Estimation of Fluor Emission Spectrum through Digital Photo Image Analysis with a Water-Based Liquid Scintillator

In this paper, we performed a feasibility study of using a water-based liquid scintillator (WbLS) for conducting imaging analysis with a digital camera. The liquid scintillator (LS) dissolves a scintillating fluor in an organic base solvent to emit light. We synthesized a liquid scintillator using water as a solvent. In a WbLS, a suitable surfactant is needed to mix water and oil together. As an application of the WbLS, we introduced a digital photo image analysis in color space. A demosaicing process to reconstruct and decode color is briefly described. We were able to estimate the emission spectrum of the fluor dissolved in the WbLS by analyzing the pixel information stored in the digital image. This technique provides the potential to estimate fluor components in the visible region without using an expensive spectrophotometer. In addition, sinogram analysis was performed with Radon transformation to reconstruct transverse images with longitudinal photo images of the WbLS sample.

The Emission Spectrum of the Hot Jupiter WASP-79b from HST/WFC3

Here we present a thermal emission spectrum of WASP-79b, obtained via Hubble Space Telescope Wide Field Camera 3 G141 observations as part of the PanCET program. As we did not observe the ingress or egress of WASP-79b’s secondary eclipse, we consider two scenarios: a fixed mid-eclipse time based on the expected occurrence time, and a mid-eclipse time as a free parameter. In both scenarios, we can measure thermal emission from WASP-79b from 1.1 to 1.7 μm at 2.4σ confidence consistent with a 1900 K brightness temperature for the planet. We combine our observations with Spitzer dayside photometry (3.6 and 4.5 μm) and compare these observations to a grid of atmospheric forward models that span a range of metallicities, carbon-to-oxygen ratios, and recirculation factors. Given the strength of the planetary emission and the precision of our measurements, we found a wide range of forward models to be consistent with our data. The best-match equilibrium model suggests that WASP-79b’s dayside has a solar metallicity and carbon-to-oxygen ratio, alongside a recirculation factor of 0.75. Models including significant H− opacity provide the best match to WASP-79b’s emission spectrum near 1.58 μm. However, models featuring high-temperature cloud species—formed via vigorous vertical mixing and low sedimentation efficiencies—with little day-to-night energy transport also match WASP-79b’s emission spectrum. Given the broad range of equilibrium chemistry, disequilibrium chemistry, and cloudy atmospheric models consistent with our observations of WASP-79b’s dayside emission, further observations will be necessary to constrain WASP-79b’s dayside atmospheric properties.

Gallic Acid-Containing Gelatin-Based Nonwoven Mat with Synergistic Photodegradation and Photoindication Function for Reducing Nicotine

Cigarette smoking is a popular habit that has negative health consequences for populations. In this study, we developed a gallic acid-containing, gelatin-based nonwoven mat with photodegradation and photoindication functions. This could react with sidestream cigarette smoke and simultaneously inhibit the activity of the microbe growth in the air. The results of a fluorescence emission spectrum evidenced this photoindication function. Neither the nicotine nor gallic acid showed a redshift emission spectrum. However, the emission spectrum of the nonwoven mat exhibited the redshift and increased in intensity after absorbing the sidestream cigarette smoke. In this spectral evidence, the natural polymer played a key role in the photoindication function’s display because it could dissolve the nicotine of the sidestream cigarette smoke and cause it to react with the gelatin structure. The high performance liquid chromatography–mass spectroscopy results indicated that the gallic acid and ultraviolet (UV) light enhanced the absorption of nicotine and nicotine-like derivatives, which were dissolved by the Tween 80 of nonwoven mat. The liquid paraffin and Tween 80 could oxidize, dehydrogenate, and demethylate the nicotine that was absorbed by the gelatin nonwoven mat. In conclusion, the nonwoven mat developed in this study provided the functions to filter the nicotine of sidestream smoke and activate the photoindication property by absorbing 365-nm UV light.

Enhancing the conversion efficiency of extreme ultraviolet light sources using a 2 µm-wavelength laser

In this study, we use the FLASH radiation hydrodynamic code and the FLYCHK atomic code to investigate the energy conversion and spectra associated with laser–Sn target interactions with 1 µm and 2 µm wavelength lasers. We found that the conversion efficiency (CE) reached as much as 3.38% with the 2 µm laser, which is 1.48 percentage points higher than the 1 µm laser (CE = 1.9%). In addition, we analyzed the contribution of dominant ionization states to the emission spectrum for both lasers. We observed that the growths of the out-of-band emission eventually led to a broadening of the spectrum, resulting in a reduction of SP for the 1 µm laser. By contrast, the emission main peaks were all centered near 13.5nm for the 2 µm laser, which is beneficial for efficient emission of light with a 13.5 nm wavelength (relevant for nanolithographic applications).

Relativistic Configuration-Interaction and Perturbation Theory Calculations of the Sn XV Emission Spectrum

Recently, there has been increased interest in developing advanced bright sources for lithography. Sn ions are particularly promising due to their bright emission spectrum in the required wavelength range. Cowan’s code has been used to model the emission; however, it has adjustable parameters, which limit its predictive power, and it has limited relativistic treatment. Here, we present calculations based on ab initio relativistic configuration-interaction many-body perturbation theory (CI-MBPT), with relativistic corrections included at the Dirac-Fock level and core-polarization effects with the second-order MBPT. As a proof of principle that the theory is generally applicable to other Sn ions with proper development, we focused on one ion where direct comparison with experimental observations is possible. The theory can also be used for ions of other elements to predict emissions for optimization of plasma-based bright sources.