Interpretation of Preferential Adsorption Using Random Phase Approximation Theory

1995 ◽  
Vol 60 (10) ◽  
pp. 1641-1652 ◽  
Author(s):  
Henri C. Benoît ◽  
Claude Strazielle

It has been shown that in light scattering experiments with polymers replacement of a solvent by a solvent mixture causes problems due to preferential adsorption of one of the solvents. The present paper extends this theory to be applicable to any angle of observation and any concentration by using the random phase approximation theory proposed by de Gennes. The corresponding formulas provide expressions for molecular weight, gyration radius, and the second virial coefficient, which enables measurements of these quantities provided enough information on molecular and thermodynamic quantities is available.


1990 ◽  
Vol 67 (9) ◽  
pp. 5079-5081 ◽  
Author(s):  
N. Bulut ◽  
D. W. Hone ◽  
D. J. Scalapino ◽  
N. E. Bickers




2011 ◽  
Vol 2011 ◽  
pp. 1-9
Author(s):  
Ju-Tang Hsiao ◽  
Hsiao-Ling Sun ◽  
Sheng-Fang Lin ◽  
Keh-Ning Huang

The relativistic calculations of the cross-section σ, the angular-distribution parameter β, and spin-polarization parameters {ξ,η,ζ} of photoelectrons using the multiconfiguration relativistic random-phase approximation theory for the photoionization of the B+ ion are presented. Precise energies and widths of all five Rydberg series of doublyexcited states (2pns)1P1o, (2pns)3P1o, (2pnd)1P1o, (2pnd)3P1o, and (2pnd)3D1o are determined. Our predictions are in very close agreement with experiments and are consistent with other calculations.



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