Carbon Disulfide. IV. Reaction with Active Methylene Compounds. The Formation of 3,5-Bismethylene-1,2,4-trithiolanes
Keyword(s):
The three-sulfur compounds formed on oxidation of the β-keto dithio acids prepared by the reaction of active methylene compounds with base and carbon disulfide have been shown to be 3,5-bis(acylmethylene)-1,2,4-trithiolane derivatives. In several cases, two of the three possible geometrical isomers have been isolated and provisional stereochemical assignments have been made. The i.r. and u.v. spectra of the trithiolanes have been compared with those of corresponding 2,4-bis(acylmethylene)-1,3-dithie-tane derivatives (desaurins) and interpreted in terms of a strong conjugative interaction between the sulfur atoms and carbonyl groups.
2018 ◽
Vol 39
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pp. 164-172
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1999 ◽
Vol 378
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pp. 43-46
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1967 ◽
Vol 32
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pp. 980-984
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1969 ◽
Vol 34
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pp. 730-732
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2010 ◽
Vol 92
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pp. 1169-1178
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