Li-Ion Transfer at the Interface Between Li4Ti5O12 and Ionic Liquid-Organic Solvent Mixtures Electrolyte

2018 ◽  
Vol 122 (43) ◽  
pp. 24788-24800 ◽  
Author(s):  
Abhishek Lahiri ◽  
Giridhar Pulletikurthi ◽  
Maryam Shapouri Ghazvini ◽  
Oliver Höfft ◽  
Guozhu Li ◽  
...  

2015 ◽  
Vol 3 (35) ◽  
pp. 18064-18073 ◽  
Author(s):  
Yun-Sheng Ye ◽  
Hao Wang ◽  
Shu-Guang Bi ◽  
Yang Xue ◽  
Zhi-Gang Xue ◽  
...  

Polymer-functionalized reduced graphene oxide (polymer-FG) combining a polymer ionic liquid and a polymer brush structure is a promising nanofiller for the effective improvement of Li-ion transfer conditions.


RSC Advances ◽  
2015 ◽  
Vol 5 (3) ◽  
pp. 2122-2128 ◽  
Author(s):  
Shizhao Xiong ◽  
Johan Scheers ◽  
Luis Aguilera ◽  
Du-Hyun Lim ◽  
Kai Xie ◽  
...  

A mixed organic solvent/ionic liquid electrolyte combined the beneficial properties of both worlds, high capacity and high safety, through the local arrangement around the Li-ion.


Author(s):  
Yassine Bencherifi ◽  
Badre Larhrib ◽  
Adnan Sayegh ◽  
Georgios Nikiforidis ◽  
Mérièm Anouti

Membranes ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 359
Author(s):  
László Koók ◽  
Piroska Lajtai-Szabó ◽  
Péter Bakonyi ◽  
Katalin Bélafi-Bakó ◽  
Nándor Nemestóthy

Hydrophobic ionic liquids (IL) may offer a special electrolyte in the form of supported ionic liquid membranes (SILM) for microbial fuel cells (MFC) due to their advantageous mass transfer characteristics. In this work, the proton and ion transfer properties of SILMs made with IL containing imidazolium cation and [PF6]− and [NTf2]− anions were studied and compared to Nafion. It resulted that both ILs show better proton mass transfer and diffusion coefficient than Nafion. The data implied the presence of water microclusters permeating through [hmim][PF6]-SILM to assist the proton transfer. This mechanism could not be assumed in the case of [NTf2]− containing IL. Ion transport numbers of K+, Na+, and H+ showed that the IL with [PF6]− anion could be beneficial in terms of reducing ion transfer losses in MFCs. Moreover, the conductivity of [bmim][PF6]-SILM at low electrolyte concentration (such as in MFCs) was comparable to Nafion.


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