The a3Π1–X1Σ+ emission system of CBr+

1983 ◽  
Vol 61 (2) ◽  
pp. 251-255 ◽  
Author(s):  
Masaharu Tsuji ◽  
Keiji Shinohara ◽  
Toshinori Mizuguchi ◽  
Yukio Nishimura
Keyword(s):  
Charge Transfer ◽  
Emission Spectrum ◽  
Thermal Energy ◽  
Transfer Reaction ◽  
Vibrational Analysis ◽  
Visible Emission ◽  
Spectroscopic Constants ◽  
Charge Transfer Reaction ◽  
Emission System ◽  
First Time

The visible emission spectrum of the CBr+ molecule has been observed for the first time in the helium afterglow reaction of CBr4. It was excited by the dissociative charge-transfer reaction of He+ with CBr4 at thermal energy. The vibrational analysis led to the following spectroscopic constants (in cm−1).[Formula: see text]

CCl+ (A1Π–X1Σ+, a3Π1–X1Σ+) emission systems produced from the thermal energy reaction between He+ and CCl4

1983 ◽  
Vol 61 (6) ◽  
pp. 838-843 ◽  
Author(s):  
Masaharu Tsuji ◽  
Toshinori Mizuguchi ◽  
Keiji Shinohara ◽  
Yukio Nishimura
Keyword(s):  
Charge Transfer ◽  
Transfer Reaction ◽  
Impact Ionization ◽  
Vibrational Analysis ◽  
The Other ◽  
Spectroscopic Constants ◽  
Charge Transfer Reaction ◽  
Transfer Ionization ◽  
First Time ◽  
Energy Reaction

Two emission systems of CCl+ have been observed by the dissociative charge-transfer reaction of He+ with CCl4 in the 230–255 and 390–405 nm region. The former system had been detected from an electronic discharge in CCl4 vapor, though the electronic transition had not been known definitely. On the other hand, the latter system was observed for the first time in this work. By comparison with spectroscopic constants obtained by ab initio calculations, the 230–255 and 390–405 nm bands were assigned to the A1Π–X1Σ+ and a3Π1–X1Σ+ systems, respectively. From the vibrational analysis of the a−X system, the following spectroscopic constants have been determined for the new state (in cm−1):a3Π,:Te = 25 480.6 ± 1.5; ωe = 1120.3 ± 1.0; ωexe = 7.52 ± 0.14. The mechanism of charge-transfer ionization leading to the CCl+ (A, a) states was discussed in comparison with that of electron-impact ionization.

Nascent rovibrational distribution of NO+(A 1Π) produced from charge-transfer reaction of He2+ with NO at thermal energy

1999 ◽  
Vol 110 (18) ◽  
pp. 9064-9070 ◽  
Author(s):  
Masaharu Tsuji ◽  
Yukio Nishimura ◽  
Hiroaki Ishimi ◽  
Masahiro Hisano ◽  
Hidefumi Oota
Keyword(s):  
Charge Transfer ◽  
Thermal Energy ◽  
Transfer Reaction ◽  
Charge Transfer Reaction

Optical study of the He2+ + CO2 charge-transfer reaction at thermal energy

1983 ◽  
Vol 82 (1-2) ◽  
pp. 67-73 ◽  
Author(s):  
Minoru Endoh ◽  
Masaharu Tsuji ◽  
Yukio Nishimura
Keyword(s):  
Charge Transfer ◽  
Thermal Energy ◽  
Transfer Reaction ◽  
Charge Transfer Reaction ◽  
Optical Study

Chemiluminescence of carbon disulfide(1+) (CS2+) initiated by a thermal energy charge-transfer reaction with argon(1+)

1986 ◽  
Vol 90 (1) ◽  
pp. 100-104 ◽  
Author(s):  
B. L. Upschulte ◽  
R. J. Shul ◽  
R. Passarella ◽  
R. E. Leuchtner ◽  
R. G. Keesee ◽  
...  
Keyword(s):  
Charge Transfer ◽  
Carbon Disulfide ◽  
Thermal Energy ◽  
Transfer Reaction ◽  
Energy Charge ◽  
Charge Transfer Reaction
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