Evaluation of Stereolithography-Based Additive Manufacturing Technology for BaTiO3 Ceramics at 465 nm

A piezoceramic BaTiO3 material that is difficult for 3D printing was tested with a homemade laser-based stereolithography (SLA) setup. The high light absorbance of BaTiO3 in the spectral range of 350–410 nm makes this material hardly usable with most commercial SLA 3D printers. The typical polymerization depth of BaTiO3 ceramic pastes in this spectral range hardly reaches 30–50 µm for 40 vol % powder loading. A spectral change to 465 nm was realized in this work via a robot-based experimental SLA setup to improve the 3D printing efficiency. The ceramic paste was prepared from a preconditioned commercial BaTiO3 powder and used for 3D printing. The paste’s polymerization was investigated with variation of powder fraction (10–55 vol %), speed of a laser beam (1–10 mm/s, at constant laser power), and a hatching spacing (100–1000 µm). The polymerization depths of over 100 µm were routinely reached with the 465 nm SLA for pastes having 55 vol % powder loading. The spectral shift from 350–410 nm spectral region to 465 nm reduced the light absorption by BaTiO3 and remedied the photopolymerization process, emphasizing the importance of comprehensive optical analysis of prospective powders in SLA technology. Two multi-layered objects were 3D-printed to demonstrate the positive effect of the spectral shift.

Neural Processing of Spectral and Durational Changes in Speech and Non-speech Stimuli: An MMN Study With Czech Adults

Neural discrimination of auditory contrasts is usually studied via the mismatch negativity (MMN) component of the event-related potentials (ERPs). In the processing of speech contrasts, the magnitude of MMN is determined by both the acoustic as well as the phonological distance between stimuli. Also, the MMN can be modulated by the order in which the stimuli are presented, thus indexing perceptual asymmetries in speech sound processing. Here we assessed the MMN elicited by two types of phonological contrasts, namely vowel quality and vowel length, assuming that both will elicit a comparably strong MMN as both are phonemic in the listeners’ native language (Czech) and perceptually salient. Furthermore, we tested whether these phonemic contrasts are processed asymmetrically, and whether the asymmetries are acoustically or linguistically conditioned. The MMN elicited by the spectral change between /a/ and /ε/ was comparable to the MMN elicited by the durational change between /ε/ and /ε:/, suggesting that both types of contrasts are perceptually important for Czech listeners. The spectral change in vowels yielded an asymmetrical pattern manifested by a larger MMN response to the change from /ε/ to /a/ than from /a/ to /ε/. The lack of such an asymmetry in the MMN to the same spectral change in comparable non-speech stimuli spoke against an acoustically-based explanation, indicating that it may instead have been the phonological properties of the vowels that triggered the asymmetry. The potential phonological origins of the asymmetry are discussed within the featurally underspecified lexicon (FUL) framework, and conclusions are drawn about the perceptual relevance of the place and height features for the Czech /ε/-/a/ contrast.

Surface and interfacial waves in a strongly stratified upper ocean

In an idealized two-layer fluid, surface waves can generate waves at the internal interface through class 3 resonant triads in which all waves are propagating in the same direction. The triads are restricted to wavenumbers above a critical value kcrit that depends on the density ratio R between the two layers, and their depths. We perform numerical simulations to analyze the evolution of a surface wave field, initially specified by a Pierson-Moskowitz type spectrum, for R = 0:97 (representing a realistic lower a bound for oceanic stratification). At high initial steepness and peak wavenumber kp ≪ kcrit, the energy increases in the spectral tail; as a parameterization of resulting wave breaking, at each time step individual waves with a steepness greater than the limiting Stokes steepness are removed. The energy change of the surface wave field is a combination of energy transfer to the interfacial waves, spectral downshift, and wave breaking dissipation. At wavenumbers ≳ 0:6kp there is a net loss of energy, with the greatest dissipation at ≈ 1:3kp. The maximum gain occurs at ≈ 0:5kp. The onset of the spectral change shows a strong threshold behaviour with respect to the the initial wave steepness. For steep initial waves the integrated energy dissipation can reach > 30% of the initial energy, and only ≈ 1% of the initial surface wave energy is transferred to the interfacial wave field. The spectral change could be expressed as an additional dissipation source term, and coupled ocean/wave models should include additional mixing associated with the interfacial waves and enhanced wave breaking turbulence.