A Kinetic Study of the Thermal Isomerization of and Related Complexes

The kinetics of the unimolecular isomerization reaction[Formula: see text]have been studied. The ΔH≠ values in kcal mol−1 are 36.8 ± 2.0 (M = M′ = Mn ), 46.8 ± 0.5 (M = M′ = Re ), 39.2 ± 2.8 (M = Mn, M′ = Re ). The mechanism of the rearrangement is discussed.

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Research on the Kinetics of Thermal Isomerization Reaction of Mesoisomer of Diethyl 2,3-Dicyano-2,3-diphenylsuccinate in Aromatic Compound Solvents by HPLC

Journal of Liquid Chromatography &amp Related Technologies ◽

10.1080/10826079808001240 ◽

1998 ◽

Vol 21 (4) ◽

pp. 567-573 ◽

Cited By ~ 1

Author(s):

S. Gao ◽

X. Zhou ◽

X. Wang

Keyword(s):

Aromatic Compound ◽

Thermal Isomerization ◽

Isomerization Reaction ◽

Kinetics Of

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ChemInform Abstract: REACTIONS OF ETHYLENEDIAMINE-N,N′-DIACETATODIAQUO COMPLEXES OF COBALT(III). 3. KINETIC STUDY OF THE β-CIS-CO(EDDA)(OH2)2+ .DBLHAR . α-CIS-CO(EDDA)(OH2)2+ ISOMERIZATION REACTION

Chemischer Informationsdienst ◽

10.1002/chin.197805296 ◽

1978 ◽

Vol 9 (5) ◽

Author(s):

J. A. WEYH

Keyword(s):

Kinetic Study ◽

Isomerization Reaction

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A kinetic study on the action of rubber oxidation inhibitors—III. Kinetics of inhibited oxidation

Polymer Science U S S R ◽

10.1016/0032-3950(64)90389-2 ◽

1964 ◽

Vol 6 (6) ◽

pp. 1208-1215

Author(s):

Kh.S. Bagdasar'yan ◽

R.I. Milyutinskaya

Keyword(s):

Kinetic Study ◽

Inhibited Oxidation ◽

Oxidation Inhibitors ◽

Kinetics Of

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Kinetics of the Thermal Isomerization of Methylcyclopropane†

The Journal of Physical Chemistry A ◽

10.1021/jp982991x ◽

1999 ◽

Vol 103 (3) ◽

pp. 362-364 ◽

Cited By ~ 9

Author(s):

Bansi L. Kalra ◽

Janet Y. Cho ◽

David K. Lewis

Keyword(s):

Thermal Isomerization ◽

Kinetics Of

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Kinetic Study of the Diels-Alder Reaction of Cyclopentadiene with Bis(2-Ethylhexyl) Maleate

Advanced Materials Research ◽

10.4028/www.scientific.net/amr.634-638.541 ◽

2013 ◽

Vol 634-638 ◽

pp. 541-545 ◽

Cited By ~ 3

Author(s):

Jun Seong Park ◽

Dae Hee Yun ◽

Tae Won Ko ◽

Yong Sung Park ◽

Je Wan Woo

Keyword(s):

Kinetic Study ◽

Reaction Temperature ◽

Atmospheric Pressure ◽

Arrhenius Equation ◽

Alder Reaction ◽

Diels Alder ◽

Influence Of Temperature ◽

Diels Alder Reaction ◽

Influence Of Temperature On ◽

Kinetics Of

The kinetics of the Diels-Alder reaction of cyclopentadiene with bis(2-ethylhexyl) maleate has been studied at temperatures between 25 and 100 °C and at atmospheric pressure. The influence of temperature on the kinetic constants was determined by fitting the results to the Arrhenius equation. As a result, fitting line similar with the linear curve of the Arrhenius equation at 25, 30 and 40 °C. However, the fitting curve, at 60, 80 and 100 °C, tended towards the outside of the curve in the form of Arrhenius equation. The ratio of endo/exo was a slight change from increase of the reaction temperature.

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