Neutral Solvolysis of Acyl Carbon and the Temperature Dependence of the Kinetic Solvent Isotope Effect
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The temperature dependence of the rate of hydrolysis of benzoic, phthalic, and succinic anhydrides have been determined in H2O and D2O under "neutral" conditions. Corresponding data have been obtained for methyl trifluoroacetate. While both series supposedly react by the same BAc2 mechanism, remarkable differences are made obvious by this investigation. Possible sources of such differences are proposed.
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1988 ◽
Vol 110
(2)
◽
pp. 590-593
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1972 ◽
Vol 94
(2)
◽
pp. 573-575
◽
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1975 ◽
Vol 53
(20)
◽
pp. 3106-3115
◽
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2021 ◽