Influence of Lewis Acids on the Diels–Alder Reaction. IV. Reaction of 2-Methyl- and 2-Phenylfuran with Ethyl Propiolate
1971 ◽
Vol 49
(19)
◽
pp. 3152-3157
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Keyword(s):
The AlCl3-promoted reactions of 2-methyl- and of 2-phenylfuran with ethyl propiolate afford as major products ethyl 5-hydroxy-2-methyl- and 2-phenylbenzoates (6a, 6b). Also isolated as minor by-products of these reactions are ethyl 3-(2-furyl-5-methyl)acrylate (5a), ethyl 3-(2-furyl-5-phenyl)acrylate (5b), ethyl 3,3-di(2-furyl-5-methyl)propionate (10a), ethyl 3,3-di(2-furyl-5-phenyl)propionate (10b), and ethyl 2-hydroxy-5-methylbenzoate (8a).
2006 ◽
Vol 84
(10)
◽
pp. 1487-1503
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1990 ◽
Vol 45
(12)
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pp. 1684-1688
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1971 ◽
Vol 74
(10)
◽
pp. 2097-2099
Keyword(s):
1990 ◽
Vol 31
(38)
◽
pp. 5433-5436
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Keyword(s):