Theoretical studies on magnetic properties of a binuclear paddle wheel Cu(II) complex {Cu2(μ2-O2CCH3)4}(OCNH2CH3)2

2017 ◽  
Vol 91 (6) ◽  
pp. 1070-1075 ◽  
Author(s):  
S. X. Cui ◽  
H. Y. Wang ◽  
J. Xu ◽  
J. P. Zhang
2013 ◽  
Vol 66 (12) ◽  
pp. 2166-2177 ◽  
Author(s):  
Jie Zhou ◽  
Lin Du ◽  
Zongze Li ◽  
Yongfeng Qiao ◽  
Jing Liu ◽  
...  

2021 ◽  
Vol 95 (S2) ◽  
pp. S406-S410
Author(s):  
J. H. Yu ◽  
W. W. Zhang ◽  
B. L. Zhu ◽  
P. Z. He ◽  
S. X. Cui

2001 ◽  
Vol 56 (8) ◽  
pp. 719-727 ◽  
Author(s):  
H. Kara ◽  
Y. Elerman ◽  
K. Prout

Preparation, crystal structure and magnetic properties of a 3,5-dimethylpyrazolate bridged binuclear copper(II) complex [Cu2(L1)(3,5 prz)] (L1 = 1,3-Bis(2-hydroxy-1-napthylideneamino) propan-2-ol) (1) are reported. Variable-temperature magnetic susceptibility measurements for a powdered sample of the complex were carried out in the temperature range 5 - 350 K and analysed to obtain values of the parameter J in the exchange Hamiltonian H = -2JS1·S2 . In the dicopper(II) complex [Cu2(L2)(3,5 prz)], (L2 = l,3-Bis(2-hydroxy-5-chlorosalicylideneamino) propan-2-ol) (2) reported recently the antiferromagnetic interaction is much less than that of 1 (-27 = 440 cm-1 ), as result which is difficult to explain in terms of structural factors on the basis of widely accepted criteria. The differences in the magnetic behaviour now have been rationalized using the “ligand orbital complementary” concept


2018 ◽  
Vol 644 (12-13) ◽  
pp. 560-563 ◽  
Author(s):  
Feng Li ◽  
Kai Liu ◽  
Shiwen Fan ◽  
Tingting Qin ◽  
Suhua Xiong ◽  
...  

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