Nuclear Magnetic Resonance Study of Ring Inversion in Cycloheptene
Keyword(s):
The p.m.r. spectrum of 4,4,5,6,6-pentadeuteriocycloheptene (3) has been studied down to −171 °C. Analysis of the spectral change below −160 °C yielded a ΔF≠ value of 5.0 kcal/mol at −165 °C. Possible energy profiles for the ring inversion of cycloheptene are discussed.
1970 ◽
Vol 11
(55)
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pp. 4833-4836
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1975 ◽
pp. 1354
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1971 ◽
Vol 32
(C1)
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pp. C1-1154-C1-1156
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1969 ◽
Vol 244
(20)
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pp. 5656-5662
1981 ◽
pp. 1082
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