THE ANALYSIS OF NUCLEAR MAGNETIC RESONANCE SPECTRA: IV. FOUR NUCLEI: AB3

1958 ◽  
Vol 36 (9) ◽  
pp. 1302-1307 ◽  
Author(s):  
R. J. Abraham ◽  
J. A. Pople ◽  
H. J. Bernstein
Keyword(s):  
Nuclear Magnetic Resonance ◽  
Magnetic Resonance ◽  
Proton Magnetic Resonance ◽  
Resonance Spectrum ◽  
Proton Magnetic Resonance Spectrum ◽  
Methyl Mercaptan ◽  
Nuclear Magnetic Resonance Spectra ◽  
Magnetic Resonance Spectra ◽  
Nuclear Magnetic

The proton magnetic resonance spectrum of methyl mercaptan has been analyzed on the basis of the nuclear grouping AB3. The spectrum calculated for [Formula: see text] agrees very well with that observed.

The nuclear magnetic resonance spectra of pyrrole and [N-D]pyrrole

1969 ◽  
Vol 22 (6) ◽  
pp. 1199 ◽  
Author(s):  
GF Katekar ◽  
AG Moritz
Keyword(s):  
Nuclear Magnetic Resonance ◽  
Magnetic Resonance ◽  
High Resolution ◽  
Proton Magnetic Resonance ◽  
Resonance Spectrum ◽  
Proton Magnetic Resonance Spectrum ◽  
Proton Spin ◽  
Proton Spectrum ◽  
Proton Proton ◽  
Nuclear Magnetic Resonance Spectra

The proton magnetic resonance spectrum at 60 MHz of pyrrole, spin- decoupled from 14N, has been studied under high resolution. Similar studies have been made on [N-D]pyrrole in which the proton spectrum was obtained simultaneously spin-decoupled from both the 14K and 2H nuclei. Analysis of the 13C-H spectra of pyrrole and [N-D]pyrrole, observed in natural abundance, gave values for all six proton-proton spin-spin couplings. Values for some of the couplings have been obtained directly and unambiguously from the spectra of samples of [S-H]pyrrole and [N- D]pyrrole in which the C-H protons have been predominantly exchanged for deuterium. The values for the couplings derived are J1,2 2.60, J1,3 2.45, J2,3 2.69, J2,4 1.44, J2,5 1.87, and J3,4 3.34 Hz.

The nuclear magnetic resonance spectrum of a cobyrinic acid derivative

1965 ◽  
Vol 288 (1414) ◽  
pp. 342-343 ◽  
Keyword(s):  
Nuclear Magnetic Resonance ◽  
Magnetic Resonance ◽  
Nuclear Magnetic Resonance Spectrum ◽  
Acid Derivative ◽  
Resonance Spectrum ◽  
Nuclear Magnetic Resonance Spectra ◽  
Magnetic Resonance Spectra ◽  
Nuclear Magnetic

In an extension of studies on the exchange of meso-hydrogen in porphyrins and reduced porphyrins (R. Bonnett & G.F. Stephenson, unpublished results) the nuclear magnetic resonance spectra of natural corrinoid derivatives have been investigated. Since it was hoped to observe a signal due to the CIO proton a nucleotide-free compound was desirable, and the hexacarboxylic acid (8-amino- cobyrinic acid c-lactam), prepared by the method of Bonnett, Cannon, Johnson & Todd (1957), was selected.

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