Reagents and synthetic methods. 31. Silylations with N-trimethylsilyl-2-oxazolidinone (TMSO)

Silylation of ketones, alcohols, mercaptans, and carboxylic acids with N-trimethylsilyl-2-oxazolidinone (TMSO) and triflic acid as catalyst has been described from synthetic and mechanistic points of view.

Download Full-text

Synthetic methods and reactions. 136. Single-step one-carbon ring homologation of cyclic and polycyclic hydrocarbons via their methyl alcohols or carboxylic acids with sodium borohydride/triflic acid

The Journal of Organic Chemistry ◽

10.1021/jo00267a043 ◽

1989 ◽

Vol 54 (6) ◽

pp. 1452-1453 ◽

Cited By ~ 7

Author(s):

George A. Olah ◽

An Hsiang Wu ◽

Omar Farooq

Keyword(s):

Carboxylic Acids ◽

Sodium Borohydride ◽

Single Step ◽

Synthetic Methods ◽

Triflic Acid ◽

Polycyclic Hydrocarbons ◽

Carbon Ring

Download Full-text

ChemInform Abstract: Synthetic Methods and Reactions. Part 136. Single-Step One-Carbon Ring Homologation of Cyclic and Polycyclic Hydrocarbons via Their Methyl Alcohols or Carboxylic Acids with Sodium Borohydride/Triflic Acid.

ChemInform ◽

10.1002/chin.198935161 ◽

1989 ◽

Vol 20 (35) ◽

Author(s):

G. A. OLAH ◽

A. WU ◽

O. FAROOQ

Keyword(s):

Carboxylic Acids ◽

Sodium Borohydride ◽

Single Step ◽

Synthetic Methods ◽

Triflic Acid ◽

Polycyclic Hydrocarbons ◽

Carbon Ring

Download Full-text

ChemInform Abstract: Synthetic Methods and Reactions. Part 158. Trifluoromethanesulfonic ( Triflic) Acid-Catalyzed Transformations of α-Hydroxy Carbonyl Compounds.

ChemInform ◽

10.1002/chin.199134144 ◽

2010 ◽

Vol 22 (34) ◽

pp. no-no

Author(s):

G. A. OLAH ◽

A. WU

Keyword(s):

Carbonyl Compounds ◽

Synthetic Methods ◽

Triflic Acid ◽

Acid Catalyzed

Download Full-text

ChemInform Abstract: Synthetic Methods and Reactions. Part 134. Single-Step Reductive Isomerization of Unsaturated Polycyclics to C4n+6H4n+12 Diamondoid Cage Hydrocarbons with Sodium Borohydride/Triflic Acid.

ChemInform ◽

10.1002/chin.198935160 ◽

1989 ◽

Vol 20 (35) ◽

Author(s):

G. A. OLAH ◽

A. WU ◽

O. FAROOQ ◽

G. K. S. PRAKASH

Keyword(s):

Sodium Borohydride ◽

Single Step ◽

Synthetic Methods ◽

Triflic Acid

Download Full-text

ChemInform Abstract: Carboxylic Acids and Derivatives (Prepared by General and Synthetic Methods)

ChemInform ◽

10.1002/chin.198905332 ◽

1989 ◽

Vol 20 (5) ◽

Author(s):

D. W. KNIGHT

Keyword(s):

Carboxylic Acids ◽

Synthetic Methods

Download Full-text

Facile Synthetic Methods for 3- and 5-Trifluoromethyl-4-trifluoroacetylpyrazoles and Their Conversion into Pyrazole-4-carboxylic Acids

Heterocycles ◽

10.3987/com-91-5969 ◽

1992 ◽

Vol 34 (4) ◽

pp. 791 ◽

Cited By ~ 6

Author(s):

Masaru Hojo ◽

Etsuji Okada ◽

Ryoichi Masuda

Keyword(s):

Carboxylic Acids ◽

Synthetic Methods

Download Full-text

ChemInform Abstract: Synthetic Methods and Reactions. Part 157. Reductive Alkylation and Reduction of Tertiary, Secondary, and Benzylic Alcohols with Trimethyl- , Triethyl-, and Triisopropylboron/Trifluoromethanesulfonic (Triflic) Acid.

ChemInform ◽

10.1002/chin.199140091 ◽

2010 ◽

Vol 22 (40) ◽

pp. no-no

Author(s):

G. A. OLAH ◽

A.-H. WU ◽

O. FAROOQ

Keyword(s):

Synthetic Methods ◽

Triflic Acid ◽

Reductive Alkylation ◽

Benzylic Alcohols

Download Full-text

Synthetic methods and reactions. 188. Triflic acid catalyzed phenylamination of aromatics with phenyl azide

The Journal of Organic Chemistry ◽

10.1021/jo00076a063 ◽

1993 ◽

Vol 58 (24) ◽

pp. 6900-6901 ◽

Cited By ~ 15

Author(s):

George A. Olah ◽

Pichika Ramaiah ◽

Qi Wang ◽

G. K. Surya Prakash

Keyword(s):

Synthetic Methods ◽

Triflic Acid ◽

Phenyl Azide ◽

Acid Catalyzed

Download Full-text

Continuous-Flow Electrophilic Amination of Arenes and Schmidt Reaction of Carboxylic Acids Utilizing the Superacidic Trimethylsilyl Azide/Triflic Acid Reagent System

The Journal of Organic Chemistry ◽

10.1021/acs.joc.6b02085 ◽

2016 ◽

Vol 81 (19) ◽

pp. 9372-9380 ◽

Cited By ~ 7

Author(s):

Yuesu Chen ◽

Bernhard Gutmann ◽

C. Oliver Kappe

Keyword(s):

Carboxylic Acids ◽

Continuous Flow ◽

Triflic Acid ◽

Schmidt Reaction ◽

Electrophilic Amination ◽

Trimethylsilyl Azide ◽

Acid Reagent

Download Full-text

ChemInform Abstract: Synthetic Methods and Reactions. Part 188. Triflic Acid Catalyzed Phenylamination of Aromatics with Phenyl Azide.

ChemInform ◽

10.1002/chin.199413142 ◽

2010 ◽

Vol 25 (13) ◽

pp. no-no

Author(s):

G. A. OLAH ◽

P. RAMAIAH ◽

Q. WANG ◽

G. K. S. PRAKASH

Keyword(s):

Synthetic Methods ◽

Triflic Acid ◽

Phenyl Azide ◽

Acid Catalyzed

Download Full-text