Investigation of amino acetonitrile (NH2CH2CN) — a precursor of glycine, in the interstellar medium

2020 ◽  
Vol 98 (3) ◽  
pp. 243-250
Author(s):  
Mohit K. Sharma

Known values of rotational and centrifugal distortion constants, in conjunction with electric dipole moment, have been used to calculate energies for the ground rotational levels, ground vibrational state, and ground electronic state of amino acetonitrile (NH2CH2CN), which is of interest for studies of life in the universe. Probabilities for radiative transitions between the rotational levels are also calculated. Such transition probabilities are used in conjunction with scaled values for the collisional rate coefficients for large velocity gradient calculations. A line 110–111 at 450.31 MHz is found to show anomalous absorption. Two observed lines 909–808 at 80.947 GHz and 120,12–110,11 at 107.283 GHz, and another nine lines, 918–817, 716–615, 817–716, 919–818, 1019–918, 808–707, 100,10–909, 110,11–100,10, and 707–606, are found to show emission features. There are several other observed lines, which are found weaker than these 11 lines. These 10 additional lines may help in the identification of amino acetonitrile in the interstellar medium.

Author(s):  
A. Chefai ◽  
M. Ben Khalifa ◽  
F. Khadri ◽  
K. Hammami

An appropriate estimation of the abundance of the observed C5 radical in the interstellar medium requires accurate radiative and collisional rate coefficients.


2015 ◽  
Vol 11 (A29A) ◽  
pp. 299-304
Author(s):  
Ewine F. van Dishoeck

AbstractThis brief overview stresses the importance of molecular processes in modern astrophysics and provides examples where the availability of new laboratory or theoretical data proved crucial in the analysis. This includes basic data such as spectroscopy and collisional rate coefficients, but also an improved understanding of reactions and photoprocesses in the gaseous and solid state. In spite of many lingering uncertainties, the future of molecular astrophysics is bright with new facilities such as ALMA, JWST and ELTs on the horizon. Together, they will allow increased understanding of the journey of gas and solids from clouds to stars and planets, and back to the interstellar medium.


2011 ◽  
Vol 134 (2) ◽  
pp. 024305 ◽  
Author(s):  
Robert Toboła ◽  
Fabien Dumouchel ◽  
Jacek Kłos ◽  
François Lique

1972 ◽  
Vol 6 (1) ◽  
pp. 38-44 ◽  
Author(s):  
R. U. Datla ◽  
H. -J. Kunze ◽  
D. Petrini

2020 ◽  
Vol 494 (4) ◽  
pp. 5239-5243
Author(s):  
Paul J Dagdigian

ABSTRACT Accurate estimates of the abundance of H2S, and inferences about the unmeasured H2 density, require accurate knowledge of radiative and collisional rate coefficients. Time-independent close-coupling quantum scattering calculations have been employed to compute rate coefficients for (de-)excitation of para- and ortho-H2S in collisions with para- and ortho-H2. These calculations utilized a potential energy surface for the interaction of H2S with H2 recently computed by the explicitly correlated CCSD(T)-F12a coupled-cluster method. Rate coefficients for temperatures ranging from 5 to 500 K were calculated for all transitions among the first 19 rotational levels of H2S, whose energies are less than or equal to 405 K. These rate coefficients are compared with previous estimates of these quantities.


1972 ◽  
Vol 14 ◽  
pp. 565-583 ◽  
Author(s):  
H.-J. Kunze

AbstractLine radiation emitted by highly ionized atoms embedded in hot laboratory plasmas can be utilized to obtain collisional rate coefficients for excitation and ionization. After a discussion of the principles underlying these measurements, the plasma device mostly used is explained briefly as are the various experimental techniques. All experimental results obtained so far are finally discussed and compared with theoretical calculations where possible.


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