Potential-time response for several types of programmed current at most usual electrodes. Theoretical study of CE and EC mechanisms
1991 ◽
Vol 56
(1)
◽
pp. 1-19
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Keyword(s):
The theoretical study of the potential-time response corresponding to the CE and EC mechanisms at the DME by using non linear perturbation functions with the general form I(t) = I0tuewt and I(t) = I0(t1 + t)v is presented. Equations for the potential-time curves and for the transition times have been derived by taking into account the sphericity of the electrode. Methods for determining heterogeneous and homogeneous kinetic parameters are proposed. The expressions corresponding to an null blank period, to an expanding plane electrode and to spherical and plane stationary electrodes, can be deduced as particular cases of the equations obtained in this work.
1997 ◽
Vol 62
(10)
◽
pp. 1511-1526
1979 ◽
Vol 101
(3)
◽
pp. 301-305
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1979 ◽
Vol 101
(3)
◽
pp. 291-300
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1988 ◽
Vol 251
(2)
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pp. 249-266
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1975 ◽
Vol 63
(3)
◽
pp. 263-273
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1987 ◽
Vol 227
(1-2)
◽
pp. 1-10
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1982 ◽
Vol 132
◽
pp. 15-23
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Keyword(s):
1971 ◽
Vol 17
(1)
◽
pp. 129-138
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2003 ◽
Vol 36
(12)
◽
pp. 2445-2454
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Keyword(s):