Platinum(II) complex with 4-nitro-N-(pyridin-2-ylmethylidene)aniline: synthesis, characterization, crystal structure and antioxidant activity

2020 ◽  
Vol 76 (11) ◽  
pp. 1005-1009
Author(s):  
Mehdi Khalaj ◽  
Abolfazl Olyaei ◽  
Mahdieh Sadeghpour ◽  
Arash Lalegani ◽  
Janusz Lipkowski ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Antioxidant Activity ◽  
Schiff Base ◽  
Schiff Base Ligand ◽  
Chain Structure ◽  
X Ray Diffraction ◽  
X Ray ◽  
Square Planar ◽  
Dpph Method ◽  
Bidentate Schiff Base Ligand

A novel complex has been prepared using the (E)-4-nitro-N-(pyridin-2-ylmethylidene)aniline bidentate Schiff base ligand and PtCl2, namely, dichlorido[(E)-4-nitro-N-(pyridin-2-ylmethylidene)aniline-κ2 N,N′]platinum(II) acetonitrile hemisolvate, [PtCl2(C12H9N3O2)]·0.5CH3CN, 1. According to the X-ray measurements of the crystal structure, the PtII ion adopts a PtCl2N2 square-planar coordination. The coordination of the Schiff base ligand to the PtII ion occurs in a cyclic bidentate fashion, as a result of which a five-membered metallacycle is formed. Furthermore, in the structure of 1, the neutral molecules form a one-dimensional chain structure through C—H...Cl and C—H...O hydrogen bonds. The characterization of the complex was performed via single-crystal X-ray diffraction, IR spectroscopy and elemental analysis, and the antioxidant activity of the complex was evaluated using spectrophotometry by the 1,1-diphenyl-2-picrylhydrazyl (DPPH) method.

Synthesis, crystal structure, spectroscopic investigations, and computational studies of Ni(II) and Pd(II) complexes with asymmetric tetradentate NOON Schiff base ligand

2019 ◽  
Vol 30 (6) ◽  
pp. 2289-2299 ◽  
Author(s):  
Hadi Kargar ◽  
Vajiheh Torabi ◽  
Alireza Akbari ◽  
Reza Behjatmanesh-Ardakani ◽  
Atefeh Sahraei ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Schiff Base ◽  
Schiff Base Ligand ◽  
Computational Studies ◽  
Spectroscopic Investigations

Cobalt(III) Complex [CoL3] Derived from an Asymmetric Bidentate Schiff Base Ligand L (L=(5-Bromo-2-hydroxybenzyl-2-furylmethyl)-imine): Synthesis, Characterization and Crystal Structure

2011 ◽  
Vol 29 (8) ◽  
pp. 1613-1616 ◽  
Author(s):  
Aliakbar D. Khalaji ◽  
Sepideh Maghsodlou Rad ◽  
Gholamhossein Grivani ◽  
Morteza Rezaei ◽  
Kazuma Gotoh ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Schiff Base ◽  
Schiff Base Ligand ◽  
Bidentate Schiff Base Ligand
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