Euphorstranoids A and B, Two Highly Rearranged Ingenane Diterpenoids from Euphorbia stracheyi: Structural Elucidation, Chemical Transformation, and Lipid-Lowering Activity

Euphorstranoids A (1) and B (2), two highly rearranged ingenane diterpenoids with an unusual 5/6/7/3 carbon ring system, were isolated from Euphorbia stracheyi. Their structures were determined by a combination...

Superconductivity in Octagraphene

This article reviews the basic theoretical aspects of octagraphene, an one-atom-thick allotrope of carbon, with unusual two-dimensional (2D) Fermi nesting, hoping to contribute to the new family of quantum materials. Octagraphene has an almost strongest sp 2 hybrid bond similar to graphene, and has the similar electronic band structure as iron-based superconductors, which makes it possible to realize high-temperature superconductivity. We have compared various possible mechanisms of superconductivity, including the unconventional s ± superconductivity based on spin fluctuation and conventional superconductivity based on electron-phonon coupling. Theoretical studies have shown that octagraphene has relatively high structural stability. Although many 2D carbon materials with C 4 carbon ring and C 8 carbon ring structures have been reported, it is still challenging to realize the octagraphene with pure square-octagon structure experimentally. This material holds hope to realize new 2D high-temperature superconductivity.

Magnetic Shielding Study of Bonding and Aromaticity in Corannulene and Coronene

Bonding and aromaticity in the bowl-shaped C5v and planar D5h geometries of corannulene and the planar D6h geometry of coronene are investigated using 3D isosurfaces and 2D contour plots of the isotropic magnetic shielding σiso(r) and, for planar geometries, of the out-of-plane component of the shielding tensor σzz(r). Corannulene and coronene both feature conjoined shielded “doughnuts” around a peripheral six-membered carbon ring, suggesting strong bonding interactions and aromatic stability; a deshielded region inside the hub ring of corannulene indicates that this ring is antiaromatic, more so in planar corannulene. The switch from the planar to the bowl-shaped geometry of corannulene is shown to enhance both bonding and the local aromaticities of the five- and six-membered rings; these factors, in addition to ring strain reduction, favour the bowl-shaped geometry. The most and least shielded bonds in both corannulene and coronene turn out to be the spoke and hub bonds, respectively. The higher π electron activity over spoke bonds in planar corannulene and coronene is supported by σzz(r) contour plots in planes 1 Å above the respective molecular planes; these findings about spoke bonds are somewhat unexpected, given that ring current studies indicate next to no currents over spoke bonds.

The influence of gamma radiation on organic compounds having carbon ring and its application in dosimetry

The formation of highly oxidizing radicals in multifunctional-solid compounds upon irradiation with gamma-ray had been investigated. Five organic compounds having a single carbon ring had been used in the present investigation; these materials are 1-chloro-4-nitrobenzene, 4′-aminoacetophenone, 3′-hydroxyacetophenone, n-anthranilic acid, and triphenylmethane. These material were irradiated using 60Co radiation with different doses between 20 and 100 kGy. Electron spin resonance spectroscopy spotted increases of the resonance absorption having landé factor around 2.0113 ± 0.003 upon irradiation with the increasing of dose. This resonance absorption was related to the formation of long-lived oxygen radicals that were attached to one of the radiation synthesized compounds. The method of infrared absorption spectroscopy emphasized the formation of cyclic and aliphatic hexane in addition to the active oxygen radicals. n-Anthranilic acid was found to be suitable for radiation the dosimetry with long-lasting radiation signature as electron spin and also to determine the exposure dose. The time-lapse infrared and electron spin resonance measurements had been used to tracked the formation of active species within the time-lapsed after the end of exposure; results showed that the dosimetric signature may be used as a tracker for the time when the exposure happens.