Relaxation behaviour of Pb(Ni1/3Nb2/3)O3 ceramics

1993 ◽  
Vol 71 (7-8) ◽  
pp. 322-325 ◽  
Author(s):  
Seema Sharma ◽  
R. Sati ◽  
R. N. P. Choudhary

Polycrystalline samples of a cubic perovskite structure with an estimated 2.9% of a minor pyrochlore phase of Pb(Ni1/3,Nb2/3)O3 were synthesized by a high-temperature solid-state reaction technique. Dielectric studies show that the material is a good relaxor with a high dielectric constant. Diffuse phase transition through a wide Curie-temperature range was observed. The activation energy in a specified range of temperature for the material is estimated.

1994 ◽  
Vol 9 (10) ◽  
pp. 2634-2644 ◽  
Author(s):  
Hyun M. Jang ◽  
Kyu-Mann Lee ◽  
Moon-Ho Lee

The perovskite phase in PZN-PMN-PT (PbZn1/3Nb2/3O3-PbMg1/3Nb2/3O3-PbTiO3) pseudoternary ceramics was stabilized by the addition of excess constituent divalent oxides (PbO, MgO, and ZnO). 5 mol% excess MgO or 7.5 mol% excess PbO was sufficient to eliminate the remnant cubic pyrochlore phase after sintering at 1100 °C for 1 h. The enhanced diffuse phase transition (DPT) and the decrease in the electrical resistivity were observed in the presence of excess ZnO or MgO. These were interpreted in terms of the additional formation of negatively charged, short-range ordered 1: 1 domains with a concomitant generation of charge carriers (holes). The behavior of excess MgO or ZnO at concentrations above 5 mol% was studied by examining complex impedance patterns.


2002 ◽  
Vol 74 (2) ◽  
pp. 113-120 ◽  
Author(s):  
N.K. Singh ◽  
R.N.P. Choudhary ◽  
A. Panigrahi

1992 ◽  
Vol 134 (1) ◽  
pp. 139-144 ◽  
Author(s):  
V. V. Lemanov ◽  
N. K. Yushin ◽  
E. P. Smirnova ◽  
A. V. Sotnikov ◽  
E. A. Tarakanov ◽  
...  

1978 ◽  
Vol 18 (1) ◽  
pp. 113-116 ◽  
Author(s):  
L. S. Kamzina ◽  
N. N. Krainik ◽  
G. A. Smolensky ◽  
V. A. Trepakov

2009 ◽  
Vol 105 (5) ◽  
pp. 054111 ◽  
Author(s):  
Takashi Teranishi ◽  
Takuya Hoshina ◽  
Hiroaki Takeda ◽  
Takaaki Tsurumi

1978 ◽  
Vol 21 (1) ◽  
pp. 521-523 ◽  
Author(s):  
G. A. Smolensky ◽  
N. N. Krainik ◽  
V. A. Trepakov ◽  
S. A. Ktitorov ◽  
L. S. Kamzina ◽  
...  

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