Rubidium-cation conductivity of Rb3–2x Pb x PO4 solid solutions

2017 ◽  
Vol 59 (7) ◽  
pp. 1377-1381
Author(s):  
G. Sh. Shekhtman ◽  
E. I. Burmakin
Materials ◽  
2021 ◽  
Vol 14 (22) ◽  
pp. 6904
Author(s):  
Georgiy Sh. Shekhtman ◽  
Anastasia V. Kalashnova ◽  
Boris D. Antonov

Li6-xZr2-xAxO7 (A = Nb; Ta) system with 0 < x < 0.30 is synthesized by glycine-nitrate method. Boundaries of solid solutions based on monoclinic Li6Zr2O7 are determined; temperature (200–600 °C) and concentration dependences of conductivity are investigated. It is shown that monoclinic Li6Zr2O7 exhibits better transport properties compared to its triclinic modification. Li5.8Zr1.8Nb(Ta)0.2O7 solid solutions have a higher lithium-cation conductivity at 300 °C compared to solid electrolytes based on other lithium zirconates due the “open” structure of monoclinic Li6Zr2O7 and a high solubility of the doping cations.


2015 ◽  
Vol 57 (5) ◽  
pp. 992-995 ◽  
Author(s):  
E. I. Burmakin ◽  
G. Sh. Shekhtman

1989 ◽  
Vol 50 (21) ◽  
pp. 3223-3232 ◽  
Author(s):  
G. Le Bastard ◽  
R. Granger ◽  
S. Rolland ◽  
Y. Marqueton ◽  
R. Triboulet

1979 ◽  
Vol 40 (C5) ◽  
pp. C5-314-C5-320 ◽  
Author(s):  
F. Holtzberg ◽  
T. Penney ◽  
R. Tournier
Keyword(s):  

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