Alumina-Supported Palladium–Silver Bimetallic Catalysts with Single-Atom Pd1 Sites in the Liquid-Phase Hydrogenation of Substituted Alkynes

2020 ◽  
Vol 61 (6) ◽  
pp. 869-878
Author(s):  
A. V. Rassolov ◽  
G. O. Bragina ◽  
G. N. Baeva ◽  
I. S. Mashkovsky ◽  
A. Yu. Stakheev
2015 ◽  
Vol 64 (1) ◽  
pp. 53-57 ◽  
Author(s):  
A. Yu. Stakheev ◽  
B. L. Moroz ◽  
I. S. Mashkovsky ◽  
P. V. Markov ◽  
O. V. Turova ◽  
...  

2019 ◽  
Vol 1 (1) ◽  
Author(s):  
Pabitra Kumar Baidya ◽  
Ujjaini Sarkar ◽  
Raffaela Villa ◽  
Suvra Sadhukhan

1989 ◽  
Vol 54 (11) ◽  
pp. 3003-3010 ◽  
Author(s):  
Jiří Hanika ◽  
Vladimíra Ehlová

Kinetics of the side reactions represented by the system involving hydrogenation and disproportionation of cyclohexene on a commercial catalyst CHEROX 41-00 (3%Pd/C) and on a supported palladium catalyst prepared by impregnation of aluminia with aqueous palladium dichloride (2.15% Pd/γ-Al2O3) have been investigated. As follows from the effectiveness factors of internal diffusion for individual reactions, in the region of internal diffusion, cyclohexene hydrogenation is preferred compared to disproportionation. This finding can be related to the fact that while the rate of disproportionation is controlled by cyclohexene diffusion, the rate of hydrogenation is controlled by diffusion of hydrogen.


1997 ◽  
Vol 172 (1) ◽  
pp. 46-54 ◽  
Author(s):  
M.A. Aramendı́a ◽  
V. Borau ◽  
C. Jiménez ◽  
J.M. Marinas ◽  
A. Porras ◽  
...  

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