Potential-Dependent Electrochemical Impedance Spectroscopy as a Powerful Tool for Evaluating Supercapacitor Electrode Performance

Author(s):  
Alan Massayuki Perdizio Sakita ◽  
Rodrigo Della Noce ◽  
Rodrigo Lavall
2011 ◽  
Vol 345 ◽  
pp. 75-78 ◽  
Author(s):  
Wei Zhou ◽  
Man Lin Tan ◽  
Xiao Song Zhou

In this paper, a facilesolution method was employed to synthesize the graphene-NiO composite. SEM and XRD results indicated the graphene sheets were covered by the NiO nanoplates. Cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS) were used to measure the electrochemical properties of the composite. The specific capacitance reached 1292F/g at a scan rate of 5mV/s. The results show that this composite is a promising material for supercapacitor electrode.


2020 ◽  
Vol 8 (7) ◽  
pp. 4099-4106 ◽  
Author(s):  
Beom-Kyeong Park ◽  
Roberto Scipioni ◽  
Dalton Cox ◽  
Scott A. Barnett

GDC nanoparticles reduce the reaction resistance associated with three-phase boundaries and improve oxygen transport in the Ni–YSZ electrode, as measured by electrochemical impedance spectroscopy under actual solid oxide cell operating conditions.


Catalysts ◽  
2020 ◽  
Vol 10 (7) ◽  
pp. 782 ◽  
Author(s):  
Adama A. Bojang ◽  
Ho Shing Wu

The main objective of this study was to examine the quantitative performance of the electrochemical redox reaction of glucose by glucosidase and oxygen with laccase in a phosphate buffer solution at pH 7.0. The characterization of electrode performance was performed by using electrochemical analysis such as cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS). The use of such electrochemical analysis (CV and EIS) enables a better understanding of the redox process, the charge transfer resistance, and, hence, the potential mass transfer among the electrode materials in phosphorus buffer solution. The experimental results show that the maximum power densities of the bioanode and the biocathode electrodes were 800 µA/cm2 and 600 µA/cm2, respectively. Both the bioanode and biocathode show high internal resistance. The occurrence of peak-separation shows an excellent mass-transfer mechanism and better chemical reactivity in the electrode.


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