Vibrational spectra of halopentacarbonylmanganese(I) derivatives
1969 ◽
Vol 47
(22)
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pp. 4117-4128
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Keyword(s):
The solid-state infrared (i.r.) and laser Raman spectra of the halopentacarbonylmanganese(I) derivatives, Mn(CO)5X (X = Cl, Br,and I), have been recorded in the C—O stretching and the low frequency (700–33 cm−1) regions. The i.r. overtone and combination spectra recorded in the regions 2800–2250 and 1350–700 cm−1 have been used to help in the assignment of some of the low frequency fundamentals. The solid-state i.r. and laser Raman spectra of the dimeric halotetracarbonylmanganese(I) derivatives, [Mn(CO)4X]2 (X = Br and I), have been recorded in the C—O stretching and the low frequency regions for comparative purposes and shown to be consistent with the expected D2h symmetry of the molecules.
Keyword(s):
1972 ◽
Vol 94
(9)
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pp. 3250-3251
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Keyword(s):
1970 ◽
Vol 48
(20)
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pp. 3117-3123
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Keyword(s):